• 한국가스학회지
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• 제13권4호
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• pp.15-21
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• 2009

섬유강화 복합재료는 비강성과 비강도등의 우수한 기계적 성질을 나타내므로 구조물의 경량화가 요구되는 여러 산업분야에서 널리 사용되고 있다. 이러한 복합재를 이용한 압력용기는 무게를 경량화함으로써 에너지를 절약할 수 있고 강한 내식성을 가지고 있기 때문에 장기간 사용에 유리하다. 본 연구에서는 유한요소법과 ANSYS 반응표면법을 이용하여 안정성 판단의 기준으로 Von-mises 항복 기준, Tasi-hill이론, 응력비를 만족시킬 수 있는 E-glass/epoxy로 필라멘트 와인딩된 CNG차량복합재 압력용기 적층판의 최적설계 모듈을 개발하였다.

• Restorative Dentistry and Endodontics
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• 제26권4호
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• pp.316-325
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• 2001

The purpose of this study was to evaluate the effect of adhesive curing timing on the direction of polymerization shrinkage of light-curing composite resin. In this study, the curing times of adhesive and composite resin were measured by differential scanning calorimeter(DSC). 28 extracted human molars were embedded in clear resin and box-type cavities were prepared. Based on DSC data, the experimental teeth were divided into 4 groups. Group 1: no bond; Group 2: late curing; Group 3: Intermediate curing; Group 4: Early curing. After treating with adhesive, the buccal cavities were filled with Z-100 hybrid composite resin and the lingual ones were filled with AEliteflo flowable composite resin. The depressions at the surface were measured by surface profilometer, then the specimens were embedded in clear resin and sectioned. Impressions were obtained and used to get epoxy resin replicas. The epoxy replicas were gold-coated and observed under SEM. Average Maximum Gap(AMG), Gap Proportion(GP), Average Marginal Index(AMI) were used to compare the shrinkage gap of each group. The results were statistically analyzed using the Kruskal-Wallis One Way ANOVA, Student-Newman-Keuls method. The results of this study were as follows. 1. Average Maximum Gap, Gap Proportion, Average Marginal Index and depression at the surface or Z-100 hybride composite resin were smaller than those of AEliteflo flowable composite resin(P<0.05). 2. When the bonding between composite resin and tooth structure was strong, the shrinkage gap was small, and depression at the surface was deep(P<0.05). 3. In the well-bonded group, light-curing composite resin shrank toward bonded cavity wall, not toward light source. The result suggested that the direction of polymerization shrinkage was affected by the quality of bonding in the dentin-resin interface. The strong was the bonding between composite resin and tooth structure, the smaller was the gap and the deeper was the depression at the surface. Then the flow to compensate the polymerization shrinkage proceeded from surface to bonded cavity wall.

• Advanced Composite Materials
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• 제18권3호
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• pp.251-264
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• 2009

Nonlinear mechanical behaviors of unidirectional carbon fiber-reinforced plastic (CFRP) laminates using cup-stacked carbon nanotubes (CSCNTs) dispersed epoxy are evaluated and compared with those of CFRP laminates without CSCNTs. Off-axis compression tests are performed to obtain the stress-strain relations. One-parameter plasticity model is applied to characterize the nonlinear response of unidirectional laminates, and nonlinear behaviors of laminates with and without CSCNTs are compared. Clear improvement in stiffness of off-axis specimens by using CSCNTs is demonstrated, which is considered to contribute the enhancement of the longitudinal compressive strength of unidirectional laminates and compressive strength of multidirectional laminates. Finally, longitudinal compressive strengths are predicted based on a kink band model including the nonlinear responses in order to demonstrate the improvement in longitudinal strength of CFRP by dispersing CSCNTs.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.265-268
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• 2002

In this work, the blend system of epoxy and PMR-15 polyimide is investigated in terms of the cure behaviors and thermal stabilities. The cure behaviors are studied in DSC measurements and thermal stabilities are also carried out by TGA analysis. DDM (4, 4'-diamino diphenyl methane) is used as curing agent for EP and the content of PMR-15 is varied within 0, 5, 10, 35, and 20 phr to neat EP. As a result, the cure activation energy ($E_a$) is increased at 10 phr of PMR-15, compared with that of neat EP. From the TGA results of EP/PMR-15 blend system, the thermal stabilities based in the initial decomposed temperature (IDT) and integral procedural decomposition temperature (IPDT) are increased with increasing the PMR-15 content. The fracture toughness, measured in the context of critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$), shows a similar behavior with $E_a$. This result is probably due to the crosslinking developed by the interactions between intermolecules in the polymer chains.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 1999년도 추계학술발표대회 논문집
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• pp.73-76
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• 1999

Near infrared spectroscopy techniques were used to study the cure reactions of epoxy resin system based on diglycidyl ether of bisphenol A(DGEBA) resins cured with 4, 4' diaminodiphenyl sulfone (DDS) hardner. Stoichiometric DGEBA/DDS resin formulation was involved in this study. The infrared absorption spectra of the prepared formulation were obtained on an FTIR spectrometer operating in the region of 11000 to 4000$cm^{-l}$. The chemical group peaks of interest in a DFEBA/DDS spectrum were identified by a comparative study with individual spectra of DGEBA and DDS monomers. Where necessary, special model compounds were used to identify unknown bands, such as the primary amine band at 4535$cm^{-l}$. The absorption bands of interest were integrated to quantify the areas and then converted to molar concentrations. This series of quantitative analyses of the major chemical groups led us to understand not only the reaction mechanism but also the cure kinetics. In this paper, the reaction mechanisms observed in stoichiometric DGEBA/DDS resin formulation and the various properties of the resin system as a function of cure temperature are described.

• 대한기계학회논문집
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• 제17권10호
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• pp.2475-2482
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• 1993

The effects of the hole size(2R) and the specimen width(W) on the fatigue strength and the fatigue life in plain woven glass/epoxy composite plates are experimentally investigated under constant amplitude tensile fatigue loading. It is shown in this study that the notch sensitivity under fatigue loading is lower than that under static loading. It can be explained by the fact that the stress concentration is relaxed by the damage developed at the boundary of circular hole. To predict the fatigue strength at a specific cycle, the modified point stress criterion represented as a function of the geometry of the specimen(2R and W) is applied. It is found that the model used in the prediction of the notched tensile strength predicts the fatigue strength with reasonable accuracy. A model for predicting the fatigue life in the notched specimen, based on the S-$N_f$, curve in the smooth specimen, is suggested.

• 한국분말재료학회지
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• 제25권4호
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• pp.291-295
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• 2018

A conductive additive is prepared by dispersing multi-walled carbon nanotubes (MWCNTs) on Cu powder by mechanical milling and is distributed in epoxy to enhance its electrical conductivity. During milling, the MWCNTs are dispersed and partially embedded on the surface of the Cu powder to provide electrically conductive pathways within the epoxy-based composite. The degree of dispersion of the MWCNTs is controlled by varying the milling medium and the milling time. The MWCNTs are found to be more homogeneously dispersed when solvents (particularly, non-polar solvent, i.e., NMP) are used. MWCNTs gradually disperse on the surface of Cu powder because of the plastic deformation of the ductile Cu powder. However, long-time milling is found to destroy the molecular structure of MWCNTs, instead of effectively dispersing the MWCNTs more uniformly. Thus, the epoxy composite film fabricated in this study exhibits a higher electrical conductivity than 1.1 S/cm.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.81-84
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• 2002

An approach for predicting the effective thermal conductivities of fiber-reinforce composite has been developed based on a thermal-electrical analogy. The unit cell of the composite laminate is divided into regular volume elements and the material properties have been given to each element. By constructing the series-parallel thermal resistance network, the thermal conductivities of composite both in-plane and out-of-plane direction have been predicted. Graphite/Epoxy composite is used for a balanced plain-weave composite laminate. By comparing the predicted results and the previous works, good agreement has been found.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.99-99
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• 2010

Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

• Transactions on Electrical and Electronic Materials
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• 제12권4호
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• pp.160-163
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• 2011

Polymer nanocomposite has been attracting more attention as a new insulation material because homogeneous dispersion of nano-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy-based nanocomposites were made, and the AC breakdown strengths of Nano filler and micro-$SiO_2$ filler mixtures of epoxy-based composites were analyzed using sphere-to-sphere electrodes. Moreover, nano- and microfiller combinations were investigated as an approach to practical application of nanocomposite insulation materials. Its composition ratio was 100 (resin):82 (hardener):1.5 (accelerator). AC breakdown tests were performed at room temperature ($25^{\circ}C$), $80^{\circ}C$, and $100^{\circ}C$ in the vicinity of $T_g$ ($90^{\circ}C$). Thermal conductivity was measured using TC-30.