• 한국세라믹학회지
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• 제48권2호
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• pp.117-120
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• 2011

In this study, the redox state of iron in sodium silicate glasses was varied by changing the melting conditions, such as the melting temperature and particle size of iron oxide. The oxidation states of the iron ion were determined by wet chemical analysis and UV-Vis spectroscopy methods. Iron commonly exists as an equilibrium mixture of ferrous ions, $Fe^{2+}$, and ferric ions $Fe^{3+}$. In this study, sodium silicate glasses containing nanoparticles of iron oxide (0.5% mol) were prepared at various temperatures. Increase of temperature led to the transformation of ferric ions to ferrous ions, and the intensity of the ferrous peak in 1050 nm increased. Nanoparticle iron oxide caused fewer ferrous ions to be formed and the $\frac{Fe^{2+}}{Fe^{3+}}$ equilibrium ratio compared to that with micro-oxide iron powder was lower.

• 설비공학논문집
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• 제19권12호
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• pp.883-888
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• 2007

As a starting point of investigating what molecular dynamic simulations can reveal about the nature of atomic level of heating and cooling process, argon described by the LJ potential is considered. Stepwise heating and cooling of constant rates are simulated in the NPT (constant number, pressure and temperature) ensemble. Hysteresis is found due to the superheating and supercooling. Drastic change of volume and energy is involved with phase change, but the melting point can not be obtained by simply observing the changes of these quantities. Since liquid and solid phases can co-exist at the same temperature, Gibbs free energy should be calculated to find the temperature where the Gibbs free energy of liquid is equal to that of the solid since the equilibrium state is the state of minimum Gibbs free energy. The obtained melting temperature, $T^*=0.685$, is close to that of the experiment with only 2% error.

• Fibers and Polymers
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• 제1권2호
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• pp.76-82
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• 2000

A series of random copolyesters having various compositions were synthesized by bulk copolymerization of bishydroxyethyl terephthalate (BHET) with 1,4-cyclohexane dimethanol (CHDM) or dimethyl isophthalate (DMI). CHDM and DMI content was less than 10 wt%. For the synthesized copolyesters, isothermal crystallization rate, melting behavior, and equilibrium temperature were investigated by calorimetry and by Avrami and Hoffman-Weeks equation. Crystalline lattice and morphology were studied by WAXD and SEM. Regardless of the composition, the value of the Avrami exponent was about 3, which indicates that crystallization mechanism of the copolyester was similar to those of PET homopolymer. Incoporation of CHDM or DMI units in PET backbone decreased the crystallization rate of the copolyesters. Surface free energy of copolyesters was evaluated using the newly proposed equation. The value of surface free energy was about 189$\times$$10^{-6}$/$J^{2}$/$m^{4}$ regardless of comonomer contents. This result is in good agreement with that of PET homopolymer.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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• pp.167-171
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• 2006

The previous models for thermal behavior in the melting furnace were deterministic, composed of such a form that if the initial input conditions are determined, the results would have been come out by using the basic heat equilibrium equations. But making the experiment by trusting the analysis results, the melted slag is fortuitously set often, because temperature variation of the melted slag in the reaction process is not point function but path function. So in this study, a transient model was developed and verified by comparing with the experimental results.

• Macromolecular Research
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• 제14권2호
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• pp.146-154
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• 2006

Organic and inorganic hybrid nanocomposites based on poly(ethylene 2,6-naphthalate) (PEN) and silica nanoparticles were prepared by a melt blending process. In particular, polymer nanocomposites consisting mostly of cheap conventional polyesters with very small quantities of inorganic nanoparticles are of great interest from an industrial perspective. The crystallization behavior of PEN/silica hybrid nanocomposites depended significantly on silica content and crystallization temperature. The activation energy of crystallization for PEN/silica hybrid nanocomposites was decreased by incorporating a small quantity of silica nanoparticles. Double melting behavior was observed in PEN/silica hybrid nanocomposites, and the equilibrium melting temperature decreased with increasing silica content. The fold surface free energy of PEN/silica hybrid nanocomposites decreased with increasing silica content. The work of chain folding (q) for PEN was estimated as $7.28{\times}10^{-20}J$ per molecular chain fold, while the q values for the PEN/silica 0.9 hybrid nanocomposite was $3.71{\times}10^{-20}J$, implying that the incorporation of silica nanoparticles lowers the work required to fold the polymer chains.

• Journal of Welding and Joining
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• 제31권5호
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• pp.1-6
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• 2013

In carrying out the elastic-plastic analysis, four conditions (equilibrium equation, constitutive equation, condition of compatibility and yield condition) should be satisfied. In welding, the temperature largely changed from a melting temperature to a room temperature. So, yield stress of materials largely changed, too. In particular, yield stress becomes about zero over $700^{\circ}C$. The analysis should be carried out under the condition that equivalent stress generated in temperature increment ${\Delta}T$ did not exceed yield stress of materials at high temperature over $700^{\circ}C$. It should be sufficiently recognized that the obtained results were not reliable if this condition was not satisfied.

• 열처리공학회지
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• 제24권5호
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• pp.262-270
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• 2011

Carbide precipitation and dissolution behavior at various temperatures during heat treatment has been studied in STD11 cold working die steel through confocal scanning laser microscopy; dilatometry; and X-ray diffraction analysis. The equilibrium phase diagram and phase fractions with temperature were calculated using a FactSage program. Confocal laser microscopic observation revealed that ${\alpha}$ to ${\gamma}$ transformation temperature is near $800^{\circ}C$; M7C3 carbides melt at $1245^{\circ}C$; and the melting temperature of STD11 is near $1370^{\circ}C$. XRD results indicated that the M23C6 carbides dissolve in the matrix if austenitized at over $1030^{\circ}C$; while the M7C3 carbides remain up to $1200^{\circ}C$ although their amount decreases. The calculated equilibrium phase diagram showed good agreement with experimental results on carbide dissolution and phase transformation temperatures.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 춘계학술발표대회 개요집
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• pp.393-395
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• 2005

The bonding for Aluminum and Copper in the air is investigated in this study. This bonding method does not include the special process of removing aluminum oxide films. In case of this bending, each metal Is heated at bonding temperature where is above eutectic temperature of Al-Cu system and below melting point of Aluminum. The liquefaction around the bonding surface occurs after the diffusion at solid state of each metal. This phenomenon is predicted by the temperature range above eutectic temperature of Al-Cu equilibrium phase diagram.

• 대한금속재료학회지
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• 제48권8호
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• pp.765-774
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• 2010

Oxygen equilibrium and the solubility of MgO have been measured in the $CaO-Fe_tO-MgO-SiO_2({\leq}5mass%)-{\Sigma}M_xO_y$ slag in equilibrium with liquid iron in the temperature range of 1550 to $1700^{\circ}C$. The effect of oxides on the MgO solubility, and a method for calculating the solubility of MgO using slag composition and temperature,were discussed. The solubility of MgO is increased with increasing temperature and $Fe_tO$ content, and with decreasing basicity (C/S). The effect of ${\Sigma}M_xO_y$ on the solubility of MgO is a dilution effect due to the increase in slag volume. The activity and activity coefficient of $Fe_tO$ decreased with increasing basicity (B). The effect of temperature on the activity was negligible. The value of ${\rho}=Fe^{3+}/Fe^{2+}$ increased with the increase of the slag basicity (B") and the decrease of the $Fe_tO$ content in the slag.

• 한국가스학회지
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• 제27권3호
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• pp.35-40
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• 2023

과충전, 이상 온도 상승 등 이상 상황이 발생하는 조건에서 암모니아 용기의 파열 사고의 예방을 위해서는 용기에 부착된 가용전식 안전밸브의 작동 메카니즘 분석을 통한 사고 예방대책 마련이 필요하다. 본 연구에서는 가압 조건에서 암모니아 용기에 작용하는 응력 분석, 온도 변화에 따른 밀도 변화 분석, 그리고 용기 충전량과 온도 및 압력 변화에 대한 상관관계를 제시하였다. 또한, 암모니아 용기의 최대 충전량을 계산하고, 상평형 선도를 통해 해당 충전량에서의 온도·압력을 산출했다. 이를 바탕으로 가용전식 안전밸브의 적정 용융점을 도출하고 용융 온도 실험을 통해 이를 검증하였다. 이와 같은 연구 결과를 바탕으로 암모니아 용기 파열 사고의 예방을 위한 조건을 제시하였다.