• Title/Summary/Keyword: Equation of State

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Isothermal Vapor-liquid Equilibria for the Binary Mixtures of 3-Methylpentane with Ethylene Glycol Monopropyl Ether and Ethylene Glycol Isopropyl Ether (3-메틸펜테인과 에틸렌 글리콜 모노프로필 에테르 및 에틸렌 글리콜 아이소프로필 에테르 혼합물에 대한 2성분계 등온 기-액 상 평형)

  • Hyeong, Seonghoon;Jang, Sunghyun;Kim, Hwayong
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.302-308
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    • 2015
  • Isothermal vapor liquid equilibria for the binary system of 3-methylpentane with ethylene glycol monopropyl ether ($C_3E_1$) and ethylene glycol isopropyl ether ($iC_3E_1$) were measured at 303.15, 318.15, and 333.15K. In our previous work, phase equilibria for the binary system of $C_3E_1$ mixtures were investigated according to the chain length of alkane, alcohol or those isomer. But in this study, we discussed the different effect of $C_3E_1$ and its isomer, $iC_3E_1$, on the phase equilibria. The measured systems were correlated with a Peng-Robinson equation of state (PR EOS) combined with Wong-Sandler mixing rule for the vapor phase, and NRTL, UNIQUAC, and Wilson activity coefficient models for the liquid phase. All the measured systems showed good agreement with the correlation results. And it was found that the phase equilibria showed very little difference between the $iC_3E_1$ mixture system and the $C_3E_1$ mixture system.

Simulation Analysis of Sludge Disposal and Volatile Fatty Acids Production from Gravity Pressure Reactor via Wet Air Oxidation (습식산화반응을 통한 중력식반응기로부터의 슬러지 처리 및 유기산 생산 공정모사)

  • Park, Gwon Woo;Seo, Tae Wan;Lee, Hong-Cheol;Hwang, In-Ju
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.248-254
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    • 2016
  • Efficacious wastewater treatment is essential for increasing sewage sludge volume and implementing strict environmental regulations. The operation cost of sludge treatment amounts up to 50% of the total costs for wastewater treatment plants, therefore, an economical sludge destruction method is crucially needed. Amid several destruction methods, wet air oxidation (WAO) can efficiently treat wastewater containing organic pollutants. It can be used not only for sludge destruction but also for useful by-product production. Volatile fatty acids (VFAs), one of many byproducts, is considered to be an important precursor of biofuel and chemical materials. Its high reaction condition has instituted the study of gravity pressure reactor (GPR) for an economical process of WAO to reduce operation cost. Simulation of subcritical condition was conducted using Aspen Plus with predictive Soave-Redlich-Kwong (PSRK) equation of state. Conjointly, simulation analysis for GPR depth, oxidizer type, sludge flow rate and oxidizer injection position was carried out. At GPR depth of 1000m and flow rate of 2 ton/h, the conversion and yield of VFAs were 92.02% and 0.17g/g, respectively.

Seismic Reliability Analysis of Offshore Wind Turbine with Twisted Tripod Support using Subset Simulation Method (부분집합 시뮬레이션 방법을 이용한 꼬인 삼각대 지지구조를 갖는 해상풍력발전기의 지진 신뢰성 해석)

  • Park, Kwang-Yeun;Park, Wonsuk
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.32 no.2
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    • pp.125-132
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    • 2019
  • This paper presents a seismic reliability analysis method for an offshore wind turbine with a twisted tripod support structure under earthquake loading. A three dimensional dynamic finite element model is proposed to consider the nonlinearity of the ground-pile interactions and the geometrical characteristics of the twisted tripod support structure where out-of-plane displacement occurs even under in-plane lateral loadings. For the evaluation of seismic reliability, the failure probability was calculated for the maximum horizontal displacement of the pile head, which is calculated from time history analysis using artificial earthquakes for the design return periods. The application of the subset simulation method using the Markov Chain Monte Carlo(MCMC) sampling is proposed for efficient reliability analysis considering the limit state equation evaluation by the nonlinear time history analysis. The proposed method can be applied to the reliability evaluation and design criteria development of the offshore wind turbine with twisted tripod support structure in which two dimensional models and static analysis can not produce accurate results.

Effects of AR Tourguide Application on Tourist Flow, Experiences, and Usage Intention (증강현실 관광 가이드 앱의 속성이 관광객의 몰입, 경험, 이용의도에 미치는 영향)

  • Kim, Eun-Joung;Song, Ni-Eun
    • The Journal of the Korea Contents Association
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    • v.22 no.2
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    • pp.487-500
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    • 2022
  • This study aims to examine visitors' usage intention of the mobile AR(Augmented reality) application for tourism in Korea. For this purpose, the study analyzed how three attributes of AR tourguide app such as interactivity, vividness, and novelty have influenced on the tourist in terms of three realms of their flow, their experience (education, entertainment, esthetics, and escapism), and their usage intention for the future. It conducted an online survey from 20 to 30 year-old 291 participants and used a structural equation modeling. Survey findings show that first, novelty has a positive influence on the state of flow in AR application after vividness; Interactivity does not any significant effect on the tourists' flow. Second, when tourists explore the flow in the AR tourguide app, it affects all realms of experience economy of education, entertainment, esthetics, and escapism. Third, when using AR tour guide app in the context of historical heritage site, the two dimensions of entertainment and education influence the usage intention but the other two of esthetics and escapism does not. This study has presented a theoretical contribution that it focuses on historical sites as one type of tourist attractions and suggests a new modeling integrating AR attributes, flow, experience, and usage intention. In addition, it can be used to become a practical reference for revising an user-oriented AR application and customer-tailored AR tourism.

Assessment of MODIS Leaf Area Index (LAI) Influence on the Penman-Monteith Evapotranspiration of SLURP Model (MODIS 위성영상으로부터 추출된 엽면적지수(LAI)가 SLURP 모형의 Penman-Monteith 증발산량에 미치는 영향 평가)

  • HA, Rim;SHIN, Hyung-Jin;Park, Geun-Ae;KIM, Seong-Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5B
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    • pp.495-504
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    • 2008
  • Evapotranspiration (ET) is an important state variable while simulating daily streamflow in hydrological models. In the estimation of ET, for example, when using FAO Penman Monteith equation, the LAI (Leaf Area Index) value reflecting the conditions of vegetation generally affects considerably. Recently in evaluating the vegetation condition as a fixed quantity, the remotely sensed LAI from MODIS satellite data is available, and the time series values of spatial LAI coupled with land use classes are utilized for ET evaluation. Four years (2001-2004) of MODIS LAI was prepared for the evaluation of Penman Monteith ET in the continuous hydrological model, SLURP (Semi-distributed Land Use-based Runoff Processes). The model was applied for simulating the dam inflow of Chungju watershed ($6661.3km^2$) located in the upstream of Han river basin. For four years (2001-2004) dam inflow data and meteorological data, the model was calibrated and verified using MODIS LAI data. The average Nash-Sutcliffe model efficiency was 0.66. The 4 years watershed average Penman Monteith ETs of deciduous, coniferous, and mixed forest were 639.1, 422.4, and 631.6 mm for average MODIS LAI values of 3.64, 3.50, and 3.63 respectively.

High Gain Observer-based Robust Tracking Control of LIM for High Performance Automatic Picking System (고성능 자동피킹 시스템을 위한 선형 유도 모터의 고이득 관측기 기반의 강인 추종 제어)

  • Choi, Jung-Hyun;Kim, Jung-Su;Kim, Sanghoon;Yoo, Dong Sang;Kim, Kyeong-Hwa
    • Journal of the Korean Institute of Intelligent Systems
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    • v.25 no.1
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    • pp.7-14
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    • 2015
  • To implement an automatic picking system (APS) in distribution center with high precision and high dynamics, this paper presents a high gain observer-based robust speed controller design for a linear induction motor (LIM) drive. The force disturbance as well as the mechanical parameter variations such as the mass and friction coefficient gives a direct influence on the speed control performance of APS. To guarantee a robust control performance, the system uncertainty caused by the force disturbance and mechanical parameter variations is estimated through a high gain disturbance observer and compensated by a feedforward manner. While a time-varying disturbance due to the mass variation can not be effectively compensated by using the conventional disturbance observer, the proposed scheme shows a robust performance in the presence of such uncertainty. A Simulink library has been developed for the LIM model from the state equation. Through comparative simulations based on Matlab - Simulink, it is proved that the proposed scheme has a robust control nature and is most suitable for APS.

Analysis of Photoluminescence of Eu3+ in YOBr and Investigation of Critical Distance (YOBr:Eu3+ 형광체의 발광특성과 임계거리 연구)

  • Kim, Gyeong Hwa;Park, Jong Gyu;Park, Hui Dong;Han, Jeong Hwa
    • Journal of the Korean Chemical Society
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    • v.45 no.6
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    • pp.570-576
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    • 2001
  • The europium doped yttrium oxybromide phosphors were synthesized by solid-state reaction method. The YOBr: $Eu^{3+}$ phosphor showed a strong and narrow red emission band at 621 nm and maximum emission intensity obtained when 0.05 mol Eu ions were doped. The red emission of $Eu^{3+}$ originated from $^5D_0$ ${\rightarrow}$ $^7F_2$electric dipole transition. In order to investigate on photoluminescence behavior, several experimental skills and numerical fittings are conducted to the YOBr: $Eu^{3+}$ phosphor. The emission spectrum was measured in the UV range and then decay curve of $^5D_0$ ${\rightarrow}$ $^7F_j$transitions was examined. The energy interaction type of YOBr: $Eu^{3+}$ phosphor was dipole-dipole interaction. In addition to the calculating by critical concentration, the critical distance ($R_0$) was calculated by decay curve fitting parameter from Inokuti-Hirayamas equation, and spectral overlap method. The critical distance was 17.03, 10.51 and 7.18$\AA$ for those methods, respectively. As considering systematic error of measurements, these values are within the same order, so that the above fitting methods are plausible and recommendable.

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The Thickness Effect on the Determination of Fracture Toughness Jic (파괴인성치 Jic 결정에 대한 시험편 두께의 영향에 관한 연구)

  • 고성위
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.24 no.2
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    • pp.83-93
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    • 1988
  • Recent Experimental results show that the J integral can be effectively used to obtain a valid parameter for predicting plane strain and plane stress fracture. However, only a few research results have been reported for the effect of thickness where the plane strain state can not be assumed. A purpose of this study is to find the behavior of fracture touhness and tearing modulus varing the specimen thickness. The type of specimen in the present study is compact tension (CT). The thicknesses of the low carbon steel specimens that are used in the experiments are 5, 10, 15, 20 and 25mm. The measurement of crack length is taken by optical measurements method. From the study, the followings are found; 1) The fracture toughness and the tearing modulus which are obtained by using Yoon's and Simpson's formula show more conservative than that by using Rice's and Merkel's. 2) The fracture toughness is increase in specimen thickness which is reached 15mm. Beyond this thickness the fracture toughness is decreased in specimen thickness. 3) In the case of CT specimen with the thickness ranging from 5 to 25mm, the tearing modulus which is applied the same J integral equation is almost constant. 4) By using Yoon's formula, the correlation of the plane slress fracture toughness J sub(C) with specimen thickness B is expressed as the following formula. J sub(C)/J sub(IC)=1.7-15.1(B/W)+112.9(B/W) super(2) -301.3(B/W) super(3) +260.6(B/W) super(4)

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Numerical Investigation on Seepage Stability in Offshore Bucket Cut-off Walls (수치해석을 이용한 대형원형강재 가물막이의 침투 안정성 분석)

  • Ssenyondo, Vicent;Tran, Van An;Kim, Sung-Ryul
    • Journal of the Korean Geotechnical Society
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    • v.33 no.11
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    • pp.73-82
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    • 2017
  • Recently, offshore bucket cut-off walls were developed to solve several problems in conventional offshore cut-off walls. In this study, a numerical analysis was carried out to investigate the seepage stability of offshore bucket cut-off walls. The ground was assumed as uniform homogeneous sand and steady state flow conditions were applied. The flow condition was compared among 2-dimensional flow (2-D), 2-dimensional concentrated flow (2-DC), and axisymmetric flow. The analysis results showed that the seepage velocities in axisymmetric flow were about 1.5 and 2 times larger than those of 2-DC and 2-D flow conditions, respectively. Thereafter, the axisymmetric flow condition was applied because the seepage flow was concentrated toward the center of the circular-shaped wall. A parametric study was performed varying bucket radius, penetration depth, total head difference between in and outside of the wall. The exit gradient, which used for the calculation of piping stability, decreased with increase of the penetration depth and bucket radius. Design charts were proposed to estimate the factor of safety and the exit gradient at various analysis conditions. Finally, the design equation was proposed to calculate the exit gradient for the preliminary design of the bucket cut-off wall.

A Study on the Current State of the Library's AI Service and the Service Provision Plan (도서관의 인공지능(AI) 서비스 현황 및 서비스 제공 방안에 관한 연구)

  • Kwak, Woojung;Noh, Younghee
    • Journal of Korean Library and Information Science Society
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    • v.52 no.1
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    • pp.155-178
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    • 2021
  • In the era of the 4th industrial revolution, public libraries need a strategy for promoting intelligent library services in order to actively respond to changes in the external environment such as artificial intelligence. Therefore, in this study, based on the concept of artificial intelligence and analysis of domestic and foreign artificial intelligence related trends, policies, and cases, we proposed the future direction of introduction and development of artificial intelligence services in the library. Currently, the library operates a reference information service that automatically provides answers through the introduction of artificial intelligence technologies such as deep learning and natural language processing, and develops a big data-based AI book recommendation and automatic book inspection system to increase business utilization and provide customized services for users. Has been provided. In the field of companies and industries, regardless of domestic and overseas, we are developing and servicing technologies based on autonomous driving using artificial intelligence, personal customization, etc., and providing optimal results by self-learning information using deep learning. It is developed in the form of an equation. Accordingly, in the future, libraries will utilize artificial intelligence to recommend personalized books based on the user's usage records, recommend reading and culture programs, and introduce real-time delivery services through transport methods such as autonomous drones and cars in the case of book delivery service. Service development should be promoted.