• Title/Summary/Keyword: Eutectic alloy

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The Effect of Sr Addition and Mold Preheating Temperature on the Solidification and Microstructure of Al-7wt%Si-0.3wt%Mg Alloy (Al-7wt%Si-0.3wt%Mg 합금의 응고 및 미세조직에 미치는 Sr 첨가와 금형예열온도의 영향)

  • Kwon, Il-Soo;Kim, Kyoung-Min;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.608-614
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    • 1997
  • The effect of mold preheating temperature on the microstructure such as grain size, eutectic silicon morphology was investigated for the Al-7wt%Si-0.3wt%Mg alloy. Microstructural variations have been characterized as a function of Sr addition and cooling rate during solidification. Microstructures were correlated with cooling rate, local solidification time and eutectic nucleation temperature, etc. In this study, Sr addition caused increase of local solidification time, undercooling and reduction of eutectic plateau temperature. In logarithmic scale, local solidification time was in inverse proportion to cooling rate. Eutectic nucleation temperature was in inverse proportion to cooling rate of logarithmic scale. Increasing the cooling rate refined dendrite arm spacing and eutectic silicon. Dendrite arm spacing was logarithmically in inverse proportion to cooling rate. Without modifier addition, eutectic silicon was modified at cooling rate of $7^{\circ}C/s$ or higher.

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Investigation on Age-hardening characteristic of thixo and rheocast by using Nano/Micro-probe Technology (나노/마이크로 프로브 기술을 통한 틱소/레오 캐스트의 시효경화 특성 조사)

  • Cho, S.H.;Lee, C.S.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.322-325
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    • 2006
  • The nano/microstructure and mechanical properties of the eutectic regions in thixo and rheo cast A356 alloy parts were investigated using nano/micro-indentation and mechanical scratching, combined with optical microscopy and atomic force microscope (AFM).Most eutectic Si crystals in the A356 alloy showed a modified morphology as fine-fibers, however Si particles of network in eutectic region was formed quickly with aging time increase in thixo-cast. The aging responses of the eutectic regions in both the thixo and rheo cast A356 alloys aged at $150^{\circ}C$ for different times (0, 2, 4, 8, 10, 16, 24, 36, and 72 h) were investigated. Both Vickers hardness ($H_V$) and indentation ($H_{IT}$) test results showed almost the same trend of aging curves, the peak was obtained at the same aging time of 10 h.

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The Effect of Sr Addition and Holding Time on Microstructure of Al-10.5%Si-2%Cu Secondary Die-casting Alloys (Al-10.5wt%Si-2wt%Cu 다이 캐스팅용 2차 지금의 미세조직에 미치는 Sr의 양과 유지시간의 영향 I)

  • Shin, Sang-Soo;Kim, Myung-Yong;Yeom, Gil-Yong
    • Journal of Korea Foundry Society
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    • v.30 no.5
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    • pp.161-166
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    • 2010
  • In this examination, the effect of Sr addition and holding time on microstructure of Al-10.5wt%Si-2wt%Cu secondary die-casting alloy was investigated. Degree of undercooling was improved with increasing the Sr content in this alloy. Up to 0.02wt%Sr addition, acicular and lamellar eutectic structure was observed in the microstructure. Meanwhile, the eutectic Si was modified toward the fine fibrous form by increasing Sr content with more than 0.03wt% and holding time of the melt. The well- modified alloys showed decreased eutectic silicon size from 3.25 ${\mu}m$ to less than 0.8 ${\mu}m$. From these results, the optimal strontium content and holding time were identified on the Al-10.5wt%Si-2wt%Cu secondary die-casting alloy.

Effect of Sc Addition on the Microstructure Modification of Al-6Si-2Cu Alloy (Sc 첨가에 따른 Al-6Si-2Cu 합금의 미세조직 개량화)

  • An, Seongbin;Kim, Chungseok
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.3
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    • pp.150-158
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    • 2022
  • The effects of scandium addition on the Al-6Si-2Cu Alloy were investigated. The Al-6Si-2Cu-Sc alloy was prepared by gravity die casting process. In this study, scandium was added at 0.2 wt%, 0.4 wt%, 0.8 wt%, and 1.0 wt%. The microstructure of Al-6Si-2Cu-Sc alloy was investigated using Optical Microscope, Field Emission Scanning Electron Microscope, Electron Back Scatter Diffraction, and Transmission Electron microscope. The microstructure of Al-6Si-2Cu alloy with scandium added changed from dendrite structure to equiaxed crystal structure in specimens of 0.4 wt% Sc or more, and coarse needle-shape eutectic Si and β-Al5FeSi phases were segmented and refined. The nanosized Al3Sc intermetallic compound was observed to be uniformly distributed in the modified Al matrix.

Influence of Minor Element on Microstructure and Mechanical Properties of TiFe Ultrafine Eutectic Alloys (TiFe 공정합금의 미소합금 첨가에 따른 미세구조 변화 및 기계적 물성)

  • Lee, Chan Ho;Jo, Jae Hyuk;Mun, Sang Chul;Kim, Jung Tae;Yeo, Eun Jin;Kim, Ki Buem
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.615-619
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    • 2012
  • Recently, ultrafine grained (ufg, typically 100 > d > 500 nm) Ti-Fe eutectic materials have been highlighted due to their extraordinarily high strength and good abrasion resistance compared to conventional coarse grained (cg, d > $1{\mu}m$) materials. However, these materials exhibit limited plastic strain and toughness during room temperature deformation due to highly localized shear strain. Several approaches have been extensively studied to overcome such drawbacks, such as the addition of minor elements (Sn, Nb, Co, etc.). In this paper, we have investigated the influence of the addition of Gd and Y contents (0.3-1.0 at.%) into the binary Ti-Fe eutectic alloy. Gd and Y are chosen due to their immiscibility with Ti. Microstructural investigation reveals that the Gd phase forms in the eutectic matrix and the Gd phase size increases with increasing Gd content. The improvement of the mechanical properties is possibly correlated to the precipitation hardening. On the other hand, in the case of Ti-Fe-Y alloys, with increasing Y contents, primary phases form and lamellar spacing increases compared to the case of the eutectic alloy. Investigation of the mechanical properties reveals that the plasticity of the Ti-Fe-Y alloys is gradually improved, without a reduction of strength. These results suggest that the enhancement of the mechanical properties is closely related to the formation of the primary phase.

Characterization of the Sn-Ag-Cu and Sn-Cu Lead-free Solder by adding P (P의 함량에 따른 Sn-Ag-Cu 및 Sn-Cu 무연솔더의 특성평가)

  • 신영의;황성진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.6
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    • pp.549-554
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    • 2003
  • The purpose of this paper is to investigate the solder properties by the change of P mass percentage. Tension test, wetting balance test, spread test, and analysis of intermetallic compound after isothermal aging of Sn-2.5Ag-0.7Cu-0.005P, Sn-2.5Ag-0.7Cu-0.01P, Sn-2.5Ag-0.7Cu-0.02P, Sn-0.7Cu-0.005P were performed. Adding P in the solder alloys resulted in improvement of tensile strength, reduction of intermetallic compound growth, reduction of oxidization in fusible solders under wave soldering. After comparing solder alloy containing P with tin-lead eutectic solder alloy, P contained solders alloys showed much better solder properties than eutectic solder alloy. Furthermore, this solder alloy presented remarkable properties than any other lead-free solder alloy.

Mechanical Behavior of A356 depending on the Variation of Microstructure (A356 합금 미세조직변화에 따른 기계적 특성에 관한 연구)

  • Kim K. J.;Kwon Y. N.;Lee Y. S.;Lee J. H.;Lee S. H.;Lee J. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.05a
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    • pp.273-276
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    • 2004
  • A356 alloy is one of the most popular casting aluminum alloys due to its good castability. It is well known that the mechanical properties of A356 alloy strongly depend on its characteristic microstructure, such as the size of eutectic Si, primary $\alpha$ dendrite and so on. These microstructural features are determined during the casting and solidification process, which implies the strong relationship with mechanical properties with solidification methods. In the present study, the mechanical characteristics of A356 alloy was investigated by using squeeze cast control arm in terms of the microstructural features, such as the size of eutectic Si, primary a dendrite. By doing so, the most favorable microstructure of A356 could be determined for Al control arm that should be one of the most reliable parts in automobile.

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Micro-macroscopic analysis on the directional casting of a metal alloy (합금의 방향성 주조에 대한 미시적-거시적 해석)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.10
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    • pp.1303-1313
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    • 1997
  • A micro-macroscopic analysis on the conduction-controlled directional casting of Al-Cu alloys is performed, in which emphases are placed on the microstructural features. In order to facilitate the solution procedure, an iterative micro-macroscopic coupling algorithm is developed. The predicted results show that the effect of finite back diffusion on the transient solidification process in comparison with the lever rule depends essentially on the initial concentration of an alloy. In the final casting, the eutectic fraction is distributed in an increasing-decreasing-increasing pattern, each mode of which is named the chill, interior and end zones. This nonuniformity per se suffices to justify the necessity of this work because it originates from the combined effects of finite back diffusion and cooling path-dependent nature of the eutectic formation. As the cooling rate is enhanced, not only the influence depths of boundaries narrow, but also the eutectic fractions in the chill and interior zones increase. In addition, it is revealed for the first time that the micro segregation band is formed in response to a sudden change in cooling rate during the directional casting. An increasing change creates an overshooting band in the eutectic fraction distribution, and vice versa.

A Study on the Relationship between Residual Stress and Wear Peroperty in Hypereutectic Al-Si Alloys (과공정 Al-Si 합금의 마모 특성에 미치는 잔류응력의 영향에 관한 연구)

  • Kim, Heon-Joo;Kim, Chang-Gyu
    • Journal of Korea Foundry Society
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    • v.20 no.2
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    • pp.89-96
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    • 2000
  • The effects of modification processing on the refinement of primary Si and the wear behavior of hyper-eutectic Al-Si alloys have been mainly investigated. Refining effects of primary Si in Al-17%Si alloy was more efficient than that of B.390 alloy. Optimum condition of getting the finest primary Si microstructure was when AlCuP modifier is added into the melt at $750^{\circ}C$ and held it at $700^{\circ}C$ for 30 minutes. Wear loss in the specimens of as-cast condition decreases as the size of primary Si decreases, in the order of B.390 alloy, B.390 alloy with AlCuP addition, Al-17%Si alloy and Al-17%Si alloy with AlCuP addition. Wear loss in the aged condition of Al-17%Si alloy, B.390 alloy and B.390 alloy with AlCuP addition decreased due to the increase of compressive residual stress in the matrix by the aging treatment. While, wear loss increased in the aged specimens of Al-17%Si alloy with AlCuP addition and Hepworth addition in which compressive residual stress decreases by the aging treatment. Therefore, it is assumed that higher compressive residual stress in the matrix can reduce the wear loss in composite materials such as hyper-eutectic Al-Si alloys.

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