• Asian Journal of Atmospheric Environment
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• 제2권1호
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• pp.34-46
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• 2008

Emissions inputs for use in air quality modeling of Korea were generated with the emissions inventory data from the National Institute of Environmental Research (NIER), maintained under the Clean Air Policy Support System (CAPSS) database. Source Classification Codes (SCC) in the Korea emissions inventory were adapted to use with the U.S. EPA's Sparse Matrix Operator Kernel Emissions (SMOKE) by finding the best-matching SMOKE default SCCs for the chemical speciation and temporal allocation. A set of 19 surrogate spatial allocation factors for South Korea were developed utilizing the Multi-scale Integrated Modeling System (MIMS) Spatial Allocator and Korean GIS databases. The mobile and area source emissions data, after temporal allocation, show typical sinusoidal diurnal variations with high peaks during daytime, while point source emissions show weak diurnal variations. The model-ready emissions are speciated for the carbon bond version 4 (CB-4) chemical mechanism. Volatile organic carbon (VOC) emissions from painting related industries in area source category significantly contribute to TOL (Toluene) and XYL (Xylene) emissions. ETH (Ethylene) emissions are largely contributed from point industrial incineration facilities and various mobile sources. On the other hand, a large portion of OLE (Olefin) emissions are speciated from mobile sources in addition to those contributed by the polypropylene industry in point source. It was found that FORM (Formaldehyde) is mostly emitted from petroleum industry and heavy duty diesel vehicles. Chemical speciation of PM2.5 emissions shows that PEC (primary fine elemental carbon) and POA (primary fine organic aerosol) are the most abundant species from diesel and gasoline vehicles. To reduce uncertainties in processing the Korea emission inventory due to the mapping of Korean SCCs to those of U.S., it would be practical to develop and use domestic source profiles for the top 10 SCCs for area and point sources and top 5 SCCs for on-road mobile sources when VOC emissions from the sources are more than 90% of the total.

• 설비공학논문집
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• 제19권8호
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• pp.607-614
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• 2007

This paper investigated that the functional group and chemical structure of additives affect ice adhesion in aqueous solutions cooling with stirring. In order to compare the effect on the ice adhesion in aqueous solutions, the functional group like carboxyl (-COOH), hydroxyl(-OH) or amine($-NH_{2}$) one were compared each other. Among the functional group, the strength of the hydrogen bonding force order is amine, hydroxyl and carboxyl one. It supports that ethylene diamine 7 mass% solution including amine group was effective to suppress the ice adhesion, though it is corrosive. Also, the ice adhesion were effectively resisted and formed lots of ice slurries in cooling experiment of 7 mass% solution of 1, 2-and 1, 3-propanediol which is different molecular structure but equal molecular weight each other.

• 한국안전학회지
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• 제27권4호
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• pp.26-32
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• 2012

With a progress of electrical and electronic technology, radio-frequency including high frequency components are widely to various industrial installations. Some of them are used in hazardous locations where explosive or flammable gases exist. As a result, ignition of such gases may be induced by a spark discharge when the radio frequency circuits are switched on or off. The purpose of this study is to investigate the ignition hazards of some kind of flammable mixtures based on the IEC 60079-11 publication. In this experiment, we used a high frequency resistive circuit which consists of a co-axial cable, a 20 ${\Omega}$, 30 ${\Omega}$, 40 ${\Omega}$ and 50 ${\Omega}$ resistor and two kind of power amplifier with frequency range up to almost 1 MHz and 50 MHz. Experimental results show that the ignition of the acetyleneair, ethylene-air mixtures and methane-air mixtures due to spark discharge depends primarily on the frequency of the power source in the resistive circuit the minimum ignition voltage increases gradually with the increase of the frequency.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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• pp.19-24
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• 2007

The deposition behavior of soot particles in a diffusion flame along a solid wall was examined experimentally by getting rid of the effect of natural convection utilizing microgravity environment. The microgravity environment was realized by using a drop tower facility. The fuel for the flame was an ethylene ($C_2H_4$) and the surrounding oxygen concentration 35% with the surrounding air velocity of $V_a$=2.5, 5, and 10 cm/s. Laser extinction method was adopted to measure the soot volume fraction distribution between the flame and burner wall. The results show that observation of soot deposition in normal flame was difficult from buoyancy and the relative position of flame and solid surface changes with time. The soot particle distribution region moves closer to the surface of the wall as the surrounding air velocity is increased. And the experiments determined the trace of the maximum soot concentration line. It was found that the distance between soot line and flame line is around 5 mm. That is, the soot particle near the flame zone tends to move away from flame zone because of thermophoretic force and to concentrate at a certain narrow area inside of the flame, finally, to adhere the solid wall.

• 대한기계학회논문집
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• 제18권10호
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• pp.2712-2723
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• 1994

Numerical simulation of an axisymmetric ethylene-air jet diffusion flame has been carried out in order to investigate flame dynamics and soot formation. The model solves the time-dependent Navier-Stokes equations and includes models for soot formation, chemical reaction, molecular diffusion, thermal conduction, and radiation. Numerically FCT(Flux Corrected Transport) and DOM(Discrete Ordinate Method) methos are used for convection and radiation trasport respectively. Simulation was conducted for a 5 cm/sec fuel jet flowing into a coflowing air stream. The maximum flame temperature was found to be approximately 2100 K, and was located at an axial position of approximately 5 cm from the base of the flame. The maximum soot volume fraction was about $7{\times}10^{-7}$, and was located within the high temperature region where the fuel mole fraction ranges from 0.01 to 0.1. The buoyancy-driven low-frequency(12~13 Hz) structures convected along the outer region of the flame were captured. In case without radiation trasport, the maximum temperature was higher by 150 K than in case with radiation. Also the maximum soot volume fraction reached about $8{\times}10^{-6}$. As the the hydrocarbon fuel forms many soot particles, the radiation transport becomes to play a more important role.

• 설비공학논문집
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• 제17권2호
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• pp.125-130
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• 2005

This study was peformed to investigate the phase change temperature, the supercooling, the maintenance time of liquid phase and the change rate of volume of TMA 30 $wt\% clathrate compound with additives. TMA 30 $wt\% clathrate compound with additive was cooled at heat source temperature of $-6^{circ}C$. The additives are ethylene glycol and chloroform. Their concentration are 0.1$wt\% respectively. The experimental results showed that the phase change temperature was not affected by additives and this was average $5.3^{circ}C$. Also the supercooling and the maintenance time of liquid phase were decreased by additives. Especially, the average value of supercooling showed by $8.8^{circ}C$ and the maintenance time of liquid phase was by 19 minutes in the case of chloroform 0.1$wt\%. Additionally, the average change rate of volume showed by $1.26{\~}1.31\%$ according to additives and the volume was decreased by the phase change from liquid to solid.

• 설비공학논문집
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• 제19권12호
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• pp.850-856
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• 2007

In a supercooled or capsule type ice storage system, aqueous solution (or water) may have trouble with non-uniform dissolution though the system contributes to the simplicity of system and ecological improvement. The non-uniform dissolution increases the instability of the system because it may cause an ice blockage in pipe or cooling part. In order to observe the supercooled state, a cooling experiment was performed with pressurization to an ethylene glycol(EG) 3 mass% solution in stationary state. Also, the effect of the pressurization from 101 to 505 kPa to the dissolution of supercooled aqueous solution was measured with the dissolution time of the supercooled aqueous solution at a fixed cooling rate of brine. At results, the dissolution of supercooled point decreased as the pressure of the aqueous solution in the vessel increased. Moreover, the dissolution point increased as the heat flux for cooling increased.

• Elastomers and Composites
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• 제37권1호
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• pp.49-56
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• 2002

UV 조사시간과 오존유량을 변화시키면서 폴리프로필렌을 UV/오존 산화하였으며 이의 표면특성을 접촉각과 XPS를 이용하여 살펴보았다. 산화된 표면의 노화거동을 공기, 물, 에틸렌 글리콜 하에서 살펴보았으며, 또한 lap shear 실험을 통하여 접착력을 관찰하였다. 극성표면 에너지와 접착력은 UV/오존 처리시간과 오존유량이 증가함에 따라 증가함을 알 수 있었다. 물에서 노화실험을 한 경우 극성표면 에너지의 변화가 없었으나, 공기 하에서 실시한 경우 2-3일 이내에 급격히 감소하여 처리하지 않은 폴리프로필렌의 값에 근접하였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 춘계학술발표대회
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• pp.34.2-34.2
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• 2009

The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

• 설비공학논문집
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• 제18권7호
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• pp.596-602
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• 2006

Ice adhesion and blockage problems have been issued in continuous ice slurry making process. So we composed continuous ice slurry making device using a commercial small plate heat exchanger (PHX), and investigated character of ice formation. An experiment of ice formation was peformed with an aqueous solution of ethylene glycol 7 mass%. In the experiment, the effect of the pressurization on ice slurry formation during the cooling process was investigated. The pressurization test for the aqueous solution was performed by setting valves at the PHX inlet and outlet. At the results, the time of continuous ice formation increased as the pressure of the plate heat exchanger increased for cooling temperature of $-5^{\circ}C$. Also continuous ice formation at the cooling temperature of $-7^{\circ}C$ showed a possibility. It was found that the pressurization may contribute to suppress the dissolution of supercooled aqueous solution in the PHX.