• Title/Summary/Keyword: Energy trap

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A study on the properties of TSC in oriented polypropylene film irradiated by laser (레이저로 조사된 이축연신 폴리프로필렌 필름의 열자격 전류특성에 관한 연구)

  • 노영배;홍진웅;김재환;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.98-101
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    • 1990
  • In order to investigate the laser effects resulted from the behaviors of carriers for BOPP film, experiment of TSC were carried out on the specimen with 15[$\mu\textrm{m}$] thick irradiated by He-Ne laser. The TSC spectras were observed in the temperature range of -100[$^{\circ}C$] to 130[$^{\circ}C$] with the electric field of 20∼60[MV/m], had show four of the distinguished peak such as ${\alpha}$$_1$, ${\alpha}$$_2$, ${\beta}$ and ${\gamma}$, which appeared at 115, 80, 17 and -30[$^{\circ}C$] respectively. Specially, ${\alpha}$$_1$ was observed and anomalous TSC flowing in the same direction as the charging current on the high-electric field such as 50∼60[MV/m]. In according on the consequences obtained from the studies, the origin of ${\alpha}$$_1$peak was attributed to the detrapping process form trap with 2.88[eV] deep of injected space charge from the chathode in the crystaline regions. The origin of ${\alpha}$$_2$ peak was regarded as the detrapping process of ions trapped with 0.9[eV] deep originated from impurity-ion remained in the specimen during production process of the material, in the crystalline regions. The origin of ${\beta}$ peak was concluded to be due to the depolarization process of "C=0"dipole with the activation energy of 0.75[eV] in the amorphous regions. The origin of ${\gamma}$ peak was responsible to the process combined with the depolarization of "CH$_3$", chain segment, with the activation energy of carriers from the shallow trap with 0.4[eV], in he amorphous regions.

Thermoluminescene Properties of Li6Gd(BO3)3:Ce3+ Scintillation Single Crystal (리튬 가돌리늄 보레이트 섬광단결정의 열형광 특성)

  • Kim, Sunghwan;Lee, Joonil
    • Journal of the Korean Society of Radiology
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    • v.8 no.7
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    • pp.455-459
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    • 2014
  • We grew the $Li_6Gd(BO_3)_3:Ce^{3+}$ scintillator and determined the scintillation and thermoluminescence properties for X-rays. The emission spectrum of $Li_6Gd(BO_3)_3:Ce^{3+}$ is located in the range of 370~500 nm, peaking at 423 nm an 455 nm, due to the $4f{\rightarrow}5d$ transition of $Ce^{3+}$ ions. The fluorescence decay time of the crystal is composed three components. The fast component is 60 ns (25%), the intermediate component is 787 ns (29%) and the slow component is $5.9{\mu}s$ (46%) of the crystal. The after-glow is caused by the electron and hole traps in the crystal lattice. We determined physical parameters of the traps in the crystal. The thermoluminescence trap are composed two traps. The determined activation energy (E), kinetic order (m) and frequency factor (s) of the first trap are 0.65 eV, 1.01 and $6.9{\times}10^8s^{-1}$. And, the determined activation energy, kinetic order and frequency factor of the second trap are 0.96 eV, 1.79 and $3.1{\times}10^{12 }s^{-1}$, respectively.

Photoluminescence Behavior of $Al^{3+}$, $Pr^{3+}$ Doped Perovskite-type $La_{2/3}TiO_{3}and Pyrochlore-type $La_{2}Ti_{2}O_{7}$ ($Al^{3+}$, $Pr^{3+}$가 첨가된 Perovskite $La_{2/3}TiO_{3}와 Pyrochlore $La_{2}Ti_{2}O_{7}$의 발광 특성)

  • Park, Sang-Mi;Park, Joung-Kyu;Kim, Chang-Hae;Park, Hee-Dong;Jang, Ho-Gyeom
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.806-810
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    • 2001
  • $La_{2/3}TiO_3$, $La_2Ti_2O_7$ are used in various parts by dielectric properties. The purpose of the present study is to understand the photoluminescence properties of $Al^{3+}\;and\;Pr^{3+}$ doped perovskite-type $La_{2/3}TiO_3$ and pyrochlore-type $La_2Ti_2O_7$ phosphor, which characterized by the red emission $(^1D_2{\rightarrow}^3H_4)\;of\;Pr^{3+}$ of $Pr^{3+}$ ion. The explanation for the energy transfer and the corresponding critical distance were proposed on the role of Al^3+ ions as energy transfer mediates in perovskite-type $La_{2/3}TiO_3$:Pr phosphor. In order to clarify the distinction of photoluminescence propoerties between the perovskite-type $La_{2/3}TiO_3$ and the pyrochlore $La_2Ti_2O_7$, the trap-involved process and the charge transfer band have been investigated.

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A Study on the Efficiency of Hydrogen-Oxygen Mixture Gas Generation Stack (수소-산소 혼합가스 발생 스택의 효율 연구)

  • Lee, Sang-Ho;Moon, Il-Sik;Kim, Chang-Hee;Kang, Kyoung-Soo;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.409-417
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    • 2006
  • The characteristics of hydrogen-oxygen mixture gas generation stack was experimentally studied in terms of efficiency. For this purpose, the mixture gas generation stack was fabricated by connecting 7 cells in series following the Tero Ranta report. In order to avoid the instrument inaccuracy, all measuring equipments were re-tested and calibrated by Korea Laboratory Accreditation Scheme (KOLAS) certified laboratories. Since the amount of produced gas is most crucial in determining the efficiency, two gas collecting methods such as bottle trap method and wet gas meter method were adopted. From the experimental results, it was found that both KOH fume and steam evaporated along with hydrogen-oxygen mixture gas, and these by-product gases could cause the misestimation of the stack efficiency. The current, voltage, and energy efficiencies of the hydrogen-oxygen mixture gas generation stack was evaluated based upon the stack efficiency calculation method summarized in this work.

Synthesis of Nanostructures by Direct Growth of Carbon Nanotubes on Micron-sized Metal Fiber Filter and its Filtration Performance (마이크론 금속섬유 필터에서 탄소나노튜브의 직접 성장에 의한 나노구조체 합성 및 여과성능)

  • Lee, Dong Geun;Park, Seok Joo;Park, Young Ok;Ryu, Jeong In
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.264-268
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    • 2007
  • The filtration performance of micron-sized metal fibrous filter was improved by synthesizing carbon nanotubes grown on the surface of metal fibers. The carbon nanotubes are grown with bush-like nanostructures covered around the micron-fibers or web-like nanostructures crossing between the fibers at different synthetic conditions. Filtration efficiency of CNT-metal-filter was measured and compared with the efficiency of the raw metal filter without CNTs. The developed CNT-metal-filter has higher filtration efficiency without significant difference in pressure drop compared with the conventional metal filter, which is because the carbon nanotubes function as the trap of pollutant nanoparticles.

TEM investigation of helium bubble evolution in tungsten and ZrC-strengthened tungsten at 800 and 1000℃ under 40keV He+ irradiation

  • I. Ipatova;G. Greaves;D. Terentyev;M.R. Gilbert;Y.-L. Chiu
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1490-1500
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    • 2024
  • Helium-induced defect nucleation and accumulation in polycrystalline W and W0.5 wt%ZrC (W0.5ZrC) were studied in-situ using the transmission electron microscopy (TEM) combined with 40 keV He+ irradiation at 800 and 1000℃ at the maximum damage level of 1 dpa. Radiation-induced dislocation loops were not observed in the current study. W0.5ZrC was found to be less susceptible to irradiation damage in terms of helium bubble formation and growth, especially at lower temperature (800 ℃) when vacancies were less mobile. The ZrC particles present in the W matrix pin the forming helium bubbles via interaction between C atom and neighbouring W atom at vacancies. This reduces the capability of helium to trap a vacancy which is required to form the bubble core and, as a consequence, delays, the bubble nucleation. At 1000 ℃, significant bubble growth occurred in both materials and all the present bubbles transitioned from spherical to faceted shape, whereas at 800 ℃, the faceted helium bubble population was dominated in W.

Experimental Study on the Characteristics of Brown Gas (브라운가스의 특성에 대한 실험적 연구)

  • Kim Chang-Hee;Oh Kyu-Hyung;Kang Kyung-Soo;Park Chu-Sik;Bae Ki-Kwang;Kim Jong-Won
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2006.05a
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    • pp.262-262
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    • 2006
  • The characteristics of Brown gas was experimentally studied in view of efficiency and flame propagation. For this study, the Brown gas stack with 7 cells was manufactured following the Brown gas related patents and reports. All measuring equipments were re-tested and calibrated by Korea Laboratory Accreditation Scheme (KOLAS) certified laboratories. Since the amount of produced gas is most crucial in determining the efficiency, we adopted two gas collecting methods such as bottle trap method and wet gas meter method. The energy efficiency of our own fabricated stack was measured to be 75%, which is comparable to general alkaline water electrolysis efficiency. In order to analyze the flame propagation characteristics of Brown gas, we measured the flame propagation pressure, velocity, and shape by using strain type pressure sensor, optical sensor, and high speed camera in conjunction with Schliren system, respectively. From the experimental results, it was found that the flame propagation behavior of Brown gas was almost the same as that of hydrogen and oxygen mixture gas in 2:1 molar ratio. Moreover, from the high speed camera analysis, we concluded that Brown gas flame exhibits explosion behavior as does mixture gas ($H_{2}:O_{2}=2:1$).

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Correlation Between Energy Gap and Defect Formation of Al Doped Zinc Oxide on Carbon Doped Silicon Oxide

  • Oh, Teresa;Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.207-212
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    • 2014
  • Aluminum-doped zinc oxide (AZO) films were deposited on SiOC/Si wafer by an RF-magnetron sputtering system, by varying the deposition parameters of radio frequency power from 50 to 200 W. To assess the correlation of the optical properties between the substrate and AZO thin film, photoluminescence was measured, and the origin of deep level emission of AZO thin films grown on SiOC/Si wafer was studied. AZO formed on SiOC/Si substrates exhibited ultraviolet emission due to exciton recombination, and the visible emission was associated with intrinsic and extrinsic defects. For the AZO thin film deposited on SiOC at low RF-power, the deep level emission near the UV region is attributed to an increase of the variations of defects related to the AZO and SiOC layers. The applied RF-power influenced an energy gap of localized trap state produced from the defects, and the gap increased at low RF power due to the formation of new defects across the AZO layer caused by lattice mismatch of the AZO and SiOC films. The optical properties of AZO films on amorphous SiOC compared with those of AZO film on Si were considerably improved by reducing the roughness of the surface with low surface ionization energy, and by solving the problem of structural mismatch with the AZO film and Si wafer.

SIMS glancing anlge을 적용한 tunnel oxide 내 Nitorgen 깊이 분해능 향상 연구

  • Lee, Jong-Pil;Choe, Geun-Yeong;Kim, Gyeong-Won;Kim, Ho-Jeong;Han, O-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.41-41
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    • 2011
  • Flash memory에서 tunnel oxide film은 electron tunnelling 현상을 이용하여 gate에 전하를 전달하는 통로로 사용되고 있다. 특히, tunnel oxide film 내부의 charge trap 현상과 불순물이 소자 특성에 직접적인 영향을 주고 있어, 후속 N2O/NO 열처리 공정에서 SiO2/Si 계면에 nitrogen을 주입하여 tunnel oxide film 특성을 개선하고 있다. 따라서 N2O/NO 열처리 공정 최적화를 위해서는 tunnel oxide film 내 N 농도와 분포에 대한 정확한 평가가 필수적이다[1]. 본 실험에서는 low energy magnetic SIMS를 이용하여 N2O로 열처리된 tunnel oxide film 내의 N농도를 보다 정확하게 평가하고자 하였다. 사용된 시료는 Si substrate에 oxidation 이후 N2O 열처리를 진행하여 tunnel oxide를 형성시켰으며, 분석 impact energy는 surface effect최소화와 최상의 depth resolution 확보를 위해 250eV를 사용하였으며, matrix effect와 mass interference를 방지하기 위해 MCs+ cluster mode[2]로 CsN signal를 검출하였다. 실험 결과, 특정 primary beam 입사각도에서 nitrogen depth resolution 저하 현상이 발생하였고, SIMS crater 표면이 매우 거칠게 나타났다. 이에, Depth resolution 저하 현상을 개선하기 위해 극한의 glancing 입사각 조건으로 secondary extraction voltage 변화를 통해 depth resolution이 개선되는 최적의 impact energy와 primary beam 입사각 조건을 확보하였다. 그 결과 nitrogen의 depth resolution은 1.6nm의 depth resolution을 확보하였으며, 보다 정확한 N 농도와 분포를 평가할 수 있게 되었다.

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Study on Energy Efficiency Improvement in Manufacturing Core Processes through Energy Process Innovation (에너지 프로세스 혁신을 통한 제조 핵심 공정의 에너지 효율화 방안 연구)

  • Sang-Joon Cho;Hyun-Mu Lee;Jin-Soo Lee
    • Journal of Advanced Technology Convergence
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    • v.2 no.4
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    • pp.43-48
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    • 2023
  • Globally, there is a collaborative effort to achieve global carbon neutrality in response to climate change. In the case of South Korea, greenhouse gas emissions are rapidly increasing, presenting an urgent situation that requires resolution. In this context, this study developed a thermal energy collection device named a 'steam trap' and created an AI model capable of predicting future electricity usage by collecting energy usage data through steam traps. The average accuracy of electricity usage prediction with this AI model was 96.7%, demonstrating high precision. Consequently, the AI model enables the prediction and management of days with high electricity consumption and identifies which facilities contribute to elevated power usage. Future research aims to optimize energy consumption efficiency through efficient equipment operation using anomaly detection in steam traps and standardizing energy management systems, with the ultimate goal of reducing greenhouse gas emissions.