• Title/Summary/Keyword: Epoxy composites

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Dielectric Properties of Epoxy Composites with Variation of Additives and Curing Conditions (첨가제 및 경화조건 변화에 따른 에폭시 복합체의 유전특성)

  • Park, Kyung-Tae;Lee, Ho-Shik;Chung, Il-Hyung;Wang, Jong-Bae;Lee, Joon-Ung
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.879-882
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    • 1992
  • In order to study electrical properties of epoxy composites with various additives rates and curing conditions, dielectric measurements have been performed over a frequency range from 30 [Hz] to 3 [MHz] and a temperature range of 20[$^{\circ}C$]$\sim$180[$^{\circ}C$] The observed higher values of dielectric permittivity and loss In the case of filled epoxy are attributed to MWS polarization effect. The low temperature peak assigned to the $\beta$-relaxation process is attributed to the enhenced rotation of the methyl group attached to the main chain and the presence of filler. And the high temperature peak ($\alpha$-relaxation process)is associated with the segmental motion or glass transition process.

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Synergic Effect of Clay on the Mechanical and Electrical Properties of SWCNT/Epoxy Composites (SWCNT/에폭시 복합체의 기계적 전기적 성질에 미치는 Clay의 상승효과)

  • Choi, Won Seok;Ryu, Sung Hun
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.204-209
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    • 2014
  • Sodium-montmorillonite ($Na^+$-MMT) was introduced into single wall carbon nanotube (SWCNT)/epoxy composite to investigate the effect of MMT size and MMT/SWCNT ratio on the mechanical and electrical properties of composite. Three different sizes of MMTs were used and all were found to function as effective dispersion aids for SWCNTs. Mechanical properties of SWCNT/epoxy composite increased with MMT content; tending to decrease once the MMT content reached a critical level. However, the surface electrical resistance decreased with increasing MMT content and tended to increase after the critical content was reached. Critical MMT/SWCNT ratio for maximum mechanical properties and minimum electrical resistivity was strongly dependent on the MMT size. Critical MMT/SWCNT ratio was decreased with MMT size.

Failure Behavior of Pin-jointed Carbon/Epoxy Composites under Hygrothermal Environmentals (열습환경을 고려한 탄소섬유/에폭시 복합재의 핀 체결부 파괴거동)

  • Kim, Chan-Gyu;Hwang, Young-Eun;Yoon, Sung-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.411-413
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    • 2012
  • This study has been investigated about hygrothermal environmental effects on the pin-joined carbon/epoxy composites through acoustic emission technique. The specimens were classified as three types for pin loading test : Base (before immersion), RT (room temperature immersion), HT ($75^{\circ}C$ immersion). As a results, the bearing strength of RT specimens was weakly decreased than that of base specimens. The bearing strength of HT specimens was greatly decreased than that of Base and RT specimens due to effects of simultaneous moisture and higher temperature. Also, the results from cumulative hit of acoustic emission indicated that AE events induced by matrix cracks of HT specimens was lower than that of base specimens.

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The Physical Properties of Ethylene Vinylacetate Emulsion Mixed with SBR, Urethane, Epoxy and Acryl Latex (아크릴, 에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌 비닐아세테이트계 에멀젼 수지의 물리적 특성)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.196-204
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    • 2000
  • SBR, polyurethane, acryl and epoxy latex were separately mixed with ethylene -vinylacetate emulsion(EVA) in the range of $0{\sim}50wt%$. For the mixtures, the various physical properties such as defoamerability, mechanical property, and water resistance were experimentally examined. The excellent defoamer was BYK-021 and the appropriate use of it was 0.3 phr for the total components. The shrinkage of compounds was influenced by the compatability of resins and the formation of voids. The mechanical properties was related to the cohesive force of resin particles, the coagulation of cement particles and the co-bonding of resin particles with cement particles. Mixing latex separately showed better properties then non-mixing in the shrinkage ratio, flexural strength, adhesive strength, and impact strength. The water resistance of composites mixed with cement was worse than that of EVA resin.

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Improvement of Physical Properties for Carbon Fiber/PA 6,6 Composites (탄소섬유/폴리아마이드 6,6 복합재료의 기계적 물성 향상)

  • Song, Seung A;On, Seung Yoon;Park, Go Eun;Kim, Seong Su
    • Composites Research
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    • v.30 no.6
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    • pp.365-370
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    • 2017
  • Mechanical properties of carbon fiber reinforced thermoplastic composites (CFRTPs) are affected by various factors. One of the them are poor compatibility of the epoxy sizing layer on the carbon fiber surface with thermoplastic matrix, which causes the inferior interfacial strength between fibers and matrix. In addition, the high molten-viscosity of thermoplastics attributes to the poor impregnation state. Consequently, many voids in the composite materials were generated, which leads to poor mechanical properties of the thermoplastic composites. In this study, the epoxy sizing on the carbon fiber surface was removed and the polyamide 6,6 solution was coated on the de-sized carbon fiber surface to improve the impregnation state and mechanical properties. Interlaminar shear strength (ILSS) of CFRPTs was estimated by implementing short beam shear tests. In addition, flexural strength was measured and the impregnation state of the composites was evaluated by calculating void content.

Influence of Acid and Base Surface Treatment of Multi-Walled Carbon Nanotubes on Mechanical Interfacial Properties of Carbon Fibers-Reinforced Composites (산-염기 표면처리된 MWNTs의 첨가가 탄소섬유 강화 복합재료의 기계적 계면특성에 미치는 영향)

  • Jung, Gun;Nah, Chang-Woon;Seo, Min-Kang;Byun, Joon-Hyung;Lee, Kyu-Hwan;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.612-616
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    • 2012
  • In this work, the effect of chemical treatments of multi-walled carbon nanotubes (MWNTs) on the mechanical interfacial properties of carbon fiber fabric-reinforced composites was investigated. The surface properties of the MWNTs were determined by acid and base values, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analyses. The mechanical interfacial properties of the composites were assessed by interlaminar shear stress (ILSS) and critical stress intensity factor ($K_{IC}$). The chemical treatments based on acid and base reactions led to a significant change of surface characteristics of the MWNTs, especially A-MWNTs/carbon fibers/epoxy composites had higher mechanical properties than those of B-MWNTs and non-treated MWNTs/carbon fibers/epoxy composites. These results were probably due to the improvement of interfacial bonding strength, resulting from the acid-base interaction and hydrogen bonding between the epoxy resins and the MWNT fillers.

Self-Sensing and Interfacial Evaluation of Ni Nanowire/Polymer Composites Using Electro-Macromechanical Technique (전기적 미세역학적 시험법을 이용한 Ni nanowire강화 고분자 복합재료의 자체 감지능 및 계면 물성평가)

  • Kim, Sung-Ju;Yoon, Dong-Jin;Hansen George;DeVries K. Lawrence;Park, Joung-Man
    • Composites Research
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    • v.19 no.5
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    • pp.20-27
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    • 2006
  • Self-sensing and interfacial evaluation of Ni nanowire/polymer composites were investigated using electro-macromechanical technique, which can be used fur a feasible sensing measurement on tensile and compressive loading/consequent unloading, temperature, and humidity. Mechanical properties of Ni nanowire with different aspect ratio and adding contents in either epoxy or silicone composites were measured indirectly using electro-pullout test under uniform and non-uniform cyclic loadings. Comparing apparent modulus with the conventional mechanical tensile modulus of Ni nanowire/epoxy composites, the trends were consistent with each other. Ni nanowire/epoxy composites showed the sensing response on humidity and temperature. Self-sensing on applied tensile and compressive loading/unloading was also responded for Ni nanowire/silicone composites via electrical contact resistivity showing the opposite trend between tension and compression. It can be due to the different electrically-interconnecting mechanisms of dispersed Ni nanowires embedded in silicone matrix.

Tribological Properties of Laminated Fiber Orientation in Carbon Fiber/Epoxy Composites for Reflecting Material of the Electromagnetic Wave (전자파 반사재료로 사용되는 탄소섬유/에폭시 복합재료의 적층 탄소섬유 방향성이 마찰특성에 미치는 영향)

  • Chun, Sang-Wook;Gimm, Youn-Myoung;Kang, Ho-Jong
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.778-783
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    • 1999
  • The effect of carbon fiber orientation on the tribological properties of carbon fiber/epoxy composites used as a reflecting material for the electromagnetic wave has been investigated. It was found that the carbon fiber/epoxy composite which slides normal to prepreg lay-up direction had less friction and wear that those slides parallel to prepreg fiber lay-up direction due to the increase of delamination between carbon fiber and epoxy. Composite with unidirectional orientation($0/0^{\circ}$) had higher tribological properties than those with multidirectional orientation($0/45/90/-45^{\circ}$ and $0/90^{\circ}$) when the sliding direction was normal to prepreg lay-up direction. This was caused by the debonding between carbon fiber and epoxy which is proportional to contact area between the sliding surface and carbon fiber. Opposite results have been found when the sliding direction was parallel to prepreg lay-up direction due tot he tensile force applied on carbon fiber. In addition, it was shown that wear factor increased with increasing sliding velocity but the friction coefficient did not depend upon the sliding velocity.

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Investigation of Properties of Structural Foam with Different Conformation and via Thermal Aging Condition (구조용 폼의 조성 및 열 노화에 따른 변형특성 관찰)

  • Choe, Jin-Yeong;Kwon, Il-Jun;Park, Sung-Min;Kwon, Dong-Jun
    • Composites Research
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    • v.31 no.4
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    • pp.122-127
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    • 2018
  • Sandwich composites of carbon fiber reinforced plastic(CFRP) and polymer foam will be used to automobile and aerospace industry according to increasing importance of light weight. In this study, mechanical and heat resistance properties of sandwich composites were compared with type of polymer foam (polyethylene terephthalate(PET), polyvinylchloride(PVC), epoxy and polyurethane). All types of polymer foams were degraded to 30, 60, 120, 180 minutes in $180^{\circ}C$. After heat degradation, the polymer foams were observed using optical microscope and compressive test was performed using universal testing machine(UTM). Epoxy foam had the highest compressive property to 2.6 MPa and after thermal degradation, the mechanical property and structure of foam were less changed than others. Epoxy foam had better mechanical properties than other polymer foams under high temperature. Because the epoxy foam was post cured under high temperature. As the results, Epoxy foam was optimal materials to apply to structures that thermal energy was loaded constantly.

Tuning Thermal Expansion Coefficient of Composites Containing Epoxy Resin/Inorganic Additives for Stone Conservation (에폭시 수지/무기물 첨가제 복합체의 열팽창계수 조절 및 석조문화재의 응용)

  • Choi, Yong-Seok;Chae, Il-Seok;Kang, Yong-Soo;Won, Jong-Ok;Kim, Jeong-Jin;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.431-440
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    • 2011
  • The thermal expansion coefficient of epoxy/inorganic additives composites was controlled by changing the amount of the inorganic additives such as talc and fused silica. The epoxy resin comprises hydrogenated bisphenol A (HBA)-based epoxide, difunctional polyglycidyl epoxide (DPE) as a diluent and isophorone-diamine (IPDA) as a crosslinking agent, which was subsequently mixed with inorganic additives (talc and fused silica). The thermal expansion coefficient was decreased by increasing amount of inorganic additives, nearly to fresh granite. Fused silica was more effective than talc in lowering the thermal expansion coefficient. Additionally, lexural and tensile strengths of the composites were getting lower and higher with the amount of the inorganic fillers, respectively. It was thus concluded that an epoxy composite containing inorganic fillers was developed to show much lower thermal expansion coefficient, similar to fresh granite, than the neat epoxy resin, and also proper mechanical strengths for applications.