• Title/Summary/Keyword: Energy carrier

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Properties of Silicon Nitride Deposited by LF-PECVD with Various Thicknesses and Gas Ratios (가스비와 두께 가변에 따른 실리콘질화막의 특성)

  • Park, Je-Jun;Kim, Jin-Kuk;Lee, Hi-Deok;Kang, Gi-Hwan;Yu, Gwon-Jong;Song, Hee-Eun
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.154-157
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    • 2011
  • Hydrogenated silicon nitride deposited by LF-PECVD is commonly used for anti-reflection coating and passivation in silicon solar cell fabrication. The deposition of the optimized silicon nitride on the surface is elemental in crystalline silicon solar cell. In this work, the carrier lifetimes were measured while the thicknesses of $SiN_x$ were changed from 700 ${\AA}$ to 1150 ${\AA}$ with the gas flow of $SiH_4$ as 40 sccm and $NH_3$ as 120 sccm,. The carrier lifetime enhanced as the thickness of $SiN_x$ increased due to improved passivation effect. To study the characteristics of $SiN_x$ with various gas ratios, the gas flow of $NH_3$ was changed from 40 sccm to 200 sccm with intervals of 40 sccm. The thickness of $SiN_x$ was fixed as 1000 ${\AA}$ and the gas flow of $SiH_4$ as 40 sccm. The refractive index of SiNx and the carrier lifetime were measured before and after heat treating at $650^{\circ}C$ to investigate their change by the firing process in solar cell fabrication. The index of refraction of SiNx decreased as the gas ratios increased and the longest carrier lifetime was measured with the gas ratio $NH_3/SiH_4$ of 3.

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Preliminary Economic Analysis for H2 Transportation Using Liquid Organic H2 Carrier to Enter H2 Economy Society in Korea (수소경제사회 실현을 위한 액체 유기 수소캐리어를 이용한 수소 수송 관련 예비 경제성 평가)

  • LEE, BOREUM;LEE, HYUNJUN;MOON, CHANGHWAN;MOON, SANGBONG;LIM, HANKWON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.119-127
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    • 2019
  • Reliable $H_2$ supply is necessary for entering a $H_2$ society. Among the various $H_2$ storage and transportation methods, liquid organic $H_2$ carrier (LOHC) is in the spotlight because of a lot of advantages compared to conventional one such as compressed $H_2$ and liquefied $H_2$. Therefore, we performed preliminary economic analysis of $H_2$ supply cost using LOHC for a $H_2$ production capacity of $300Nm^3\;h^{-1}$ employing itemized cost estimation and sensitivity analysis to evaluate economic viability of this technology in Korea.

Performance Estimation and Process Selection for Chemical-Looping Hydrogen Generation System (금속매체 순환식 수소생산 시스템의 성능예측 및 공정선정)

  • Ryu, Ho-Jung;Jin, Gyoung-Tae
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.3
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    • pp.209-218
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    • 2005
  • To find a suitable metal component in oxygen carrier particles for chemical-looping hydrogen generation system(CLH), oxygen transfer capacities of metal components were compared and Ni has been selected as the best metal component. The proper operating conditions to achieve high hydrogen generation rate have been investigated based on the chemical-equilibrium composition analysis for water splitting reactor. Moreover, suitable compositions of syngas from gasifier of heavy residue to achieve high energy efficiency have been investigated by calculation of heat of reaction. Based on the selected operating conditions, the best configuration of two interconnected fluidized beds system for the chemical-looping hydrogen generator has been investigated as well.

Observation of Carrier Multiplication via Internal Quantum Efficiency Exceeding 100% in PbS QDs Monolayer Solar Cells

  • Park, So Yeon;Chung, Hyun Suk;Han, Gill Sang;Su, Jang Ji;Jung, Hyun Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.467.1-467.1
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    • 2014
  • Quantum dots (QD) solar cells has received considerable attention due to their potential of improving the overall conversion efficiency by harvesting excess energy via multiple excitons generation (MEG). Although there have been many reports which show MEG phenomena by using optical measurement of quantum dots themselves, carrier multiplication in real QD photovoltaic devices has been sparsely reported due to difficulty in dissociation of excitons and charge collection. In this reports, heterojunction QD solar cells composed of PbS QD monolayer on highly crystalline $TiO_2$ thin films were fabricated by using Langmuir-Blodgett deposition technique to significantly reduce charge recombination at the interfaces between each QD. The PbS CQDs monolayer was characterized by using UV-vis, transmission electron microscopy (TEM) and atomic force microscopy (AFM). The internal quantum efficiency (IQE) for the monolayer QD solar cells was obtained by measurement of external quantum efficiency and determining light absorption efficiency of active layer. Carrier multiplication was observed by measuring IQE greater than 100% over threshold photon energy. Our findings demonstrate that monolayer QD solar cell structure is potentially capable of realizing highly efficient solar cells based on carrier multiplication.

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The Hydrogen Generation's Characteristics using Plasma Reactor of Multi-needle Electrode Type (다중침전극형 플라즈마 반응기를 이용한 수소발생 특성)

  • Park, Jae-Yoon;Kim, Jong-Seok;Jung, Jang-Gun;Goh, Hee-Seok;Park, Sang-Hyun;Lee, Hyun-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1246-1251
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    • 2004
  • This paper is investigated about the effect of carrier gas type and the humidity for generating hydrogen gas. The vibration of the water surface is more powerful with increasing applied voltage. In this experimental reactor which is made of multi-needle and plate, the maximum acquired hydrogen production rate is about 3500 ppm. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with water droplet by humidifier and without water droplet by humidifier, the generation of hydrogen gas is decreased in case of water droplet by humidifier. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small water molecular produced from humidifier.

열선 CVD를 이용한 a-Si:H의 c-Si표면 passivation 및 열처리 효과 분석

  • Jeong, Dae-Young;Kim, Chan-Seok;Song, Jun-Yong;Wang, Jin-Suk;Park, Sang-Hyun;Lee, Jeong-Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.397-397
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    • 2009
  • c-Si wafer에 HWCVD로 증착된 a-Si:H 박막은 초기에 낮은 passivation 특성을 가지나 열처리 공정을 통해 효과적인 passivation을 가진다. 열처리 공정은 온도와 시간에 따라 큰 차이를 보인다. 이에 열선CVD를 이용하여 n type의 c-Si 기판에 a-Si:H을 증착하여 열처리 온도에 따른 Minority carrier Lifetime를 QSSPC를 통해 passivation 특성을 측정하였다. 온도는 $150^{\circ}C{\sim}270^{\circ}C$로 변화하여 측정하였다. 또한 열처리 시간을 10분씩 증가시켜 열처리 시간에 따른 passivation을 연구, 1ms에 이르는 Minority carrier lifetime을 얻었다.

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Characteristics of VOx Thin Film, NiOx Thin Film, and CuIx Thin Film for Carrier Selective Contacts Solar Cells (전하선택접촉 태양전지 적용을 위한 VOx 박막, NiOx 박막, CuIx 박막의 특성 연구)

  • Kiseok Jeon;Minseob Kim;Eunbi Lee;Jinho Shin;Sangwoo Lim;Chaehwan Jeong
    • Current Photovoltaic Research
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    • v.11 no.2
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    • pp.39-43
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    • 2023
  • Carrier-selective contacts (CSCs) solar cells are considerably attractive on highly efficient crystalline silicon heterojunction (SHJ) solar cells due to their advantages of high thermal tolerance and the simple fabrication process. CSCs solar cells require a hole selective contact (HSC) layer that selectively collects only holes. In order to selectively collect holes, it must have a work function characteristic of 5.0 eV or more when contacted with n-type Si. The VOx, NiOx, and CuIx thin films were fabricated and analyzed respectively to confirm their potential usage as a hole-selective contact (HSC) layer. All thin films showed characteristics of band-gap engergy > 3.0 eV, work function > 5.0 eV and minority carrier lifetime > 1.5 ms.

Characterization of Absorption Process of Taurine Across Rat Small Intestine

  • Kim, Kyung-Soon
    • Archives of Pharmacal Research
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    • v.6 no.2
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    • pp.109-114
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    • 1983
  • A mechanism of taurine transfer across the rat small intestine was elucidated by using the in situ recirculation perfusion or loop method. Taurine uptake was saturable, Km= 39.9 mM, and energy dependent, and required sodium. The close structural analogues, aminomethane sulfonic acid, .gamma.-amino-butyric acid, hypotaurine, and .betha.-alanine, reduced significantly taurine uptake when present in 10-fold excess. The .alpha.-amino acid, glycine, did not inhibit uptake. Hence, all of these findings lead to a conclusion that a carrier-mediated transport system for taurine exists in the small intestine.

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Reduction Characteristics of Oxygen Carrier Particles for Chemical-looping Combustor with Different Fuels (매체순환식 가스연소기용 산소공여입자들의 연료별 연소특성)

  • Ryu, Ho-Jung;Kim, Kyung-Su;Park, Yeong-Seong;Park, Moon-Hee
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.1
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    • pp.45-54
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    • 2009
  • Reduction reactivity and carbon deposition characteristics of three oxygen carrier particles(OCN01, OCN02, OCN03) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all particles, the maximum conversion, the oxygen transfer capacity, and the degree of carbon deposition increased as the reactive carbon contents increased. The reduction rate and the oxygen transfer rate increased as the moles of required oxygen per input gas increased. The change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels can be explained consistently by using parameters such as the reactive carbon contents and the moles of require oxygen per input gas.