• Title/Summary/Keyword: Energy basic unit

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Ammonia Decomposition over Ni Catalysts Supported on Zeolites for Clean Hydrogen Production (청정수소 생산을 위한 암모니아 분해 반응에서 Ni/Zeolite 촉매의 반응활성에 관한 연구)

  • Jiyu Kim;Kyoung Deok Kim;Unho Jung;Yongha Park;Ki Bong Lee;Kee Young Koo
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.19-26
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    • 2023
  • Hydrogen, a clean energy source free of COx emissions, is poised to replace fossil fuels, with its usage on the rise. Despite its high energy content per unit mass, hydrogen faces limitations in storage and transportation due to its low storage density and challenges in long-term storage. In contrast, ammonia offers a high storage capacity per unit volume and is relatively easy to liquefy, making it an attractive option for storing and transporting large volumes of hydrogen. While NH3 decomposition is an endothermic reaction, achieving excellent low-temperature catalytic activity is essential for process efficiency and cost-effectiveness. The study examined the effects of different zeolite types (5A, NaY, ZSM5) on NH3 decomposition activity, considering differences in pore structure, cations, and Si/Al-ratio. Notably, the 5A zeolite facilitated the high dispersion of Ni across the surface, inside pores, and within the structure. Its low Si/Al ratio contributed to abundant acidity, enhancing ammonia adsorption. Additionally, the presence of Na and Ca cations in the support created medium basic sites that improved N2 desorption rates. As a result, among the prepared catalysts, the 15 wt%Ni/5A catalyst exhibited the highest NH3 conversion and a high H2 formation rate of 23.5 mmol/gcat·min (30,000 mL/gcat·h, 600 ℃). This performance was attributed to the strong metal-support interaction and the enhancement of N2 desorption rates through the presence of medium basic sites.

A Study on the Characteristics of Local Energy Consumption by Using Index Decomposition Analysis (지수분해분석을 이용한 지자체의 에너지 소비특성에 관한 연구)

  • Jin, Sang Hyeon;Hwang, In Chang
    • Environmental and Resource Economics Review
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    • v.18 no.4
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    • pp.557-586
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    • 2009
  • Although energy demand management policy attracts attention internationally and domestically, the importance of local government in this policy is not so much as central government. But local government can do a role with regard to this policy because it is close to energy consumers not like central government. So local energy plan should be based on the understanding local energy consumption characteristics to activate local energy demand management policy. This paper tries to analyze energy characteristics of 16 local governments by decomposing energy consumption into population, production and intensity factors. The result of index decomposition analysis shows that energy intensity improvement has offset the increase of energy consumption caused by economic growth in the metropolitan cities, while it couldn't offset in the other provinces because of industrialization based on the manufacturing. In conclusion, this paper suggests that it will be necessary to switch to low energy society by carrying out concrete energy efficiency improvement projects in the metropolitan cities while it will be helpful to make a local development plan for low energy intensive industrialization in the other provinces.

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A Study on Rhythm Information Visualization Using Syllable of Digital Text (디지털 텍스트의 음절을 이용한 운율 정보 시각화에 관한 연구)

  • Park, seon-hee;Lee, jae-joong;Park, jin-wan
    • Proceedings of the Korea Contents Association Conference
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    • 2009.05a
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    • pp.120-126
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    • 2009
  • As the information age grows rapidly, the amount of digital texts has been increasing as well. It has brought an increasing of visualization case in order to figure out lots of digital texts. Existing visualized design of digital text is merely concentrating on figuration of subject word through adoption of stemming algorithm and word frequency extraction, prominence of meaning of text, and connection in between sentences. So it is a fact that expression of rhythm that can visualize sentimental feeing of digital text was insufficient. Syllable is a phoneme unit that can express rhythm more efficiently. In sentences, syllable is a most basic pronunciation unit in pronouncing word, phase and sentence. On this basis, accent, intonation, length of rhythm factor and others are based on syllable. Sonority, which is most closely associated with definitions of syllable, is expressed through air flow of igniting lung and acoustic energy that is specified kinetic energy into sonority. Seen from this perspective, this study examines phonologic definition and characteristics based on syllable, which is properties of digital text, and research the way to visualize rhythm through diagram. After converting digital text into phonetic symbol by the experiment, rhythm information are visualized into images using degree of resonance, which was started from rhythm in all languages, and using syllable establishment of digital text. By visualizing syllable information, it provides syllable information of digital text and express sentiment of digital text through diagram to assist user's understanding by systematic formula. Therefore, this study is aimed at planning for easy understanding of text's rhythm and realizing visualization of digital text.

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An Application of the Enrichment Zoning Concept to $17\times{17}$ KOFA ($17\times{17}$ 국산 핵연료에의 다중농축도 개념 적용)

  • Kim, K.S.;Kim, J.H.;Zee, S.K.;Song, J.W.
    • Nuclear Engineering and Technology
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    • v.26 no.3
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    • pp.337-344
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    • 1994
  • Enthalpy rise hot channel factor($F_{\Delta{H}}$$^{N}$) is one of the most limiting constraints in determining the fuel loading pattern(LP) for PWR's. In order to enhance the LP design flexibility without any changes of not only basic fuel specifications but also Technical Specifications and Operation Procedures, we apply the enrichment zoning concept to Westinghouse designed PWR's to flatten the rod power distributions within the fuel assembly and thus to reduce $F_{\Delta{H}}$$^{N}$. Enrichment zoning is described that each assembly consists of two different enrichment fuels ; the lower enriched fuels are located in positions which are expected to have the higher rod power and vice versa for the higher enriched fuels. As a result of unit assembly calculations to flatten the rod power distribution within the assembly, the appropriate enrichment difference is found to be 0.3~0.4w/o. Through core depletion calculations for the 18-month cycle of Kori Unit 4, the $F_{\Delta{H}}$$^{N}$ behavior in core with the enrichment zoning concept is investigated. A comparison with the reference case without the enrichment zoning results in a reduction in $F_{\Delta{H}}$$^{N}$ of approximately 1.5%.TEX>H/$^{N}$ of approximately 1.5%.

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Analysis of Heating and Desalination Cycle Using Low Temperature Seawater (저온 해수를 이용한 난방 및 담수화사이클 성능 해석)

  • Lee, H.S.;Lee, S.W.;Jung, D.H.;Moon, D.S.;Kim, H.J.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.4
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    • pp.301-306
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    • 2011
  • The paper presents an analysis of the heating cycle and discusses a desalination cycle that uses lowtemperature seawater. The basic heating cycle model is the heat pump cycle, and seawater desalination is usually performed by the indirect freezing desalination method. The low temperature of the seawater (below $5^{\circ}C$) acts as the heat source of the evaporator. R-134a, R-1234yf, R-600a are used as working fluids. In the 2-stage compression cycle, the compressor's work decreased by about 15.6% from that in the 1-stage compression cycle. Further, the COP in the 2-stage cycle was 17.6% higher than that in the 1-stage cycle. In the indirect desalination cycle, the energy per unit fresh water productivity in the 2-stage cycle was 19.8% lower than that in the 1-stage cycle.

Study on the Composition of Acupoints of Eight Constitution Acupuncture (8체질침의 혈위구성에 관한 연구)

  • Jeong, Sang-Jee;Kim, Byung-Soo;Kang, Jung-Soo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.22 no.6
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    • pp.1397-1402
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    • 2008
  • As eight constitution acupuncture began to be applied in clinics, the acupuncture method and the method of differentiating constitution became widely known. However, no official principles of composing acupuncture prescriptions have been established so far. Therefore, this study examined unique and novel interpretations among a variety of theories on the composition of acupoints of eight constitution medicine. The basic principles of the general formula of unit prescription discussed in the study are that the compatibility and incompatibility of the five elements is acknowledged not in one way but in interactive way, and that when an energy shown in the compatibility and incompatibility chart of five elements is tonified, its two neighboring competible energies are tonified due to the effects of compatibility. On the other hand, two other energies which are incompatible with the energy and exist on the opposite side of it are sedated due to the effect of incompatibility. In contrast, when an energy is sedated, its two neighboring competible energies are sedated while two other energies in incompatible with it are tonified. In addition, eight constitution acupuncture could be explained as a variant of Saam acupuncture. It is unfortunate that there exist no established theory but hypotheses with regard to the composition of acupoints of eight constitution acupuncture. It is expected that young scholars will produce better results if they continue researching eight constitution acupuncture.

Structural Safety Evaluation for Fixed CO2 Extinguishing Systems Under Ship Motion (선박모션에 따른 고정식 CO2소화 장치 구조안전성 평가)

  • Kim, Seung Chan;Kang, Sang Hoon;Choi, Joo Hyoung;Kim, Jeong-Hwan;Park, Young Chul
    • Transactions of the KSME C: Technology and Education
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    • v.4 no.2
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    • pp.75-83
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    • 2016
  • Since fire is one of the most dangerous threats to the safety of the ship, from the safety device is installed on the vessel the digestive apparatus can be viewed as the most important safety device. The fire-extinguishing device to be mounted to the vessel structure affected the stability of the structure in accordance with the blue of the sea. In particular, the Rack part of the basic safety of a fixed fire extinguishing system in the absence of a $CO_2$ container. In this paper, by utilizing simulation techniques to apply the pressure data being ejected in each direction by ship motion and $CO_2$ containers Rack perform an analysis of the structural safety assessment was part of the digestive system accordingly.

Influence of Flowing Velocity and Length of Delivery Hoses on Power Requirement of Agricultural pump. (각종 송출 호오스의 구경 및 길이가 농용양수로의 소요동력에 미치는 영향)

  • 김기대;김성래;이한만
    • Journal of Biosystems Engineering
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    • v.4 no.2
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    • pp.46-52
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    • 1979
  • The water delivery hose for agricultural pump is getting popular in rural areas in korea. Friction head loss, discharge, and power requirements were measured in various discharge for different material and diameter of hose to get basic data for economical use in agricultural pump. The results attained in this study were as follows ; 1. Friction head loss increased significantly as the velocity increased, and the difference of velocity between the different diameter of hose was bigger than that between materials, which was resulted in the increase of the friction head loss. 2. Friction head loss in the case of that the velocity with 2m/sec was constant was about 3.53 to 4.01 m/100m in the diameter 3" and about 2.30 to 3.10 m/100m in the diameter 4". Material A of diameter 3" showed the maximum value 8.4m/100m in Reynolds number $2.0\times10^5$, 4" got the minimum value 2.24m/100m, the difference between these values was bigger than 6m per 100 meters in the friction head loss. 3. Darcy-Weisbach formular with friction coefficient [f] calculated by Nikurades formular in the smooth pipe or with friction coefficient [f] calculated on the base of C value 125 in Hazen-Williams formular was available in friction head loss of the water discharger hose in rural areas. 4. Total head increased as friction head loss increased , meanwhile total discharge decreased, and 20 percents of energy was more saved in Material C 4″pipe than Material A 3″pipe in the view point from the discharge per unit power requirement, this phenomenon suggested that long distance pipe would be advantage in larger diameter pipe for save of energy. for save of energy.

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Significance of Nanotechnology and Preparation Methods of Bioactive Organic Nanoparticle (나노 기술의 중요성과 생체 활성 유기 나노 입자의 제조법)

  • Yu, Ji-Yeon;Choe, Ji-Yeon;Kim, Gi-Hyeon;Lee, Jong-Chan;Lee, Jong-Hwi
    • Journal of Dairy Science and Biotechnology
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    • v.23 no.1
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    • pp.9-17
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    • 2005
  • Nanotechnology has penetrated into the various branches of research and development and it is particularly of benefit to the particle size engineering. It has been widely known that the particle size of an active pharmaceutical ingredient (API) is critical in determining the bioavailability and processability of pharmaceutical formulation. However, the window of appropriate particle size has been limited mainly due to related processing difficulties. The windows have been widened by the recent development of nanotechnologies, resulting in diversified drug delivery systems. The impact of this development is far more fundamental than what can be expected from conventional particle size engineering. It is the case that the preparation and use of nanoparticles will soon be a common task in the particle engineering step of pharmaceutical unit operations. In this chapter, the basic principles of variouspreparation techniques will be discussed in detail. Regardless of processing details, the preparation methods of pharmaceutical nanoparticles mainly concern how to deal with the extra energy related with particle size. Depending on the ways of treating the e103 energy, preparation methods can be classified into two major classes, i.e.. thermodynamic and kinetic approaches. The recent progresses have shown the possibilities of much more complex combinations of different approaches and the use of new types of energy and nanostructures.

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A Study on the X-ray Image Reading of Radiological Dispersal Device (방사능 폭발물의 X-ray 영상판독에 관한 연구)

  • Geun-Woo Jeong;Kyong-Jin Park
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.2_2
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    • pp.437-443
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    • 2024
  • The purpose of radiological Dispersal Device(RDD) is to kill people by explosives and to cause radiation exposure by dispersing radioactive materials. And It is a form of explosive that combines radioactive materials such as Co-60 and Ir-192 with improvised explosives. In this study, we tested and evaluated whether it was possible to read the internal structure of an explosive using X-rays in a radioactive explosive situation. The improvised explosive device was manufactured using 2 lb of model TNT explosives, one practice detonator, one 9V battery, and a timer switch in a leather briefcase measuring 41×35×10 cm3. The radioactive material used was the Co-60 source used in the low-level gamma ray irradiation device operated at the Advanced Radiation Research Institute of the Korea Atomic Energy Research Institute. The radiation dose used was gamma ray energy of 1.17 MeV and 1.33 MeV from a Co-60 source of 2208 Ci. The dose rates are divided into 0.5, 1, 2, and 4 Gy/h, and the exposure time was divided into 1, 3, 5, and 10 minutes. Co-60 source was mixed with the manufactured explosive and X-ray image reading was performed. As a result of the experiment, the X-ray image appeared black in all conditions divided by dose rate and time, and it was impossible to confirm the internal structure of the explosive. This is because γ-rays emitted from radioactive explosives have higher energy and stronger penetrating power than X-rays, so it is believed that imaging using X-rays is limited By blackening the film. The results of this study are expected to be used as basic data for research and development of X-ray imaging that can read the internal structure of explosives in radioactive explosive situations.