• Nuclear Engineering and Technology
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• v.56 no.10
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• pp.4169-4175
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• 2024

Traditional physical methods for measuring solubility were often affected by viscosity, density, and surface tension. In this study, we selected appropriate electrolytes to determine the solubility of impurities in the lead-bismuth circuit at reactor operating temperatures using electrochemical methods. Taking the measurement of the solubility of impurity Ce in liquid Bi as an example, we demonstrated that electrochemical methods can accurately determine its solubility in the LiCl-KCl molten salt. Furthermore, the successful measurement of other impurities such as La, Ce, U, and Mn in lead-bismuth eutectic (LBE) using the designed system has confirmed the universality of this method.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.190-193
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• 2008

The heat transfer characteristics of molten salt storage system for the solar thermal power generation were investigated. Temperature profiles and the heat transfer coefficients during the storage and discharge stage were obtained with the steam as the heat transfer fluid. Two kinds of inorganic salt were employed as the storage materials and coil type of heat exchanger were installed in both tanks to provide the heat transfer surfaces during the storage and discharge stage. The effects of steam flow rates, flow direction of steam in the storage tank and the initial temperature of storage and discharge tank on the heat transfer were tested.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.10a
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• pp.71-72
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• 2017

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.05a
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• pp.161-162
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• 2017

• Solar Energy
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• v.8 no.1
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• pp.13-21
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• 1988

Heat transfer phenomena in a high-temperature heat storage unit were investigated using molten salts. Carbonate salt, an equimolar mixture of $Li_2CO_3$ and $K_2CO_3$, which melts at $505^{\circ}C$ with a latent heat of 82 cal/g, was selected as the most promising latent heat storage material based on its low cost and excellent thermophysical properties at moderately high temperatures. It was also found that nitrate salts were good candidates of sensible heat storage materials. For the carbonate salt to be utilized commercially, however, several means of enhancing thermal recovery must be explored by promoting heat conduction through the solid salt formed during the heat discharge period. These would be achieved by the additions of aluminum screens and wool, and stainless fins. Finally, experimental results of moving boundary of phase change were well compared with predictied values obtained from the approximate solution.

• Proceedings of the Korea Technology Innovation Society Conference
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• 2001.05a
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• pp.285-302
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• 2001

At the present time the desalination technology of sea water for portable water in islands employs the RO method. The technology which needs complicated pretreatment processes with various chemicals can generate secondary water pollution and the high maintenance costs such as replacements of filters and membranes make islanders nearly impossible to operate. The MVRS technology for desalination of sea water however has several advantages such as constant production of quality portable water and capability of managing broad operating load. The variable-speed turbo-type vapor compressors employed in the system can utilize wind energy which is abundant in most Korean islands. Salt as a by-product can be produced by applying solar energy to the salt-concentrated waste water from the system. This paper discusses the relating topics such as technical and economical viabilities of the new MVRS desalination system for the production of portable water and salt as a by-product using new & renewable sources of energy.

• Journal of Surface Science and Engineering
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• v.47 no.6
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• pp.282-286
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• 2014

Wear characteristic of the nitrided SKD61 which is a typical mold material using for the extrusion of Al6061 alloy was investigated. The surface of SKD61 was nitrided by salt bath and plasma processes. The thickness of surface nitride layer was about $8.9{\mu}m{\sim}21.3{\mu}m$. Reciprocating friction wear test conducted using pin on disk type indicated the plasma treatment followed salt bath has a lower friction coefficient and a smaller adhesive wear with Al6061 alloy. That was identified by the $Fe_4N$ which has a better wear resistance than FeN mainly formed by plasma nitriding.

• Bulletin of the Korean Chemical Society
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• v.12 no.2
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• pp.163-169
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• 1991

The photochemical and photophysical properties of N-(2-haloarylmethyl)pyridinium, N-(arylmethyl)-2-halopyridinium, N-(2-haloarylmethyl)-2-halopyridinium salts and N-(2-halobenzyl)-isoquinolinium salt are studied. The pyridinium salts photocyclize to afford isoindolium salts, while the isoquinolium salts do not. In the photocyclization of N-(2-chlorobenzyl)-2-chloropyridinium salts, pyrido[2,1-a]-4-chloroisoindolium salt is formed by the cleavage of chlorine of pyridinium ring. This indicates that the excited moiety is not the phenyl ring, but the pyridinium ring. The triplet states of the pyridinium salts are believed to be largely involved in the photocyclization, since oxygen retards most of the reaction. Some assistance of a ${\pi}$-complex between the excited chlorine moiety of the salt and phenyl plane of the same molecule is required to explain the reactivity of the salts. N-(Benzyl)-2-chloropyridinium salt is two times more reactive than N-(2-chlorobenzyl)pyridinium salt. N-(Benzyl)-2-chloropyridinium salt can form ${\pi}-complex$ effectively because of the electron-rich phenyl group. The ${\pi}$-complex affords an intermediate, phenyl radical by cleaving the chlorine atom. The photocyclized product, isoindolium salt is obtained by losing the hydrogen atom from the phenyl radical. The reactive pyridinium salts 1a, 2a and 3a have a low fluorescence quantum yield (${\Phi}F$ < 0.01) and a higher triplet energy (ET > 68 kcal/mole) than the unreactive quinolinium salt. The unreactivity of isoquinolinium salt can be understood in relation to its high fluorescence quantum yield and its low triplet energy $(E_T = 61 kcal/mole).$.

• Journal of the Korean Solar Energy Society
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• v.27 no.3
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• pp.63-69
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• 2007

The heat transfer characteristics of inorganic salt for high temperature heat storage material of solar power system were examined. The inorganic salts employed in this study was a mixture of $NaNO_3$ and $KNO_3$ and the operating temperature range was determined by measuring the melting temperature with DSC and by measuring the thermal decomposition temperature with TGA. The heat transfer characteristics was qualitatively obtained in terms of temperature profiles of salt in the tanks during the heat storage and heat release process as a function of steam flow rates, steam inlet temperature and the inlet position of steam. The effects of steam flow rates and inlet temperature of steam were experimentally determined and the effect of natural convection was observed due to significant density difference with temperature.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.560-565
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• 2014

Alumina nano-asperites were grown on plate-like alumina particles of which the surface had been covered with a capping agent to control the asperite formation sites on the particles. Utilized alumina source for asperite was nano sized ${\gamma}$-alumina, which was prepared by calcination of $Al(OH)_3$ at $600^{\circ}C$; silica suspension was used as the capping agent. Plate like alumina particles were covered by silica suspension and continuously heat-treated to $900^{\circ}C$ with nano sized ${\gamma}$-alumina, as the source material, under molten-salt atmosphere. Asperite growing site were controlled by the degree of coating of the capping agent; 10-20 nanosize of ${\theta}$-alumina were formed on the particle surface. On the other hand, alumina particles without capping agent were observed to undergo only step-like crystal growth during heat-treatment.