• Proceedings of the KIEE Conference
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• 1998.07f
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• pp.1981-1983
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• 1998

The principle of the MHD generation is based on Faraday's law of induction that a eletromotive force(u ${\times}$ B) is generated when the working gas of velocity u flows a channel in which magnetic field of strength(B) exists. In MHD power generation system, enthalpy of the working gas is converted to electric power directly through expansion in generator channel. It means that electric power can be generated without moving mechanical linkage such as turbine blades. There are two types in the MHD generator; linear type Faraday and disk type hall generator. Disk type hall generator is the main target of this paper. Isentropic efficiency and enthalpy extraction rate of disk type shock tube driven hall generator is discussed here.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.3 no.2
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• pp.447-453
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• 1999

In MHD power generation system, enthalpy of the working gas is convened to electric power directly through expansion in generator channel. It means that electric power can be generated without a moving mechanical linkage such as turbine blades. The principle of MHD generation is based on Faraday'law of induction that eletromotive force(u$\times$B) is generated when the working gas of velocity u flows a channel in which magnetic field of strength(B) exists. In this paper, helium gas seeded with cesium is used as working gas. There are two types of generator in MHD generation; linear type faraday and disk type hall generator. Rogowski coils having the bandwidth of the 100(Hz) ~ 20(kHz) were used for measuring current flowing MHD disk channel. Optimum load resistor value of the MHD generator studied was 2.5[$\Omega$]. Disk type hall generator's generation performance is the main target of this paper, which superiors to linear type Faraday generator in many points. Isentropic efficiency and enthalpy extraction rate of disk type shock tube driven hall generator is discussed here.

• Preventive Nutrition and Food Science
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• v.12 no.3
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• pp.131-134
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• 2007

The kinetic analyses for thermal products of alpha-, gamma- and delta-tocopherols during heating as functions of temperature and time were studied. Alpha-, gamma- and delta-tocopherols dissolved in glycerol were heated at $100{\sim}200^{\circ}C$ for $5{\sim}60$ min. The thermal products were separated by hexane extraction and analyzed by HPLC using a reversed phase ${\mu}-Bondapak$ $C_{18}-column$ with two kinds of elution solvents in a gradient mode. The formation kinetics of thermal products of tocopherols followed a first-order kinetic model. The formation rate of thermal products of tocopherols was dependent on heating temperatures and heating times. The activation energy and enthalpy for the thermal products of ${\gamma}-and$ ${\delta}-tocopherols$ were higher than those for ${\alpha}-tocopherol$ as in the case of the oxidative degradation kinetics of tocopherol. The magnitude order of the activation energy was ${\gamma}->{\delta}->{\alpha}-tocopherol$.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.697-708
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• 1992

Liquid Chromatographic behavior of Ni(II) in Isonitrosoethylacetoacetate Imine(IEAA-NR), Ni(IEAA-NH)(IEAA-NR)(R = H, CH_3, C-2H_5, n-C_4H_9, C_6H_5-CH_2) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of Ni(IEAA-NH)(IEAA-NR) chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It was fo$und that metal chelates were properly eluted in an acceptable range of capacity factor value(0{\le}logk'{\le}1). The dependence of the logarithm of capacity factor (k') on the volume fraction of water in the binary mobile phase as well as on the liquid-liquid extraction distribution ratio (Dc) in methanol-water/n-alkane extraction system showed the good linearties, and the dependence of the logarithm of capacity factor (k') on the column temperature and on the enthalpy exhibited the good linearties, and the compensation temperature ({\beta}) from the slope was 773.47{\circ}K. It was suggested that the retention of metal chelates was largely affected by the hydrophobic effect.

• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.1035-1046
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• 1993

Some iron(III)porphyrin complexes were prepared, and identified by the spectroscopic methods. Elution behavior of iron(III)porphyrin complexes was investigated by reversed-phase HPLC. The optimum conditions for the separation of iron(III)porphyrin complexes were examined with respect to flow rate and mobile phase strength. These complexes were successfully separated on NOVA-PAK $C_{18}$ column using methanol / water(95/5) for $[T_pCF_3PP)Fe(R)]$ and methanol / water (98/2) for $[(P)Fe(C_6F_5)]$ as a mobile phase. It was found that these complexes were largely eluted in an acceptable range of capacity factor value ($0{\leq}logk'{\leq}1$). The dependence of the capacity factor (k') on the volume fraction of water in the binary mobile phase as well as the dependence of k' on the liquid-liquid extraction distribution ratio$(D_c)$ in methanol-water / n-pentadecane extraction system showed a good linearity. It means that the retention of iron(III)porphyrin complexes on NOVA-PAK $C_{18}$ column is largely due to the solvophobic effect. Also, there was a good linear dependence of the capacity factor(k') on the column temperature and enthalpy calculated by van't Hoff plot. From these results, it was confirmed that the retention mechanism of iron(III)porphyrin complexes in reversed-phase liquid chromatography was invariant under the condition of various temperature, and the solvophobic binding process exhibited isoequilibrium behavior.