• Title/Summary/Keyword: Energy release rate

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Detachment of nanoparticles in granular media filtration

  • Kim, Ijung;Zhu, Tongren;Jeon, Chan-Hoo;Lawler, Desmond F.
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.1-10
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    • 2020
  • An understanding of particle-particle interactions in filtration requires studying the detachment as well as the attachment of nanoparticles. Nanoparticles captured in a granular media filter can be released by changing the physicochemical factors. In this study, the detachment of captured silver nanoparticles (AgNPs) in granular media filtration was examined under different ionic strengths, ion type, and the presence or absence of natural organic matter (NOM). Filtration velocity and ionic strength were chosen as the physical and chemical factors to cause the detachment. Increasing filtration velocity caused a negligible amount of AgNP detachment. On the other hand, lowering ionic strength showed different release amounts depending on the background ions, implying a population of loosely captured particles inside the filter bed. Overall detachment was affected by ionic strength and ion type, and to a lesser degree by NOM coating which resulted in slightly more detachment (in otherwise identical conditions) than in the absence of that coating, possibly by steric effects. The secondary energy minimum with Na ions was deeper and wider than with Ca ions, probably due to the lack of complexation with citrate and charge neutralization that would be caused by Ca ions. This result implies that the change in chemical force by reducing ionic strength of Na ions could significantly enhance the detachment compared to that caused by a change in physical force, due to a weak electrostatic deposition between nanoparticles and filter media. A modification of the 1-D filtration model to incorporate a detachment term showed good agreement with experimental data; estimating the detachment coefficients for that model suggested that the detachment rate could be similar regardless of the amount of previously captured AgNPs.

Effect of Center Pin in Free Fall Test for a Cylindrical Li-ion Cell (원형 리튬 전지의 센터 핀이 낙하 충격에 미치는 영향)

  • Kim, Simon;Lee, Young Shin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.6
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    • pp.639-644
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    • 2015
  • A cylindrical secondary Li-ion cell is a device in which stored chemical energy is converted to electrical energy via an electrochemical reaction. These cells are widely used for applications that require high capacity and rate power, such as notebooks, power tools, and electric vehicles. The role of a center pin is to retain the channel for gas release, preventing blockage of the hollow of the jelly roll during a charge-discharge cycle, and to prevent an internal short circuit for tearing of separator under mechanical free fall. In this paper, two experiments are conducted with and without the center pin to experimentally verify the importance of the role of the center pin. The first experiment is a 50-cycle charge-discharge cycle test, and the second is a free fall test conducted according to the Underwriters Laboratories (UL) standards. Based on these experiments, we demonstrate that the center pin in a cylindrical cell is a very important component in terms of safety.

Influence of SiC on Thermal Stabilities and Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites (탄화규소의 첨가가 탄소섬유 강화 복합재료의 열안정성 및 기계적 계면특성에 미치는 영향)

  • Oh Jin-Seok;Park Soo-Jin;Lee Jae-Rock;Kim Yeung-Keun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.182-185
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    • 2004
  • In this work, the effect of chemical treatments on surface properties of SiC was investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the SiC were determined by acid/base values and contact angles. The thermal stabilities of carbon fibers-reinforced composites were investigated by thermogravimetric analysis (TGA). Also, the mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical strain energy release rate mode II $(G_{IIC})$ measurements. As a result, tile acidically treated SiC (A-SiC) had higher acid value than that of untreated SiC (V-SiC) or basically treated SiC (B-SiC). According to the contact angle measurements, it was observed that chemical treatments led to an increase of surface free energy of the SiC surfaces, mainly due to the increase of the specific (polar) component. The mechanical interfacial properties of the composites, including ILSS and $(G_{IIC})$, had been improved in the specimens treated by chemical solutions. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between SiC and epoxy resin matrix.

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Cure Behaviors and Mechanical Interfacial Properties of Epoxy/Polyurethane Blends Initiated by Latent Thermal Catalyst (열잠재성 개시제에 의한 에폭시/폴리우레탄 블렌드의 경화거동 및 파괴인성)

  • Park, Soo-Jin;Seok, Su-Ja;Kang, Jun-Gil;Kwon, Soo-Han
    • Elastomers and Composites
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    • v.39 no.1
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    • pp.42-50
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    • 2004
  • In this work, the diglycidylether of bisphenol A (DGEBA) and modified polyurethane (PU) blends were initiated by N-benzylpyrazinium hexafluoroantimonate (BPH). The cure and fracture toughness of neat DGEBA with the addition of PU were investigated. The cure properties of DGEBA/PU blend system were examined by DSC and near-IR measurements. The fracture touhtness were investigated by measuring the critical stress intensity factor ($K_{IC}$) and the critical strain energy release rate ($G_{IC}$). According to the results, the maximum values of owe activation energy ($E_a$) and conversion (${\alpha}$) were found at 10 phr of PU. Also the $K_{IC}$ showed a similar behavior with the results of conversion. These results were probably due to increase of crosslinking density in the blends resulted from increase of the hydrogen bonding between the hydroxyl groups of DGEBA and isocyanate groups of PU.

An Experimental Study on the Three Dimensional Turbulent Flow Characteristics of Swirl Burner for Gas Furnace (가스난방기용 스월버너의 3차원 난류유동 특성에 관한 실험적 연구)

  • Kim, Jang-Gwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.2
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    • pp.225-234
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    • 2001
  • This paper represents the vector fields, three dimensional mean velocities, the turbulent intensities, the turbulent kinetic energy, and the Reynolds shear stresses in the X-Y plane of gas swirl burner with a cone type baffle plate measured by using X-probe from hot-wire anemometer system. This experiment is carried out at flow rates 350 and 450ℓ/min respectively, which are equivalent to the combustion air flow rate necessary for heat release 15,000 kcal/hr in gas furnace, in the test section of subsonic wind tunnel. The vector plot shows that the maximum axial mean velocity component exists in the narrow slits situated radially on the edge of gas swirl burner, for that reason, there is some entrainment phenomena of ambient air in the outer region of burner. Moreover, mean velocities in the initial region are largely distributed near the outer region of burner at Y/R≒0.97, but they diffuse and develop into the center flow region of burner according to the increase of axial distance. The turbulent intensities and the turbulent kinetic energy due to large inclination of mean velocity and swirl effect show that the maximum value in the initial region of burner is formed in the narrow slits situated radially on the edge of gas swirl burner and large values are mainly formed in the entire region of burner after X/R=2.4358, hence, the combustion reaction is anticipated to occur actively near this region. And the Reynolds shear stresses are also largely distributed from slite to vanes of gas swirl burner in the intial region, but their values largely disappear after X/R=3.2052.

Implementation of an Electrode Positioning System to Improve the Accuracy and Reliability of the Secondary Battery Stacking Process (2차 전지 적층 공정의 정확성과 신뢰성 향상을 위한 전극 위치결정 시스템 구현)

  • Lee, June-Hwan
    • Journal of Convergence for Information Technology
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    • v.11 no.6
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    • pp.219-225
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    • 2021
  • As for the battery package method, a prismatic package method is preferred for stability reasons, but it is rapidly expanding due to the stability verification of a pouch type package. The pouch type using the lamination process has an advantage of high battery energy density because it can reduce space waste, but has a disadvantage of low productivity. Therefore, in this paper, by extracting edge detection algorithm precision, pattern algorithm precision, and motion controller recall rate by improving backlight lighting fixtures to minimize light diffusion, securing standards for stereo camera position relationship displacement monitoring, and securing standards for lens release monitoring. We propose to implement a system that ensures accuracy and reliability in positioning. As a result of the experiment, the proposed system shows an average error range of 0.032mm for edge detection, 0.02mm for pattern algorithm, and 0.014mm for motion controller, thus ensuring the accuracy and reliability of the positioning mechanism.

Establishing the Concept of Buffer for a High-level Radioactive Waste Repository: An Approach (고준위폐기물처분장의 완충재 개념 도출: 접근방안)

  • Lee, Jae Owan;Lee, Minsoo;Choi, Heuijoo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.4
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    • pp.283-293
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    • 2015
  • The buffer is a key component of the engineered barrier system in a high-level radioactive waste (HLW) repository. The present study reviewed the requirements and functional criteria of the buffer reported in literature, and also based on the results, proposed an approach to establish a buffer concept which is applicable to an HLW repository in Korea. The hydraulic conductivity, radionuclide-retarding capacity (equilibrium distribution coefficient and diffusion coefficient), swelling pressure, thermal conductivity, mechanical properties, organic carbon content, and illitization rate were considered as major technical parameters for the functional criteria of the buffer. Domestic bentonite (Ca-bentonite) and, as an alternative, MX-80 (Na-bentonite) were proposed for the buffer of an HLW repository in Korea. The technical specifications for those proposed bentonites were set to parameter values that conservatively satisfy Korea's functional criteria for the Ca-bentonite and Swedish criteria for the Na-bentonite. The thickness of the buffer was determined by evaluating the means of shear behavior, radionuclide release, and heat conduction, which resulted in the proper buffer thickness of 0.25 to 0.5 m. However, the final thickness of the buffer should be determined by considering coupled thermal-hydraulic-mechanical evaluation and economics and engineering aspects as well.

Static and Dynamic Fracture Analysis for the Interface Crack of Isotropic-Orthotropic Bimaterial

  • Lee, Kwang-Ho;Arun Shukla;Venkitanarayanan Parameswaran;Vijaya Chalivendra;Hawong, Jae-Sug
    • Journal of Mechanical Science and Technology
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    • v.16 no.2
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    • pp.165-174
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    • 2002
  • In the present study, interfacial cracks between an isotropic and orthotropic material, subjected to static far field tensile loading are analyzed using the technique of photoelasticity. The fracture parameters are extracted from the full-field isochromatic data and the same are compared with that obtained using boundary collocation method. Dynamic photoelasticity combined with high-speed digital photography is employed for capturing the isochromatics in the case of propagating interfacial cracks. The normalized stress intensity factors for static cracks are greate. when ${\alpha}$: 90$^{\circ}$(fibers perpendicular to the interface) than when ${\alpha}$=0$^{\circ}$(fibers parallel to the interface), and those when ${\alpha}$=90$^{\circ}$are similar to ones of isotropic material. The dynamic stress intensity factors for interfacial propagating cracks are greater when ${\alpha}$=0$^{\circ}$ than ${\alpha}$=90$^{\circ}$. For the velocity ranges (0.1 < C/C$\sub$s1/<0.7) observed in this study, the complex dynamic stress intensity factor │K$\sub$D/│increases with crack speed c, however, the rate of increase of │K$\sub$D/│with crack speed is not as drastic as that reported for homogeneous materials.

The Role of Slits and Swirl Vanes on the Turbulent Flow Fields in Cone Type Gas Burner (콘형 가스버너의 난류유동장에 대한 슬릿과 스월베인의 역할)

  • Kim, Jang-Kweon;Jeong, Kyu-Jo
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.341-346
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    • 2001
  • The gun-type gas burner adopted in this study is generally composed of some slits and swirl vanes. Therefore, this paper is studied to investigate the effect of slits and swirl vanes on the turbulent flow fields in the horizontal plane of gas swirl burner with a cone type baffle plate measured by using X-probe from hot-wire anemometer system. This experiment is carried out at flow rate $450\;{\ell}/min$, which is equivalent to the combustion air flow rate necessary for heat release 15,000 kcal/hr in gas furnace, in the test section of subsonic wind tunnel. When the burner has only swirl vanes, the axial mean velocity component shows the characteristic that spreads more remarkably toward radial direction than axial one, but when it has only slits, that is developed spreading more toward axial direction than radial one. Therefore, because the biggest speed is spurted in slits and it derive main flow toward axial direction encircling rotational flow that comes out from swirl vane that is situated on the inside of slits, both slits and swirl vanes composing of cone type gas burner act role that decreases the speed near slits and increases the flow speed in the central part of a burner. Moreover, because rotational flow by swirl vanes and fast jet flow by slits increase turbulent intensities effectively coexisting, the turbulent kinetic energy is distributed with a bigger size fairly near slits than burner models which have only slit or swirl vanes within X/R<0.6410.

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Feasibility Study on the Fire Scenario Design of a Couch Burning through a Fire Spread Model (화염 전파모델을 이용한 소파화재 설계화원구성의 적용성 연구)

  • Kim, Sung-Chan
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.37-42
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    • 2016
  • The present study has been performed to examine the feasibility of a flame spread model on the design fire scenario for fire risk analysis. Thermo-Gravimetric analysis and sample burning test were conducted to obtain the material properties of a single couch covered with synthetic leather material and a series of FDS calculations applying with the measured material properties were performed for different grid sizes. The overall fire growth characteristics predicted by the fire model were quite different from the results of a real scale fire test and the initial peak value of the HRR and total released energy showed the results within a 30% discrepancy for the computational grids used in the present study. The current model has some limitations in predicting the fire growth characteristics, such as fire growth rate and the time to the maximum HRR. This study shows that the fire model may be applicable to creating the design fire scenario through continuous model improvement and detailed material properties.