• 한국응용과학기술학회지
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• 제26권4호
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• pp.379-384
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• 2009

Epoxy resin based encapsulants are widely used in semiconductor packaging applications. Epoxy resin based encapsulants are often subject to crack or delamination during the reliability test due to the thermal stress caused by high modulus nature of epoxy resins. Epoxy functional siloxanes are often added into epoxy resin to reduce the modulus so that the thermal stress can be reduced. Epoxy functional siloxanes, additives for reduced modulus, were synthesized and added into the curable epoxy resins. The modulus and the coefficient of thermal expansion (CTE) were also measured to investigate the thermal stress and to see whether the epoxy functional siloxane adversely affects the CTE or not. As a result, around 26% to 72% of thermal stress reduction was observed with no adverse effect on CTE.

• 한국응용과학기술학회지
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• 제33권4호
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• pp.634-646
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• 2016

본 논문에서는 약용매에서 용해될 수 있는 지방산 변성 에폭시수지를 합성하였고, 합성한 수지의 용해도 평가가 이루어졌다. 지방산 변성 에폭시수지를 합성하기 위하여 비스페놀A형, 페놀 노볼락형 및 오르소 크레졸 노볼락형의 3종류 에폭시수지를 사용하였고, 여기에 지방산, dodecyl phenol (DP), toluene diisocyanate (TDI)를 도입하였다. 합성조건은 당량기준으로 에폭시수지/지방산 = 1/0.5, 지방산/DP = 0.25/0.25, TDI 0.5이었고, 에폭시수지 종류에 따라 12종류의 지방산 변성 에폭시수지가 합성되었다. 합성된 지방산 변성 에폭시수지에 대하여 점도 및 용매${\surd}$가용성을 평가한 결과, 벤젠고리와 글리시딜기의 함량 및 알킬기의 탄소수가 증가할수록 약용매에 대한 용해성이 우수한 것으로 나타났다. 또한 약용매에 용해성이 우수한 지방산 변성 에폭시수지를 사용하여 투명 도료를 제조하여 물성을 평가한 결과, 비스페놀A형 에폭시수지/지방산/DP/TDI의 당량비가 1.0/0.25/0.25/0.5인 것과 페놀 노볼락형 에폭시수지/지방산/DP의 당량비가 1.0/0.25/0.25인 조성에서 건조시간, 접착력, 도막경도, 내충격성, 내알칼리성에서 양호한 물성을 나타내었다.

• 보존과학연구
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• 통권17호
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• pp.39-47
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• 1996

In this research, many effects were examined by testing of adhesive intensity and accelerated weathering with synthetic resins for the conservation treatment of cracks and damaged parts of Kyound Chun-Sa10-story Pagodas, the National Treasure No. 86.It was tested with two kinds of Epoxy resins, Acrylic, Silicone resin, and five kinds of Acetics vinyl resins, and then which was ensured a successful result with Epoxy resins. According to these consequences, they are determined to treat damaged parts with Epoxy resin.

• 한국응용과학기술학회지
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• 제24권4호
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• pp.399-409
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• 2007

Characteristics of polyaniline anti-corrosive coatings with various primer coating resins(epoxy resin, urethane resin, and others) and top coating resins(epoxy and acrylic urethane resins) were investigated through adhesion, acid resistance, alkaline resistance, water resistance, and anti-corrosion tests. As a result, the anti-corrosive properties of the prepared coatings using polyaniline varied with the types of primer and top coating resins. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using emeraldine base (EB) of polyaniline blended with single-packaged urethane and acrylic urethane resins as the primer coatings, and using acrylic urethane resin as the top coatings. Also, the anti-corrosive function of these anti-corrosive coatings was well preserved for 1000 hr in the salt spray experiment.

• 전기학회논문지
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• 제67권10호
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• pp.1322-1329
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• 2018

In this paper, the reliability test of three kinds of epoxy resin for GIS Spacer, which is a high voltage based heavy electric machine, AC electrical treeing experiments were performed. Three types of epoxy resins, Araldite B41, CT 5531 CI and B46, have slight viscosity differences. An non-uniform electric field, E = 1149.4 kV/mm, as the needle to plate electrode, a power source with a frequency of 1 kHz was applied to the tree electrode for accelerated deterioration. The treeing phenomena of the three kinds of epoxy resin all initiated, propagated, and destroyed by the branch tree. Epoxy Resin B46 was 145 times longer than B41 and 53 times longer than CT 5531CI. I think that the choice of epoxy resin is very important in choosing high voltage heavy electric machine insulation materials.

• Transactions on Electrical and Electronic Materials
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• 제11권2호
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• pp.89-91
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• 2010

Partial discharge (PD) resistances were investigated for three types of samples: original epoxy resins, epoxy micro composites with and without the silane processing, and mixture composites with micro and nano particles. The PD was applied to these materials using rod, gap, and plane electrodes. The partial discharge resistance found in the micro composites was better than that found in the original epoxy resin. Moreover, the mixture composites of $SiO_2$ nano and micro particles had much larger resistances than the original epoxy resin or microcomposites. It can be regarded that this excellent property was due to the fact that the nano particles have a dense structure between the micro particles.

• 한국전기전자재료학회논문지
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• 제29권9호
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• pp.565-570
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• 2016

In this work, the complex permittivity of epoxy resins is measured. Epoxy resins, epoxy with micro size fillers and epoxy with micro+nano alumina composites have been evaluated for dielectric properties according to frequency variation. The dielectric spectroscopy measurement and analyses are carried out in the frequency range of $10^{-2}Hz$ to 1MHz and constant to room temperature. The results of dielectric loss suggest that significant improvement in the electrical performance can be expected by using samples containing nano and micro fillers mixture when compared to materials containing only microfillers. As the result, we verified the specific characteristics of dielectric permittivity and dielectric loss namely, relative permittivity become low with improving dispersibility of nano+micro mixture composites and become rise with agglomerate of nano particles.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.659-664
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• 1997

RC structures can deteriorate for many defective factors. In the repair and retrofit works of concrete, epoxy resins are widely used as repair materials. The object of this study is to investigate the material properties and durabilities of epoxy resins which are commonly used in repairing concrete. The material properties such as line-expansion modulus, viscosity, microstructure and physical parameter as well as the durabilities such as gravity change, tensile strength, elongation change were carried out.

• 보존과학회지
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• 제21권
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• pp.41-48
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• 2007

본 연구에서는 현재 철기 유물의 복원에 일반적으로 사용되고 있는 5종의 상용 에폭시 수지(Araldite rapid, Araldite AW 106, Araldite SV 427, Devcon, CDK)를 선택하여 온도, 자외선, 그리고 철기 유물의 부식인자 중 하나인 수분에 대한 내후성을 조사하였다. 각각의 에폭시 수지는 온도 상승에 따라 일정하게 부피가 변화되는 것을 알 수 있었으며, 특히 $40^{\circ}C$와 $70^{\circ}C$ 사이에서 급격한 변형이 일어나는 것을 확인하였다. UV에 노출시켰던 에폭시 수지는 모두 표면의 색상이 큰 폭으로 변화되었다. 실내조건의 경우는 모든 시험편의 색차(${\Delta}E$)가 2미만으로 색상의 변화가 약하였다. 에폭시 수지 시료 표면의 수분에 대한 평형 접촉각은 Araldite rapid>AW 106>Devcon>SV 427>CDK의 순서로 나타났다. 에폭시 수지를 UV에 노출시킨 경우 평형접촉각은 전반적으로 모두 감소하였으나, SV 427이 가장 안정적인 것으로 나타났다.

• Carbon letters
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• 제11권2호
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• pp.102-106
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• 2010

In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor ($K_{IC}$), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.