• Bulletin of the Korean Chemical Society
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• 제3권3호
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• pp.92-98
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• 1982

Solvolysis reactions of some substituted benzoyl chlorides were studied in ethanol-water, ethanol-trifluoroethanol and methanol-acetonitrile mixtures. Results showed that the reaction proceeds via an $S_N2$ process in which bond formation is more advanced than bond cleavage. Comparison of the two models for predicting transition state variation indicated superior nature of the quantum mechanical model relative to the potential energy surface model.

• 한국식생활문화학회지
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• 제9권5호
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• pp.447-455
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• 1995

The purpose of the present study is to assess nutrient content for providing nutrition information such as nutrition labeling on Korean dishes in restaurant and food service institutions. The content of nutrients was calculated in recipies used to prepare dishes which has been frequently consumed in such four groups as the literature, foodservice institutions of industries, restaurants, and households. The numbers of dishes surveyed were 15. Total numbers of literture used for recipies analysis are 20. Recipies used in foodservice institutions of industries were abstracted from the journal 'Guk-Min Young-Yang' published in Korea dietetic association and obtained with the help of dietitians working in those institutions. Also, recipies has been using in restaurants were given from the Korea restaurant association. Recipies in households was calculated from the secondary analysis of the Korean National Nutrition Survey. Nutrient content from foods except steamed rice and side dishes in each dish was calculated using data of Korean food composition table published. The content of energy and protein in 'Gal-bi tang' (beef-rib soup) were highest in recipes used at restaurants, vitamin C in recipes of food service institutions of industries due to the generous use of meats and vegetables than other recipies. 'Doen-jang chigae' (soybean paste stew) showed the lowest content of energy in results analyzing recipes presented on the literature and varied protein level by four groups for difference of protein source used. The content of energy in 'Gop-chang jeongol' (small intestines stew) is 150 kcal more than 'Soegogi jeongol' (beef stew) in general. The energy level of 'Daeji-galbi' jim (braised pork ribs) and 'Dak jim' (braised chicken) turned out to be the highest in recipies presented on literature. Variation of each nutrient content including energy and protein was relatively high, since some of foods used in 'Pibimbab' (mixed rice) varied with four groups. Amounts of energy and protein in 'Naeng-myeun' (cold noodles) is the highest in recipies of foodservice institution of industries because much amounts of noodle and meats were used comparing to other groups. The average content of energy in 'Pulgogi' (grilled meat with sauce) was 50% to Korea recommended amounts of one meal, 833.3 kcal. Content of vitamin $B_1$ in 'Jeuk pyeunuk' (boiled pork), which is made of pork meat, was higher than other dishes. The ingredients of frequently consumed Korean dishes were highly variable among the four groups which inevitably results in variation of nutrient content in each dishes. The high variation of nutrient content in each dish according to study requires careful collecting of the large number of recipies in presenting representative nutrient content for nutrition labeling on dishes in restaurant and food service institutions effectively.

• 한국압력기기공학회 논문집
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• 제12권2호
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• pp.58-65
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• 2016

Since, in case of high energy piping, steam jets ejected from the rupture zone may cause damage to nearby structure, it is necessary to design it into consideration of nuclear power plant design. For the existing nuclear power plants, the ANSI / ANS 58.2 technical standard for high-energy pipe rupture was used. However, the US Nuclear Regulatory Commission (USNRC) and academia recently have pointed out the non-conservativeness of existing high energy pipe fracture evaluation methods. Therefore, it is necessary to develop a highly reliable evaluation methodology to evaluate the behavior of steam jet ejected during high energy pipe rupture and the effect of steam jet on peripheral devices and structures. In this study, we develop a method for analyzing the impact load of a jet by high energy pipe rupture, and plan to carry out an experiment to verify the evaluation methodology. In this paper, the basic data required for the design of the jet impact load experiment equipment under construction, 1) the load change according to the jet distance, 2) the load change according to the jet collision angle, 3) the load variation according to structure diameter, and 4) the load variation depending on the jet impact position, are numerically obtained using the developed steam jet analysis technique.

• 한국가스학회지
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• 제17권2호
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• pp.78-84
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• 2013

수증기 개질 반응로 설계를 위해 수증기 개질 반응로에 대한 열유동 해석을 수행하였다. 6개의 이중관형 개질기 튜브들과 1개의 버너로 구성된 반응로에 대해 개질반응과 열유동 해석을 연계하여 수치계산을 수행하였다. 버너 형상 변화에 따른 반응로 내에서의 유동구조를 계산하여 버너 형상을 선택하였다. 개질반응 통합해석 결과, 반응로 상하단내에서 온도구배가 크게 나타났으며 개질기 튜브 내의 조성 변화도 반응로 온도분포의 영향을 받는 것으로 나타났다. 또한, 운전조건인 SCR 및 GHSV 변동에 따른 개질 반응특성이 변화함을 확인할 수 있었다.

• Journal of Korean Society for Atmospheric Environment
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• 제20권E1호
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• pp.15-28
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• 2004

To study the characteristics of ammonia and the related compounds, atmospheric aerosols and gases were collected using a triple filter pack sampler, a low volume air sampler, and a three-stage Anderson air sampler in Seoul and Kangwha Island, Korea from Dec. 1996 to Oct. 1997. Ammonia concentrations showed approximately two times higher in summer than in winter at both sites. The highest $HNO_3$ levels were generally observed in summertime at two sampling sites. The average mass concentration of $PM_{2.5}$ in heavily industrialized Seoul was about three times higher than that of Kangwha. In winter, the sum of $NH_4^+$ and its counter ions (such as $Cl^-,\;NO_3^-$, and $SO_4^{2-}$) comprised $30-41\%$ of $PM_{2.5}$ mass concentration at each sampling site. Temperature dependence of particulate nitrate was examined at the urban sampling site. The formation of the nitrate in the fine mode was dependent not only on the amount of precursors but also on the variation of temperature. $(NH_4)_2SO_4$ and $NH_4HSO_4$ coexisted with $NH_4NO_3$ and $NH_4Cl$ at each site. According to the summertime backward trajectory analysis, $NO_3^-$ showed higher level with air parcels transported from northeast Asian continent. On the other hand, the concentration of $SO_4^{2-}$ showed significantly higher level when air masses originated from Pacific Ocean, southern part of Japan, and Korea.

• Advances in Energy Research
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• 제5권3호
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• pp.227-237
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• 2017

The continuous increase of emission rates of green house gases and the effects on global warming added a new dimension to the problem of substituting the petroleum and its derivatives by environment friendly and sustainable energy sources for the world. Solar and wind energy appear at the top of the list of renewable of high potential, widely available, of dominated technology and well accepted. Brazil is one of the few countries in the world that receives number hours of sunshine exceeding 3,000 hours per year with a daily average of 4.5 to 6 kWh. However, this potential is largely unexplored and poorly tapped. The number of renewable systems implanted in Brazil has grown in recent years, but still insignificant when compared, for example, with Germany and Spain among others. This paper presents the results of an optical study on small concentration solar collector with evacuated tube enveloping the absorber and internal reflective surface fixed on the bottom part of the evacuated tube. The designed collector has a 2D geometrical concentration ratio between 2.455 and 4.91. The orientation of the solar collector, the ratio of the radius of the receiver to the radius of the absorber, the incidence angle for each period of the year, the collector inclination angle, the aperture angle of the reflective surface, concentration and optical efficiency were determined. The ray traces and flux distribution on the absorber of the evacuated tube solar collector were determined by using the program Ray Optics Simulation. The optical efficiency varies during the year according to the solar declination. For the periods were the solar declination is close to zero the efficiencies are maximum, and the variation during the day is around 25.88% and 99.9%. For the periods were the solar declination is maximum the efficiencies are minimum, and the variation during the day is around 23.78% and 91.79%.

• 방사선산업학회지
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• 제5권4호
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• pp.347-352
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• 2011

In order to identify the genetic relationship analysis by acute and chronic gamma irradiation, Arabidopsis (Arabidopsis thaliana L.) were irradiated with 200 Gy of gamma-rays using gamma-irradiator (3,000 Ci; Nordion, Canada) and gamma-phytotron (400 Ci; Nordion, Canada) for acute and chronic irradiation, respectively. Genetic relationship among two acute gamma-irradiated plants (A1 and A24) and three chronic gamma-irradiated plants (C1W, C2W, C3W) were analyzed using the amplified fragment length polymorphism (AFLP) technique compared with each non-irradiated plant. A total of 28 EcoRI and MseI primer combinations were used to screen 8 treatments by the ABI3130 capillary electrophoresis system. Amplified products by 28 primer sets showed 1,679 bands with an average of 51 bands per primer combination. Out of the total bands scored, 1,164 fragments were polymorphic bands, with different alleles existing among the treatments. The cluster analysis was performed using the UPGMA (Unweighted Pair Group Method using Arithmetic) in the computer program NTSYS-pc. In clustery analysis, acute gamma-irradiation showed higher genetic variation compared with chronic gamma-irradiation.

• 반도체디스플레이기술학회지
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• 제18권4호
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• pp.30-34
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• 2019

We analyzed how the features in plasma information based virtual metrology (PI-VM) for SiO₂ etching depth with variation of 5% contribute to the prediction accuracy, which is previously developed by Jang. As a single feature, the explanatory power to the process results is in the order of plasma information about electron energy distribution function (PI_EEDF), equipment, and optical emission spectroscopy (OES) features. In the procedure of stepwise variable selection (SVS), OES features are selected after PI_EEDF. Informative vector for developed PI-VM also shows relatively high correlation between OES features and etching depth. This is because the reaction rate of each chemical species that governs the etching depth can be sensitively monitored when OES features are used with PI_EEDF. Securing PI_EEDF is important for the development of virtual metrology (VM) for prediction of process results. The role of PI_EEDF as an independent feature and the ability to monitor variation of plasma thermal state can make other features in the procedure of SVS more sensitive to the process results. It is expected that fault detection and classification (FDC) can be effectively developed by using the PI-VM.

• Bulletin of the Korean Chemical Society
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• 제21권3호
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• pp.281-290
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• 2000

We varied recombination method of fenetic algorithm (GA), i.e., crossover step, to compare efficiency of these methods, and to find more optimum GA method. In one method (A), we select two conformations(parents) to be recombined by systematic combination of lowest energy conformations, and in the other (B), we select them in a ratio proportional to the energy of the conformation. Second variation lies in how to select crossover point. First, we select it randomly(1). Second, we select range of residues where internal energy of the molecule does not vary for more than two residues, select randomly among such regions, and we select either thr first (2a) or the second residue (2b) from the N-terminal side, or the first (2c) or the second residue (2d) from the C-terminal side in the selected region for crossover point. Third, we select longest such hregion, and select such residue(as cases 2) (3a, 3b, 3c or 3d) of the region. These methods were tested in a 2-dimensionl lattice system for 8 different sequences (the same ones used by Unger and Moult., 1993). Results show that compared to Unger and Moult's result(UM) which corresponds to B-1 case, our B-1 case performed similarly in overall. There are many cases where our new methods performed better than UM for some different sequences. When cooling factor affecting higher energy conformation to be accepted in Monte Carlo step was reduced, our B-1 and other cases performed better than UM; we found lower energy conformers, and found same energy conformers in a smaller steps. We discuss importance of cooling factor variation in Monte Carlo simulations of protein folding for different proteins. (A) method tends to find the minimum conformer faster than (B) method, and (3) method is superior or at least equal to (1) method.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2000년도 춘계공동학술발표회
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• pp.247-248
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• 2000