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Studies on the Elution Behavior and the Simultaneous Analysis of Some Metal-Dithiocarbamate Chelates by Reversed-Phase High Performance Liquid Chromatography (역상 액체 크로마토그래피에 의한 몇가지 금속-Dithiocarbamate 킬레이트의 용리거동 및 동시분석에 관한 연구)

  • Dai Woon Lee;Yun Je Kim;Hyun Chul Kim;Won Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.211-226
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    • 1988
  • Liquid chromatographic behavior of several metal ions in dithiocarbamate(DTC) chelates were investigated by reversed phase high performance liquid chromatography on Novapak $C_{18}$ and ${\mu}$-Bondapak $C_{18}$ columns. The optimum conditions for the separation of DTC-metal chelate were examined with respect to the pH, shaking time, flow rate, extraction solvent, and mobile phase strength. The metal ions in mixtures at trace level, chelated with some dithiocarbamate derivatives were separated successfully on Novapak $C_{18}$ column using acetonitrile/methanol/water or acetonitril/water mixtures as mobile phases. It was found that all DTC metal chelates studied were eluted in an acceptable range of capacity factor values ($0{\leqq}log\;k'{\leqq}1$). Although several foreign metal ions were coexisted, high recovery and good precision were attained ; 97.0-106.7 % for the recovery and 0.98-3.41% for the coefficient of variation. Under the optimum analytical conditions, trace metal ions in the composite water samples were determined sucessfully with in relative error of about {\pm}$6.7 %.

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Basic Research for Resistance Prediction of Aluminium Alloy Plate Girders Subjected to Patch Loading (패치로딩을 받는 알루미늄 합금 플레이트 거더의 강도 예측에 대한 기초 연구)

  • Oh, Young-Cheol;Bae, Dong-Gyun;Ko, Jae-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.2
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    • pp.218-227
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    • 2014
  • In this paper, it performed to the elastic-plastic large deflection series analysis using the experimental model and predicted a failure mode and ultimate strength. The collapse mode of numerical analysis model is formed a plastic hinge on loaded flange and consistent with the collapse mode of experimental model. Also, The yield line is formed in the web could observed that have occurred the crippling collapse mode and the ultimate loads of the experimental model and numerical analysis model have maintained linearly Means 1.07, Standard deviation 0.04, Coefficient of variation(COV) 0.04 and the result of ultimate loads have appeared approximately 8% error rate. it was found that very satisfied to the experimental results and the applied rules. if it is considered to be maintain a reasonable safety level, it is possible to predict the failure modes of aluminium alloy plate girders and ultimate loads.

Study on Improving Safety Cultures by Analysing Behavior Characteristics of Korean Seafarers (한국 선원의 행동특성 분석을 통한 안전문화 제고방안 연구)

  • Kim, Young-Mo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.5
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    • pp.503-510
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    • 2013
  • This study aims to propose safety culture design to ease to find out and control behavior characteristics of Korean seafarers. By empirical research of 377 Korean seafarers, the result revealed that significant characteristic of Korean seafarers was "affection to others" and custom of Confucianism affected Korean maritime society prevalently. But there were no significant differences between groups, such as rank, age, gender and sailing route with vessel type except educational background. Furthermore, this study concluded that positive reinforcement was more useful than negative reinforcement to promote safety operation of vessels. Regarding the vessel's safety management, the fact that means for vessel's safety management are linked only to the levels of educational background suggests that the efficiency of vessel's safety operation would be achieved by introducing suitable safety management system depending on the level of educational background.

A Two-Phase Pressure Drop Calculation Code Based on A New Method with a Correction Factor Obtained from an Assessment of Existing Correlations (기존 상관관계식들의 평가를 통해 얻은 수정계수를 사용하는 새로운 방법에 기초한 2상류 압력강하 계산코드)

  • Chun, Moon-Hyun;Oh, Jae-Guen
    • Nuclear Engineering and Technology
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    • v.21 no.2
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    • pp.73-88
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    • 1989
  • Ten methods of the total two-phase pressure drop prediction based on five existing models and correlations have been examined for their accuracy and applicability to pressurized water reactor conditions. These methods were tested against 209 experimental data of local and bulk boiling conditions : Each correlations were evaluated for different ranges of pressure, mass velocity and Quality, and best performing models were identified for each data subsets. A computer code entitled 'K-TWOPD' has been developed to calculate the total two-phase pressure drop using the best performing existing correlations for a specific property range and a correction factor to compensate for the predicted error of the selected correlations. Assessment of this code shows that the present method fits all the available data within $\pm$11% at a 95% confidence level compared with $\pm$25%, for the existing correlations.

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An Improved Calibration Method for the COCOMO II Post-Architecture Model

  • Yoon, Myoung-Young
    • Journal of Korea Society of Industrial Information Systems
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    • v.5 no.2
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    • pp.47-55
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    • 2000
  • To date many software engineering cost models have been developed to predict cost, schedule, and effort of the software under development. The COCOMO Ⅱ is well- suited for the new software development life cycle such as non-sequential and rapid- development processes. The traditional regression approach based on the least square criterion is the most commonly used technique for empirical calibration in the COCOMO Ⅱ model. It has a few assumptions frequently violated by software engineering data sets. The source data is also generally imprecise in reporting size effort, and cost-driver ratings, particularly across different organizations. And that the outlier for the source data is a peculiarity and indicates a data point. To cope with difficulties, in this paper, we propose a new regression method for calibrating COCOMO Ⅱ post-architecture model based on the minimum relative error(MRE) criterion. The characteristic of the proposed method is insensitive to the extreme values of the data in the empirical calibration. As the experimental results, It is evident that our proposed calibration method MRE was shown to be superior to the traditional regression approach for model calibration, as illustrated by the values obtained for standard deviation(^σ), and prediction at level LPRED(L) measures.

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Presumption Method for Optimum Correction Rate of Total Construction Cost Using the Median based on Historical Data Analysis in Public Office Buildings (공공건축물 실적자료 분석에 따른 중위수를 활용한 총공사비의 적정보정율 추정방법)

  • Yim, Jin-Ho;Park, Jun-Mo;Kim, Ok-Kyue
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.415-422
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    • 2014
  • There is growing difference between a planned value and an actual cost for increasing as an risk of construction cost. A construction cost index is an alternative to redeem a problem, but it is still very difficult to reduce an actual differential as a price fluctuation. Furthermore an existing theory of a construction cost index is overly complex, and is unsuitable for using in working-level. This study suggests an optimum correction rate in respect of a total construction cost. It is analyzing the actual cost of 53 public buildings that the Public Procurement Service ordered. The objects are main processes that include architectural works, mechanical works, electrical works, telecommunication works, and service facilities. It is compared a total construction cost based on absolute error rate using the median from frequentist principle. For this, it is selected the suitable regression model and set a correction rate.

Analysis of Dynamic Relationship between Changes in Domestic and Overseas Orders and Insolvency of Construction Companies (국내외 수주동향과 건설업체 부실화 간의 동태성 분석)

  • Jang, Sewoong
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.2
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    • pp.87-94
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    • 2014
  • This study aims to analyze the relationship. The study applies EDF (Expected Default Frequency) as a variable that indicates management status of a construction company. To analyze changes in business structure of construction companies, the study refers to the amounts of domestic and overseas project orders as variables. The data was retrieved from TS2000 established by Korea Listed Companies Association (KLCA), Statistics Korea and International Contractors Association of Korea. The analysis period is between first quarter of 2001 and fourth quarter of 2010. The analysis results showed that as more domestic and overseas orders rolled in for domestic companies, their business conditions improved as the hypothesis suggested. However, the level of improvement varied. Further, when construction companies' business slowed down, the proportion of overseas projects tended to rise, while the ratio of domestic business decreased.

A Measurement on Subscriber Line Characteristics in Service of Narrow Band ISDN in Korea (협대역ISDN서비스 제공을 위한 우리나라의 가입자 선로 특성 측정)

  • 성태경;진용옥
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.13 no.1
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    • pp.94-105
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    • 1988
  • In this paper, we deal with to survey a narrow band ISDN transmission capability through the local subscriber line in Korea. First, we disscuss international activity trends of technical references required for a narrow band ISDN services using existing pair cables. Second, we have measured transmission characteristics to send digital signals at 144kbps ratio through the local subscriber line With this result, we have found that 3.6% of measured lines are not availlable for a narow band ISDN channel, obtained a conclusion that the input level of U-transceiver should be more than -31dBm so as to assure the sufficient digital transmission quality. We also know that majority noise cased by transmission error are due to impulsive noise and near end crosstalk. Fianlly. as a result of the BER measruement, it is observed that, within 2.5km, more than 70% of measured cables are satisfied with the reference quality.

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Multiple-Symbol Differential Detection Scheme of Differentially Encoded MultiPhase Clipped MultiCode CDMA System (차동 부호화된 MultiPhase Clipped MultiCode CDMA 시스템의 수신 성능 개선을 위한 다중 심볼 차동 검출 방식 연구)

  • 이병하;안철용;김동구;조진웅
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.10A
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    • pp.807-815
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    • 2003
  • MultiCode-CDMA (MC-CDMA) system of chip level MPSK incorporating with clipper (MP-CDMA)[l] shows constant envelope signal which can mitigate the performance degradation due to nonlinear transmit amplifier. In this paper, modulation is modified to carry out differential encoded MPSK rather than MPSK. The modified system is called DMP-CDMA. DMP-CDMA using differential detection has advantages on receiver complexity and pilot overhead. However, it is inferior to coherent detection by about 4.0dB due to inherent power inefficiency of noncoherent detection and the error propagation. Multiple symbol differential detection is employed in order to improve DMP-CDMA using differential detection. As the result, the performance of DMP-CDMA system is improved about 3.6dB compared to differential detection.

Link Adaptation with SNR Offset for Wireless LAN Systems (무선 LAN 시스템에서의 SNR 오프셋을 이용한 링크 적응화)

  • Kim, Chan-Hong;Jeong, Kyo-Won;Ko, Kyeong-Jun;Lee, Jung-Woo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.10A
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    • pp.839-846
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    • 2011
  • Link Adaptation should select the best modulation and coding scheme (MCS) which gives the highest throughput as channel conditions vary. Several link adaptation algorithms for wireless local area network (WLAN) have been proposed but for the future WLAN systems such as 802.11n system, these algorithms do not guarantee the best performance. In this paper, we propose a new link adaptation algorithm in which an MCS level is chosen by the received SNR plus the offset value obtained from the transmission results. The performance of proposed algorithm is simulated by an IEEE 802.11n system. From the analysis, we conclude the proposed algorithm performs better than the well-known link adaptation algorithms such as auto rate fallback and general SNR-based techniques. Particularly, the proposed algorithm improves throughput when the packet error ratio (PER) is constrained for fast fading channels.