• Title/Summary/Keyword: Equilibria

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A Study on the Solid-liquid Equilibria for Benzene+aniline, Benzene+nitrobenzene, p-xylene+cyclohexane (Benzene+aniline, benzene+nitrobenzene, p-xylene+cyclohexane계의 고액평형에 관한 연구)

  • Park, So-Jin;Paik, Seung-Kwan
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.864-869
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    • 1998
  • In this work, the solid-liquid equilibria (SLE) of some aromatic organic mixtures including benzene, widely used as an industrial solvent, were measured by static method using our own made experimental apparatus. The accuracy and reproducibility of apparatus were tested by comparing experimental results with literature values for 1-dodecanol+cyclohxane and benzene + p-xylene systems. The SLE for new binary systems of benzene+aniline, benzene+nitrobenzene, p-xylene+cyclohexane were measured afterwards and compared with the calculated values by modified UNIFAC(Dortmund) equation.

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A Study on Product Positioning based on Conjoint Analysis in a Competitive Market (경쟁시장에서 컨조인트분석에 기초한 제품포지셔닝에 대한 연구 : 온라인 게임을 중심으로)

  • Baek Seung-Kee;Rhim Ho-Sun;Park Myung-Sub
    • Journal of the Korean Operations Research and Management Science Society
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    • v.31 no.3
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    • pp.107-125
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    • 2006
  • We introduce a two-stage game theoretic model to support decision making processes for product Positioning and pricing in competitive environment. In the first stage, firms decide on entry and product position, in the second stage, firms compete with price. 'Alpha rule' is used as a choice model. Demand parameters of the choice model are estimated by conjoint analysis. We investigate conditions for the existence of Nash price equilibria in the pricing game. Nash equilibria in the entry and positioning game are produced using a concept of stable sets. An example of the online game industry in Korea is examined.

DYNAMIC BEHAVIOR OF A PREDATOR-PREY MODEL WITH STAGE STRUCTURE AND DISTRIBUTED DELAY

  • Zhou, Xueyong
    • Journal of applied mathematics & informatics
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    • v.28 no.1_2
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    • pp.193-207
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    • 2010
  • In this paper, a predator-prey model with stage structure and distributed delay is investigated. Mathematical analyses of the model equation with regard to boundedness of solutions, nature of equilibria, permanence, extinction and stability are performed. By the comparison theorem, a set of easily verifiable sufficient conditions are obtained for the global asymptotic stability of nonnegative equilibria of the model. Taking the product of the per-capita rate of predation and the rate of conversing prey into predator as the bifurcating parameter, we prove that there exists a threshold value beyond which the positive equilibrium bifurcates towards a periodic solution.

Equations of State for Hard-Sphere Chains: Effect of Attractive Contribution

  • Kim Jae-Jun
    • Macromolecular Research
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    • v.14 no.2
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    • pp.220-229
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    • 2006
  • Several equations of state for hard-sphere chains with various perturbation terms are reviewed. For each model, three characteristic parameters are required to represent phase equilibria of normal fluids and obtained from thermodynamic properties of pure saturated liquids. The models are then compared with computer simulation data to show the effect of attractive contribution forms employed. Calculated values of vapor-liquid equilibria (VLE) of hydrocarbons that can be reproduced for each model are also compared with experimental results. An additional parameter, ${\zeta}_{KB}$, is required to represent the VLE of pure water, which is ascertained to have a strong influence on the theoretical coexistence curve.

Bimatrix Game Approach to Power System Market Analysis (전력거래에서의 내쉬균형점 해석을 위한 Bimatrix 게임 기법 연구)

  • Lee, Kwang-Ho
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.380-382
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    • 2002
  • An important aspect of the study of power system markets involves the assessment of strategic behavior of participants for maximizing their profits. In models of imperfect competition of a deregulated electricity system the key task is to find the Nash equilibrium. In this paper, the bimatrix approach for finding Nash equilibria in electricity markets is investigated. This approach determines pure and mixed equilibria using the complementarity pivot algorithm. The mixed equilibrium in the matrix approach has the equal number of non-zero property. This property makes it difficult to reproduce a smooth continuous distribution for the mixed equilibrium. This paper proposes an algorithm for adjusting the quantization value of discretization to reconstruct a continuous distribution from a discrete one.

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Polymker Adsorption Model Using the Flory-Huggins Equation and Asdsorption of Starch (Flory-Huggins 식을 이용한 고분자 흡착 모델 및 전분의 흡착)

  • 현상훈;정한남
    • Journal of the Korean Ceramic Society
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    • v.23 no.3
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    • pp.35-43
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    • 1986
  • The equilibrium dsorption of starch on activated alumina and kaolin was studied to provide the fundamental data for investigating the effect of polymer adsorption on the flocculation of solid particles. The new polymer adsor-ption model(PAH-FH) predicting the adsorption equilibria of polymers on the solid surface has been developed using the solution theory and the concepts of Gibbs dividing surface in conjunction with the Flory-Huggins eq-uation and the adsorption behaviors of polymers were examined by this model The accurate adsorption equilibrium data of starch on alumina and kaolin were determined within the tempera-ture range of 298-318K by the ignition loss method. Using these experimenta data the model developed in this study was evaluated. It was shown that this model could predict the adsorption isotherm more accura-tely than the Langmuir model as well as could describe the characteristics of the adsorption equilibria through model parameters.

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Electrochemical behaviors of Indium

  • Chung, Yong-Hwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.1-13
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    • 2012
  • Many researchers focus on indium contained semiconductors and alloy compounds for their various applications. Electrochemists want to obtain indium contained compounds simply via one-step electrodeposition. First of all, electrochemistry of constituent elements must be understood in order to develop the best condition for the electrodeposition of indium contained compounds. We will review the electrochemistry of indium. Equilibria between indium metal and indium ions and the standard electrode potentials of the equilibria will be reviewed. The electrochemical reactions of indium species are affected by surrounding conditions. Thus dependences of electrochemical behaviors of indium metal and indium ions on various parameters will be reviewed.

THE DYNAMICS OF POSITIVE SOLUTIONS OF A HIGHER ORDER FRACTIONAL DIFFERENCE EQUATION WITH ARBITRARY POWERS

  • GUMUS, MEHMET;SOYKAN, YUKSEL
    • Journal of applied mathematics & informatics
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    • v.35 no.3_4
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    • pp.267-276
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    • 2017
  • The purpose of this paper is to investigate the local asymptotic stability of equilibria, the periodic nature of solutions, the existence of unbounded solutions and the global behavior of solutions of the fractional difference equation $$x_{n+1}=\frac{^{{\alpha}x}n-1(k+1)}{{\beta}+{\gamma}x^p_{n-k}x^q_{n-(k+2)}}$$, $$n=0,1,{\dots}$$ where the parameters ${\alpha}$, ${\beta}$, ${\gamma}$, p, q are non-negative numbers and the initial values $x_{-(k+2)}$,$x_{-(k+1)}$, ${\dots}$, $x_{-1}$, $x_0{\in}\mathb{R}^+$.

Solidification and Phase Equilibria Studies by Directional Solidification Technique in the Ni-Al System (Ni-Al계에서 일방향응고에 의한 응고 및 상평형 연구)

  • Lee, Jae-Hyeon;Jo, Chang-Yong;Lee, Jong-Hun;Choe, Seung-Ju
    • 연구논문집
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    • s.25
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    • pp.163-168
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    • 1995
  • The intermetallic compound $Ni_3Al$ causes a peritectic reaction at the composition and temperature very close to the eutectic reaction in Ni-Al system. Although the phase diagram accepted for this system by ASM Handbook has the eutectic forming between the $\gamma$ and $\gamma$ phases, directional solidification study has shown that the eutectic occurs between $\beta$ and $\gamma$. This work examines the liquidus region using quenched, directional solidification experiments that preserve the microstructrues formed at the solidification front. It is also shown that under certain composition and growth conditions a metastable eutectic between the $\beta$ and $\gamma$ phases forms in this system. Finding of the metastable eutectic provided an important information to understand the phase equilibria near the $Ni_3Al$ composition.

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A Study on the Recovery of Acetonitrile in the Process of Manufacturing Acrylonitrile (아크릴로니트릴 제조공정에서 아세토니트릴 회수에 관한 연구)

  • 박동원;최성욱;김영일
    • Resources Recycling
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    • v.8 no.3
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    • pp.31-36
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    • 1999
  • In the process of manufacturing acrylonitrile, azeotrope of water-acetonitrile is formed as by-product. To1uene-ethylacetate mixture was selected as solvent to determine the liquid-liquid equilibria for to1uene(l)-water(2)-acetomtrile(3)-ethyjacetate(4) system. The experimental he-line data were correlated with the UNIFAC model. The distribution and selectivity for quaternary system was also studied.

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