• 환경영향평가
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• 제26권6호
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• pp.479-494
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• 2017

후쿠시마 사태 이후 형성된 원전에 대한 부정적인 여론은 몇몇 국가에서 '탈원전'이라는 정책으로 표출됐다. 한국도 문재인 정부가 들어서면서 원전의 비중을 단계적으로 낮추는 에너지 정책 전환 계획을 발표했다. 이로써 기후변화와 에너지 안보라는 두 가지 문제를 동시에 해결할 주요 에너지원으로 꼽혔던 원전 사용에 제한이 발생했다. 이 연구는 원전의 단계적 폐쇄를 주요 내용으로 하는 에너지 정책 전환 이행과 기후변화체제라는 상황 속에서 2016년부터 2030년까지 한국의 최적전력구성비를 찾는 것이 목적이다. 최적전력구성비는 시간당 전력수요와 INDC를 최소비용으로 만족하는 구성비를 의미한다. 이 연구에서는 선형계획법을 통해 에너지 정책 전환을 이행하는 시나리오와 원전을 2017년 수준으로 유지하는 시나리오로 나누어 비용을 비교분석했다. 그 결과 두 시나리오 모두 풍력은 2018년부터 꾸준히 증가하는 반면 태양광은 2021년부터 경제성을 갖춰 발전량이 대폭 늘어났다. 한편 총 비용은 에너지 전환 시나리오가 약 56조원으로 원전 유지 시나리오에 비해 약 5.5조원 더 비싼 것으로 나타났다.

• Archives of Pharmacal Research
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• 제7권1호
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• pp.47-52
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• 1984

Four polymorphic forms (I, II, III and IV) of hydrochlorothiazide have been characterized on the basis of x-ray diffractometry and differential thermal analysis. Form I was obtained by crystallization from N, N-dimethylformamide and Form II was crystallized from hot methanol. Form III was precipitated from sodium hydroxide aqueous solution by treatment with hydrochloric acid and Form IV was crystallized from 50% methanol. The metastable form I was a most stable form among four polymorphs, which was stable more than ten months at room temperature. The thermodynamic parameters such as heat of solution, enthalpy, entropy, free energy difference and transition temperature were determined by the measurement of intrinsic dissolution rate. The transition temperature and the heat of transition between the metastable Form I an Form II were determined to be $299.15^{\circ}$K and 5.03 Kcal/mole, respectively and free energy difference ($\delta$ F) was 302. 13 cal/mole. Diuretic action of these four polymorphic forms was also evaluated by monitoring the difference in urinary excretion of sodium, potassium and magnesium in rats.

• International Journal of Fluid Machinery and Systems
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• 제4권1호
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• pp.114-132
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• 2011

We have proposed a new approach based on energy gradient concept for the study of flow instability and turbulent transition in parallel flows in our previous works. It was shown that the disturbance amplitude required for turbulent transition is inversely proportional to Re, which is in agreement with the experiments for imposed transverse disturbance. In present study, the energy gradient theory is extended to the generalized curved flows which have much application in turbomachinery and other fluid delivery devices. Within the frame of the new theory, basic theorems for flow instability in general cases are provided in details. Examples of applications of the theory are given from our previous studies which show comparison of the theory with available experimental data. It is shown that excellent agreement has been achieved for several configurations. Finally, various prediction methods for turbulent transition are reviewed and commented.

• Bulletin of the Korean Chemical Society
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• 제18권11호
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• pp.1186-1191
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• 1997

Solvolyses of methanesulfonyl chloride (CH3SO2Cl) in water and methanol have been studied theoretically using ab initio self-consistent reaction field (SCRF) molecular orbital method. All stationary structures including transition state on the potential energy surface in solution have been found and compared with the gas phase structures. The overall reaction occurs via a concerted SN2 mechanism with a non-cyclic trigonal bipyramidal transition state, and the activation barrier is lowered significantly in solution. The transition state for the hydrolysis reaction is looser than that for the methanolysis reaction, and this is in accord with the experimental findings that an SN2 type mechanism, which is shifted toward an SN1 process or an SAN process in the hydrolysis and alcoholysis reaction, respectively, takes place. The catalytic role of additional solvent molecules appears to be a purely general-base catalysis based on the linear transition structures. Experimental barrier can be estimated by taking into account the desolvation energy of nucleophile in the reaction of methanesulfonyl chloride with bulk solvent cluster as a nucleophile.

• 지구물리와물리탐사
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• 제25권1호
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• pp.1-13
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• 2022

포항분지 천부가스 탐사를 위해 육상과 해상이 연결되는 전이대에서 탄성파 탐사 방법을 제안하고 탐사를 수행하였다. 해저면 환경, 육상 탐사 환경을 고려하여 탐사를 설계하였다. 육상노드 수진기는 육상에만 설치하였고 육상에서는 바이브로사이스 음원을, 해양에서는 에어건 음원을 이용하여 자료를 취득하였다. 전이대에서 취득한 탄성파 탐사자료의 경우 육상탐사와 해상탐사 간의 정확한 연계를 위해 신중한 자료 취득과 처리 과정이 필요하다. 음원 종류에 따른 진폭과 위상변화를 고려하고, 음원위치에 따른 정적보정을 적용한 자료처리를 통해 지층단면도에서 반사파 연속성이 유지되게 하였다. 자료처리 결과 육상과 해상의 지층구조가 연결된 탄성파 지층단면도를 확보하고 포항분지 천부 가스층 탐사에 활용하고자 하였다. 전이대에서 탄성파 탐사는 천부가스뿐만 아니라 연안지역 단층대 조사에도 활용할 수 있을 것으로 기대된다.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.980-986
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• 2012

In this paper we develop a minimalist model of single molecule spectroscopy in a dynamic environment. Our model is based upon a lattice system consisting of a probe molecule embedded in an Ising-model like environment. We assume that the probe molecule interacts with the Ising spins via a dipole-dipole potential, and calculate free energy curves and lineshapes of the system. To investigate fluctuation behavior of the system we exploit the metadynamics sampling method. In particular, using the method, we calculate the free energy curve of magnetization of the lattice and that of the transition energy of the probe molecule. Furthermore, we compare efficiencies of three different sampling methods used; unbiased, umbrella, and metadynamics sampling methods. Finally, we explore the lineshape behavior of the probe molecule as the system undergoes a phase transition from a sub-critical and to a super-critical temperature. We show that the transition energy of a probe molecule is broadly distributed due to the heterogeneous, local environments.

• 한국응용과학기술학회지
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• 제13권3호
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• pp.127-136
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• 1996

Thermograms of methylene blue(MB) in $L-{\alpha}-lecithin$ vesicle and incorporated purple membrane vesicle(InPM) systems have been studied by photochemical reaction differential scanning calorimetry at $25{\sim}55^{\circ}C$. Phase transition temperatures of lecithin vesicle, purple membrane(PM), and InPM were found to be independent of illumination of light(436nm) at $39{\sim}40^{\circ}C$, but endothermic phase transition was found in InPM vesicle. In MB-InPM system, endothermic phase transition was found on unillumination of light at $40{\sim}42^{\circ}C$, but exothermic phase transition was found on steady illumination of light at $48{\sim}52^{\circ}C$. It was estimated that the light energy absorbed from MB on vesicular surface was transferred to PM, and the transferred energy was redistributed to hydrophobic site of membrane. Therefore, the exothermic phase transition was measured at high temperature because of the increased hydrophobicity of acyl chain.

• Nuclear Engineering and Technology
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• 제44권5호
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• pp.543-550
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• 2012

The decrease in the fracture toughness of ferritic steels in a reactor pressure vessel is an important factor in determining the lifetime of a nuclear power plant. A surveillance program has been in place in Korea since 1979 to assess the structural integrity of RPV steels. In this work, the surveillance data were collected and analyzed statistically in order to derive the empirical relationship between the embrittlement and strengthening of irradiated reactor pressure vessel steels. There was a linear relationship between the yield strength change and the transition temperature shift change at 41 J due to irradiation. The proportional coefficient was about $0.5^{\circ}C$/MPa in the base metals (plate/forgings). The upper shelf energy decrease ratio was non-linearly proportional to the yield strength change, and most of the data lay along the trend curve of the US results. The transition regime temperature interval, ${\Delta}T_T$, was less than the US data. The overall change from irradiation was very similar to the US results. It is expected that the results of this study will be applied to basic research on the multiscale modeling of the irradiation embrittlement of RPV materials in Korea.

• 한국재료학회지
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• 제25권8호
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• pp.417-422
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• 2015

In this study, low-carbon hypoeutectoid steels with different ferrite-pearlite microstructures were fabricated by varying transformation temperature. The microstructural factors such as pearlite fraction and interlamellar spacing, and cementite thickness were quantitatively measured and then Charpy impact tests conducted on the specimens in order to investigate the correlation of the microstructural factors with impact toughness and ductile-brittle transition temperature. The microstructural analysis results showed that the pearlite interlamellar spacing and cementite thickness decreases while the pearlite fraction increases as the transformation temperature decreases. Although the specimens with higher pearlite fractions have low absorbed energy, on the other hand, the absorbed energy is higher in room temperature than in low temperature. The upper-shelf energy slightly increases with decreasing the pearlite interlamellar spacing. However, the ductile-brittle transition temperature is hardly affected by the pearlite interlamellar spacing because there is an optimum interlamellar spacing dependent on lamellar ferrite and cementite thickness and because the increase in pearlite fraction and the decrease in interlamellar spacing with decreasing transformation temperature have a contradictory role on absorbed energy.

• Nuclear Engineering and Technology
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• 제56권1호
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• pp.233-240
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• 2024

The wall friction correlations of oscillatory natural circulation loops are highly loop-specific, making it difficult to perform 1-D system simulations before obtaining specific experimental data. To better predict the friction characteristics, the nonlinear dynamics of a toroidal single-phase natural circulation loop were numerically investigated, and the transition effect was considered. The k-k_L-ω transitional turbulence and k-ω SST turbulence models were used to compute the flow characteristics of the loop under different heating powers varying from 0.48 to 1.0 W/cm², and the results of both models were compared with previous experiments. The mass flow rates and friction factors predicted by the k-k_L-ω model showed a better agreement with the experimental data than the results of the k-ω SST model. The oscillation frequencies calculated using both models agreed well with the experimental data. The k-k_L-ω transitional turbulence model provided better friction-factor predictions in oscillatory natural circulation loops because it can reproduce the temporal and spatial variation of the wall shear stress more accurately by capturing the movement of laminar, transition turbulent zones inside unstable natural circulation loops. This study shows that transition effects are a possible explanation for the highly loop-specific friction correlations observed in various oscillatory natural circulation loops.