• Title/Summary/Keyword: Evaporation and condensation

검색결과 150건 처리시간 0.022초

국부분자배향의 탄소 미세기공 구조에 대한 질소의 흡착 특성 (Adsorption Characteristics of Nitrogen in Carbonaceous Micropore Structures with Local Molecular Orientation)

  • 서양곤
    • 청정기술
    • /
    • 제28권3호
    • /
    • pp.249-257
    • /
    • 2022
  • Grand canonical Monte Carlo 전산모사 방법에 의하여 77.16 K에서 국부분자배향 모델을 가지는 나노 기공 탄소 흡착제에 대한 질소의 평형 흡착량을 계산하였다. 국부분자배향 모델은 일정한 공간을 가지는 규칙적인 격자에 동일한 크기를 배열하였다. 국부분자배향 영역의 연속적인 평면의 직교(out-of-plane)의 제거에 의해 미세기공을 도입하였고, 기본구조단위의 기울임을 통해 기울어진 기공을 도입하였다. 이런 기공 구조는 틈새형 기공 구조보다 나노기공을 가지는 탄소계 흡착제의 흡착 연구에 보다 현실적인 모델이 된다. 또한 이들 기공 구조에 대해 기공도, 표면적 그리고 제한된 비선형 최적화 기법을 활용하여 기공크기분포에 구하였다. 또한 참고 자료로써 틈새형 기공에서의 등온 평형흡착량도 계산하였다. 틈새형 기공에서는 질소분자의 5배 이상의 기공에서 hysteresis 루프가 관찰되었고, 모세관 응축과 응축의 역과정인 증발이 한 압력에서 한 번에 일어났다. 국부분자배향 기공모델에서는 질소분자의 크기의 6배 큰 기공에서 기저 슬립면, armchair 슬립면 그리고 상호연결된 채널에서 각각 세 가지 연속적인 응축이 관찰되었다. 탈착 과정의 hysteresis 루프에서는 단일 또는 두 압력에서 응축의 반대인 증발이 관찰되었다.

Preliminary Study on the Cloud Condensation Nuclei (CCN) Activation of Soot Particles by a Laboratory-scale Model Experiments

  • Ma, Chang-Jin;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
    • /
    • 제8권4호
    • /
    • pp.175-183
    • /
    • 2014
  • To visually and chemically verify the rainout of soot particles, a model experiment was carried out with the cylindrical chamber (0.2 m (D) and 4 m (H)) installing a cloud drop generator, a hydrotherometer, a particle counter, a drop collector, a diffusing drier, and an artificial soot particle distributer. The processes of the model experiment were as follows; generating artificial cloud droplets (major drop size : $12-14{\mu}m$) until supersaturation reach at 0.52%-nebulizing of soot particles (JIS Z 8901) with an average size of $0.5{\mu}m$-counting cloud condensation nuclei (CCN) particles and droplets by OPC and the fixation method (Ma et al., 2011; Carter and Hasegawa, 1975), respectively - collecting of individual cloud drops - observation of individual cloud drops by SEM - chemical identifying of residual particle in each individual droplet by SEM-EDX. After 10 minutes of the completion of soot particle inject, the number concentrations of PM of all sizes (> $0.3{\mu}m$) dramatically decreased. The time required to return to the initial conditions, i.e., the time needed to CCN activation for the fed soot particles was about 40 minutes for the PM sized from $0.3-2.0{\mu}m$. The EDX spectra of residual particles left at the center of individual droplet after evaporation suggest that the soot particles seeded into our experimental chamber obviously acted as CCN. The coexistence of soot and mineral particle in single droplet was probably due to the coalescence of droplets (i.e., two droplets embodying different particles (in here, soot and background mineral particles) were coalesced) or the particle capture by a droplet in our CCN chamber.

부양가스증발응축법으로 제조된 Ti-Ni 합금 나노분말의 특성 연구 (A study on the Particulate Properties of Ti-Ni alloy Nanopowders Prepared by Levitational Gas Condensation Method)

  • 한병선;엄영랑;이민구;김길무;이창규
    • 한국분말재료학회지
    • /
    • 제13권6호
    • /
    • pp.396-400
    • /
    • 2006
  • The Ti-Ni alloy nanopowders were synthesized by a levitational gas condensation (LGC) by using a micron powder feeding system and their particulate properties were investigated by x-ray diffraction (XRD), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) method. The starting Ti and Ni micron powders $150{\mu}m$ were incorporated into the micron powder feeding system. An ingot type of the Ti-Ni ahoy was used as a seed material for the levitation and evaporation reactions. The collected powders were finally passivated by oxidation. The x-ray diffraction experiments have shown that the synthesized powders were completely alloyed with Ti and Ni and comprised of two different cubic and monoclinic crystalline phases. The TEM results showed that the produced powders were very fine and uniform with a spherical particle size of 18 to 32nm. The typical thickness of a passivated oxide layer on the particle surface was about 2 to 3 nm. The specific surface area of the Ti-Ni alloy nanopowders was $60m^2/g$ based on BET method.

중간기 열원수 온도에 따른 만액식 해수냉각시스템의 성능 특성 (Performance Characteristics of Flooded Type Evaporator for Seawater Cooling System with Heat Source Temperature of Mid-year)

  • 윤정인;손창효;이정목;강인호
    • 동력기계공학회지
    • /
    • 제21권2호
    • /
    • pp.64-69
    • /
    • 2017
  • The purpose of this study is to investigate the performance characteristics of seawater cooling system for a fishing vessel. The circulation amount of refrigerant, condensation capacity, evaporation capacity, compression work and coefficient of performance(COP) were analyzed as the heat source temperature changed. The experimental setup consisted of an open-type compressor, a shell&tube type condenser, an evaporator and an expansion valve. The heat source was controlled by a constant temperature chamber. The main results of this study are summarized as follows. The condensation capacity increased with increasing heat source temperature, and it was confirmed that the effect of circulating amount of refrigerant was dominant. The amount of heat for vaporization was almost constant even though the temperature of the heat source increased. On the other hand, the compression power was increased. This is because the compression ratio increases as the condensation pressure, the enthalpy difference between inlet and outlet, the amount of circulating refrigerant increases. The performance coefficient of this system showed a tendency decreasing with increasing heat source temperature. Therefore, the basic data of the seawater cooling system for the maintenance of the catch line of the shore fishing boats was acquired through this study, and it is considered that it will be sufficient for the actual design.

R744-R404A용 캐스케이드 냉동시스템의 엑서지 분석 (Exergy Analysis of R744-R404A Cascade Refrigeration System)

  • 오후규;손창효
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제35권8호
    • /
    • pp.1001-1008
    • /
    • 2011
  • 본 논문은 내부 열교환기를 가지는 R744와 R404A용 캐스케이드 냉동시스템의 운전변수에 대한 최적의 설계를 위해서 냉동장치의 성능과 엑서지를 이론적으로 분석하였다. 본 연구에서 고려된 작동변수로는 과열도와 과냉각도, 내부 열교환기와 압축기 효율, 증발 및 응축온도 등이다. 분석한 결과를 요약하면 다음과 같다. 캐스케이드 증발온도가 증가할수록 R404A용 고온사이클의 COP는 증가하는 반면에, R744용 저온사이클의 COP는 감소한다. 따라서 이러한 이유로 전체 캐스케이드 냉동사이클의 COP는 거의 일정하다. 또한 캐스케이드 증발온도가 증가할수록 R404A용 응축기와 압축기의 엑서지 손실이 가장 큰 것을 알 수 있다. 따라서 R744와 R404A용 캐스케이드 냉동시스템의 COP 향상을 위해서는 R404용 응축기와 압축이의 엑서지 손실을 줄여야만 한다.

납작관의 종횡비가 R-410A 증발열전달 및 압력손실에 미치는 영향 (Effect of Aspect Ratio of Flat Tube on R410A Evaporation Heat Transfer and Pressure Drop)

  • 김내현;이을종;변호원
    • 대한기계학회논문집B
    • /
    • 제37권4호
    • /
    • pp.395-404
    • /
    • 2013
  • 본 연구에서는 내경 5.0mm 원관을 납작하게 한 납작관에 대하여 R-410A를 사용하여 증발열전달 실험을 수행하였다. 실험은 포화온도를 $15^{\circ}C$로 고정한 상태에서 열유속을 $5{\sim}15kW/m^2$, 질량유속을 $200{\sim}400kg/m^2s$로 변화시키며 수행되었다. 실험결과 납작관의 종횡비가 증가할수록 열전달계수와 압력손실 모두 증가하였는데 특히 종횡비 4 인 경우 증가폭이 현저하였다. 납작관의 실험결과를 기존 상관식들과 비교한 결과 열전달계수는 Shah 상관식, 마찰계수는 Jung and Radermacher 상관식이 적절히 예측하였다.

해수 열원 및 폐열 이용 고성능 열펌프 시스템 모사 (Simulation for High Efficient Heat Pump System using Seawater Heat Source and Exhaust Energy)

  • 최광일;오종택;오후규
    • 설비공학논문집
    • /
    • 제15권1호
    • /
    • pp.59-66
    • /
    • 2003
  • The purpose of this study is to analyze the characteristics (COP) of the heat pump system for various operating conditions with the use of seawater heat source and exhaust energy. To accomplish the goal, first of all, the computer simulation for heat pump system is carried out. The heat pump system model is made of a waste heat recovery system and a vapor compression refrigeration system, and the working fluid is R-22. The model calculated the change of COP with the variation of temperature and flow rate. The COP and the plate heat exchanger (PHE) area of the heat pump system are considered moderately high in the condensation temperature of $25^{\circ}^C$ and the evaporation temperature of $2^{\circ}^C$ in indoor culture system. The simulation results will be used effectively for the design and the performance prediction of heat pump system using unused energy in a land base aquaculture system.

친환경 프레온 냉매를 이용하는 단압축 단팽창 냉동시스템의 성능예측 (Performance Analysis of Two-stage Compression and Two-stage Expansion Refrigeration System using Freon Refrigerants)

  • 노건상;김종열
    • 수산해양교육연구
    • /
    • 제25권2호
    • /
    • pp.301-306
    • /
    • 2013
  • In this paper, cycle performance analysis of two-stage compression and two-stage expansion refrigeration system using alternative freon refrigerants is presented to offer the basic design data for the operating parameters of the system. Alternative freon refrigerant for freon refrigerant R22 were used as working fluids in this study. The operating parameters considered in this study included evaporation temperature, condensation temperature, subcooling degree, superheating degree, and mass flow rate ratio of inter-cooler. The main results were summarized as follows : The COP of two-stage compression and two-stage expansion refrigeration system increases with the increasing subcooling degree and mass flow rate ratio of inter-cooler, but decreases with the increasing evaporating temperature, condensing temperature and superheating degree. Therefore, subcooling degree, mass flow rate ratio of inter-cooler of two-stage compression and two-stage expansion refrigeration system using alternative freon refrigerants have an effect on COP of this system.

R410A 냉매를 사용한 열펌프용 열교환기의 형상에 따른 성능특성 연구 (A Study on Performance Characteristics of Heat Exchanger for Heat Pump with R410A Refrigerant)

  • 정규하;박윤철;오상경
    • 설비공학논문집
    • /
    • 제16권4호
    • /
    • pp.340-348
    • /
    • 2004
  • The air and refrigerant side heat transfer performances are key parameters to improve heat transfer efficiency of the heat exchanger including the fan performance. Design of the fins, treatment of the tube inside, tube diameter and tube array effect heat transfer performance of the heat exchanger. The heat exchanger is used as a condenser at cooling mode and used as an evaporator at heating mode in the heat pump system. The heat pump system uses R410A as the refrigerant. The heat exchangers are consisted with 7 mm diameter tubes with slit-type fins. The study was conducted with variation of arrangement of the refrigerant path and air flow rate and refrigerant pressure drop and heat transfer rate were measured with a code tester. The capacity of the 3 path heat exchanger is more efficient than 2 or 4 path heat exchangers in heating or cooling modes.

실리콘과 카본을 이용한 다공질 탄화규소의 제조와 기계적 특성 (Fabrication and Mechanical Properties of Porous Silicon Carbide Ceramics from Silicon and Carbon Mixture)

  • 김종찬;이은주;김득중
    • 한국세라믹학회지
    • /
    • 제50권6호
    • /
    • pp.429-433
    • /
    • 2013
  • Silicon, carbon, and B4C powders were used as raw materials for the fabrication of porous SiC. ${\beta}$-SiC was synthesized at $1500^{\circ}C$ in an Ar atmosphere from a silicon and carbon mixture. The synthesized powders were pressed into disk shapes and then heated at $2100^{\circ}C$. ${\beta}$-SiC particles transformed to ${\alpha}$-SiC at over $1900^{\circ}C$, and rapid grain growth of ${\alpha}$-SiC subsequently occurred and a porous structure with elongated plate-type grains was formed. The mechanism of this rapid grain growth is thought to be an evaporation-condensation reaction. The mechanical properties of the fabricated porous SiC were investigated and discussed.