• 제목/요약/키워드: Evaporation gas

검색결과 427건 처리시간 0.022초

금속 산화물 반도체 나노구조의 합성과 가스 감응 특성 (Synthesis of Metal Oxide Semiconductor Nanostructures and Their Gas Sensing Properties)

  • 최권일;이종흔
    • 한국전기전자재료학회논문지
    • /
    • 제25권8호
    • /
    • pp.632-638
    • /
    • 2012
  • The prepartion of various metal oxide nanostructures via hydrothermal method, hydrolysis, thermal evaporation and electrospinning and their applications to chemoresistive sensors have been investigated. Hierarchical and hollow nanostructures prepared by hydrothermal method and hydrolysis showed the high response and fast responding kinetics on account of their high gas accessibility. Thermal evaporation and electrospinning provide the facile routes to prepare catalyst-loaded oxide nanowires and nanofibers, respectively. The loading of noble metal and metal oxide catalyst were effective to achieve rapid response/recovery and selective gas detection.

Preparation of Ultrafine Au-Pb Particles by Gas-evaporation Technique

  • Ohno, Takehisa;Funaguchi, Hironori
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.158-159
    • /
    • 2006
  • Ultrafine Au-Pb particles prepared by two method, (1) simultaneous evaporation of Au and Pb in inert gas and (2) subsequent vapor condensation of Pb in a differentially evacuated tube onto flying Au nanoparticles prepared by gasevaporation technique, were observed by electron microscopy. In the method (1), the particles that grew at the region where the two smoke masses converged, consisted of alloy phases. In the method (2), the particles consisted of two or three phases of Au, $Au_2Pb$, $AuPb_2$ and Pb phases in turn from the inner part, Pb-rich particles being composed of only two phases of $AuPb_2$ and Pb.

  • PDF

가스터빈 연소기내의 고온공기 분무연소 해석 (Spray combustion with high temperature air in a Gas Turbine Combustor)

  • 조상필;김호영;박심수
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
    • /
    • pp.192-198
    • /
    • 2004
  • A numerical study was conducted to determine the effects of high temperature air, including equivalent ratio on flow field, temperature, evaporation, and overall temperature distribution in gas turbine combustor. A sector model of a typical wall jet can combustor, featuring introduction of primary air and dilution air via wall jet, was used in calculations. Flow field and temperature distribution were analyzed. Operating conditions such as inlet temperature and overall equivalent ratio were varied from 373 to 1300 K, and from 0.3 to 0.6, respectively, while any other operating conditions were fixed. The RNG ${\kappa}-{\varepsilon}$ model and eddy breakup model were used for turbulence and combustion model respectively. It was found that the increase with the inlet air temperature, velocity in the combustor is accelerated and evaporation of liquid fuel is not affected in primary zone, high temperature inlet air enhances the evaporation and improves overall temperature distribution factor.

  • PDF

화학증착 및 증발-산화법에 의한 알루미나 복합분리막의 제조 및 투과특성 (Preparation and Permeation Characteristics of Alumina Composite Membranes by CVD and Evaporation-Oxidation Process)

  • 안상옥;최두진;현상훈;정형진;유광수
    • 한국세라믹학회지
    • /
    • 제30권8호
    • /
    • pp.678-684
    • /
    • 1993
  • Alumina composite membranes were prepared by chemical vapor deposition and evaporation-oxidation process. For CVD process, deposition was carried out using aluminum-tri-isopropoxide at 35$0^{\circ}C$, 2 torr by heterogeneous reaction, and for evaporation-oxidation process, alumina composite membranes were prepared by evaporation of aluminum and dry oxidation at 80$0^{\circ}C$. As deposition time increases, water flux and N2 gas permeability of the composite membranes prepared by both processes were reduced. Applying gas permeation model, permeability and cracking possibility of top layer were evaluated.

  • PDF

공증발과 열산화로 제조한 Ag-CuO-SnO2 박막에서 미세조직과 CO 가스 감지특성 (Microstructure and CO Gas Sensing Properties of Ag-CuO-SnO2 Thin Films Prepared by Co-Evaporation and Thermal Oxidation)

  • 지인걸;한규석;오재희;고태경
    • 한국세라믹학회지
    • /
    • 제46권4호
    • /
    • pp.429-435
    • /
    • 2009
  • In this study, we investigated microstructure and the CO gas sensing properties of Ag-CuO-$SnO_2$ thin films prepared by co-evaporation and subsequently thermal oxidation at air atmosphere. The sensitivity of a Cu-Sn films, thermally oxidized at $600^{\circ}C$, is strongly affected by the amount of Cu. At Cu:7 wt%-Sn:93 wt%, the film exhibited a maximum sensitivity of ${\sim}2.3$ to CO gas of 1000 ppm at $300^{\circ}C$. In contrast, the sensitivity of a Sn-Ag film did not change significantly with the amount of Ag. An enhanced sensitivity of ${\sim}3.7$ was observed in the film with a composition of Ag:3 wt%-Cu:4 wt%-Sn:93 wt%, when thermally oxidized at $600^{\circ}C$. In addition, this thin film shows a response time of ${\sim}80$ sec and a recovery time of ${\sim}450$ sec to 1000 ppm CO gas. The results demonstrate that the CO sensitivity of the Ag-CuO-$SnO_2$ thin films may be closely associated with coexistence of $SnO_2$ and SnO phase, decrease in average particle size, and a porous microstructure. We also suggest that co-evaporation and followed by thermal oxidation is a very simple and effective method to prepare oxide gas sensor thin films.

진공증착법으로 제조한 In2O3 나노벨트막의 NO가스감지특성 (NO gas-sensing properties of In2O3 nanobelt films prepared by thermal evaporation)

  • 최무희;마대영
    • 센서학회지
    • /
    • 제15권6호
    • /
    • pp.406-410
    • /
    • 2006
  • The films of indium oxide $In_{2}O_{3}$) were deposited onto $SiO_{2}$ coated Si wafers by a thermal evaporation method. Substrate temperature was varied from $25^{\circ}C$ to $300^{\circ}C$. Deposition rate increased to $250^{\circ}C$ and then decreased rapidly. The crystallographic properties and surface morphologies of the films were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The films deposited at $250^{\circ}C$ were found to have a nanobelt structure. Resistor-type gas-sensors were fabricated with $In_{2}O_{3}$ films using Pt as electrodes. The resistance variation of $In_{2}O_{3}$ films with the concentration of NO gas was measured. The $In_{2}O_{3}$ films deposited at $250^{\circ}C$ showed the highest sensitivity to the NO gas.

마이크로핀관에서 프로판과 이소부탄의 증발 열전달 특성에 관한 연구 (Evaporation Heat Transfer Characteristics of Propane and Iso-butane in Micro-fin Tubes)

  • 손창효;노건상
    • 한국가스학회지
    • /
    • 제11권4호
    • /
    • pp.35-40
    • /
    • 2007
  • 본 연구는 마이크로핀관에서 이소부탄과 프로판의 증발 열전달 특성에 대해 실험적으로 조사하였다. 시험부는 외경 12.70 mm이고, 높이가 0.25 mm인 75개 핀이 원주방향으로 삽입되어 있다. 실험결과, 탄화수소계 냉매의 평균 열전달계수는 프레온계 냉매인 HCFC22보다 높을 것으로 나타났고, 높은 질랑유속에서는 이소부탄 > 프로판 순으로 나타났다. 마이크로핀관에서 증발 열전달 계수는 평활관에 비해 약 $80{\sim}100%$ 정도가 향상되었다. 이러한 본 연구 결과로부터 탄화수소계 냉매를 냉동 공조 시스템의 냉매로 사용하여 열교환장치를 설계할 경우에는 유리하리라 생각된다.

  • PDF

가습연소 폐열회수 보일러의 물분사 설계모델 구축에 관한 연구 (Establishing the Models for Optimized Design of Water Injection in Boilers with Waste-heat-recovery System)

  • 신재훈;문석수
    • 한국분무공학회지
    • /
    • 제26권2호
    • /
    • pp.96-103
    • /
    • 2021
  • In order to improve the overall efficiency and meet the emission regulations of boiler systems, the heat exchanging methods between inlet air and exhaust gas have been used in boiler systems, named as the waste-heat-recovery condensing boiler. Recently, to further improve the overall efficiency and to reduce the NOx emission simultaneously, the concept of the water injection into the inlet air is introduced. This study suggests the models for the optimized design parameters of water injection for waste-heat-recovery condensing boilers and performs the analysis regarding the water injection amount and droplet sizes for the optimized water injection. At first, the required amount of the water injection was estimated based on the 1st law of thermodynamics under the assumption of complete evaporation of the injected water. The result showed that the higher the inlet air and exhaust gas temperature into the heat exchanger, the larger the amount of injected water is needed. Then two droplet evaporation models were proposed to analyze the required droplet size of water injection for full evaporation of injected water: one is the evaporation model of droplet in the inlet air and the other is that on the wall of heat exchanger. Based on the results of two models, the maximum allowable droplet sizes of water injection were estimated in various boiler operating conditions with respect to the residence time of the inlet air in the heat exchanger.

합성절차에 따른 1차원 ZnO 나노구조의 형태조절과 특성평가 (Shape Control and Characterization of One-dimensional ZnO Nanostructures through the Synthesis Procedure)

  • 공보현;박태은;조형균
    • 한국전기전자재료학회논문지
    • /
    • 제19권1호
    • /
    • pp.13-17
    • /
    • 2006
  • The one-dimensional ZnO nanostructures prepared through thermal evaporation under various cooling down procedures by changing the flow rates of the carrier gas and the reactive gas were investigated. The nanorod structures were changed into the nanonail types with a broad head through the reduction of the flow rate of the carrier gas. The decrease of the reactive gas reduced the length of the nail heads due to the limited mass transport of reactive gas. The intensity ratio of the ultraviolet emission/green emission of photoluminescence was proportional to the length of the broad head showing a larger surface area. The vertically aligned nanostructures were grown along the [0001] direction of ZnO regardless of the aligned directions. The crystal direction of the nanostructures was determined by that of the initial ZnO crystal.