• Title/Summary/Keyword: Energy barrier model

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Theoretical and Experimental Studies on the Kinetics of Cation Redistribution Processes in Complex Oxides

  • Shi, Jianmin;Becker, Klaus-Dieter
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.39-46
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    • 2010
  • The kinetics of cation reequilibration have been studied theoretically and experimentally in complex oxides after an external perturbation of equilibrium by temperature jumps. A general kinetic model for cation redistribution amongst non-equivalent sites in complex oxides is derived based on a local homogeneous point defect mechanism involving cation vacancies. Temperature-jump optical relaxation spectroscopy has been established to investigate cation kinetic processes in spinels and olivines. The kinetic model satisfactorily describes the experimental absorbance relaxation kinetics in cobalt containing olivines and in nickel containing spinels. It is found that the kinetics of cation redistribution in complex oxides shows a strong temperature- and composition-dependence. Activation energies for cation redistribution in Co-Mg olivines are found to range between 200 and 220 kJ/mol whereas an energy barrier of about 230 kJ/mol is observed in the case of nickel gallate spinel.

INTERPARTICLE POTENTIAL OF 10 NANOMETER TITANIUM NANOPARTICLES IN LIQUID SODIUM: THEORETICAL APPROACH

  • KIM, SOO JAE;PARK, GUNYEOP;PARK, HYUN SUN;KIM, MOO HWAN;BAEK, JEHYUN
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.662-668
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    • 2015
  • A suspension of titanium nanoparticles (Ti NPs) in liquid sodium (Na) has been proposed as a method to mitigate the violent sodium-water reaction (SWR). The interparticle potential between Ti NPs in liquid Na may play a significant role in the agglomeration of NPs on the reaction surface and in the bulk liquid Na, since the potential contributes to a reduction in the long-term dispersion stability. For the effective control of the SWR with NPs, a physical understanding of the molecular dynamics of NPs in liquid Na is key. Therefore in this study, the nonretarded Van der Waals model and the solvation potential model are employed to analyze the interparticle potential. The ab initio calculation reveals that a strong repulsive force driven by the solvation potential exceeds the interparticle attraction and predicts the agglomeration energy required for two 10-nm Ti NPs to be $4{\times}10^{-17}J$. The collision theory suggests that Ti NPs can be effective suppressors of the SWR due to the high energy barrier that prevents significant agglomeration of Ti NPs in quiescent liquid Na.

Model Calculation of the Np-237 Fission Cross-Sections for En=0 to 20 MeV (중성자 에너지 En=0-20 MeV에 대한 Np-237 핵분열단면적의 모형계산)

  • Bak, H.I.;Strohmaier, B.;Uhl, M.
    • Nuclear Engineering and Technology
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    • v.13 no.4
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    • pp.207-220
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    • 1981
  • The Np-237 fission cross-sections up to 20 MeV incident neutron energy are calculated by means of the computer code STAPRE- a statistical model code with consideration of preequilibrium decay. The higher chance fissions up to third compound nucleus are taken into account, and the main input parameters in the treatment of fission under consideration of a double-humped fission barrier are carefully adjusted, so that the current trend of experimental data can be fitted within an apparent deviation of about 10% throughout the entire energy range. Results are presented in the form of point-wise cross-section values, and also in the form of graph to demonstrate the shape agreement.

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Coupled T-H-M Processes Calculations in KENTEX Facility Used for Validation Test of a HLW Disposal System (고준위 방사성 폐기물 처분 시스템 실증 실험용 KENTEX 장치에서의 열-수리-역학 연동현상 해석)

  • Park Jeong-Hwa;Lee Jae-Owan;Kwon Sang-Ki;Cho Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.117-131
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    • 2006
  • A coupled T-H-M(Thermo-Hydro-Mechanical) analysis was carried out for KENTEX (KAERI Engineering-scale T-H-M Experiment for Engineered Barrier System), which is a facility for validating the coupled T-H-M behavior in the engineered barrier system of the Korean reference HLW(high-level waste) disposal system. The changes of temperature, water saturation, and stress were estimated based on the coupled T-H-M analysis, and the influence of the types of mechanical constitutive material laws was investigated by using elastic model, poroelastic model, and poroelastic-plastic model. The analysis was done using ABAQUS, which is a commercial finite element code for general purposes. From the analysis, it was observed that the temperature in the bentonite increased sharply for a couple of days after heating the heater and then slowly increased to a constant value. The temperatures at all locations were nearly at a steady state after about 37.5 days. In the steady state, the temperature was maintained at $90^{\circ}C$ at the interface between the heater and the bentonite and at about $70^{\circ}C$ at the interface between the bentonite and the confining cylinder. The variation of the water saturation with time in bentonite was almost same independent of the material laws used in the coupled T-H-M processes. By comparing the saturation change of T-H-M and that of H-M(Hydro-Mechanical) processes using elastic and poroelastic material mod31 respectively, it was found that the degree of saturation near the heater from T-H-M calculation was higher than that from the coupled H-M calculation mainly because of the thermal flux, which seemed to speed up the saturation. The stresses in three cases with different material laws were increased with time. By comparing the stress change in H-M calculation using poroelasetic and poroelasetic-plastic model, it was possible to conclude that the influence of saturation on the stress change is higher than the influence of temperature. It is, therefore, recommended to use a material law, which can model the elastic-plastic behavior of buffer, since the coupled T-H-M processes in buffer is affected by the variation of void ratio, thermal expansion, as well as swelling pressure.

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Probabilistic Safety Assessment for High Level Nuclear Waste Repository System

  • Kim, Taw-Woon;Woo, Kab-Koo;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.16 no.1
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    • pp.53-72
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    • 1991
  • An integrated model is developed in this paper for the performance assessment of high level radioactive waste repository. This integrated model consists of two simple mathematical models. One is a multiple-barrier failure model of the repository system based on constant failure rates which provides source terms to biosphere. The other is a biosphere model which has multiple pathways for radionuclides to reach to human. For the parametric uncertainty and sensitivity analysis for the risk assessment of high level radioactive waste repository, Latin hypercube sampling and rank correlation techniques are applied to this model. The former is cost-effective for large computer programs because it gives smaller error in estimating output distribution even with smaller number of runs compared to crude Monte Carlo technique. The latter is good for generating dependence structure among samples of input parameters. It is also used to find out the most sensitive, or important, parameter groups among given input parameters. The methodology of the mathematical modelling with statistical analysis will provide useful insights to the decision-making of radioactive waste repository selection and future researches related to uncertain and sensitive input parameters.

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Dependence of Drain Induced Barrier Lowering for Doping Profile of Channel in Double Gate MOSFET (이중게이트 MOSFET에서 채널내 도핑분포에 대한 드레인유기장벽감소 의존성)

  • Jung, Hak-Kee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.9
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    • pp.2000-2006
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    • 2011
  • In this paper, the drain induced barrier lowering(DIBL) for doping distribution in the channel has been analyzed for double gate MOSFET(DGMOSFET). The DGMOSFET is extensively been studing because of adventages to be able to reduce the short channel effects(SCEs) to occur in convensional MOSFET. DIBL is SCE known as reduction of threshold voltage due to variation of energy band by high drain voltage. This DIBL has been analyzed for structural parameter and variation of channel doping profile for DGMOSFET. For this object, The analytical model of Poisson equation has been derived from Gaussian doping distribution for DGMOSFET. To verify potential and DIBL models based on this analytical Poisson's equation, the results have been compared with those of the numerical Poisson's equation, and DIBL for DGMOSFET has been investigated using this models.

Evaluating the Application of Portable Safety Equipment in Nuclear Power Plants using Multi-unit PSA (다수기 PSA 기반 원자력 발전소 이동형 안전 설비 활용성 평가)

  • Jae Young Yoon;Ho-Gon Lim;Jong Woo Park
    • Journal of the Korean Society of Safety
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    • v.38 no.3
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    • pp.110-120
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    • 2023
  • Following the Fukushima accident, portable equipment employed as accident mitigating systems have been installed and operated to reduce core damage and large early release frequencies. In addition, the establishment of an accident management strategy has gained importance. This study investigated the current status of portable equipment including the international portable equipment FLEX (diverse and flexible coping strategies), and domestic portable equipment multi-barrier accident coping strategy (MACST). Research on optimal utilization of MACST remains insufficient. As a preliminary study for establishing an optimal strategy, sensitivity studies were conducted to facilitate the priority of use on portable equipment, number of portable equipment, and dependency of operator actions based on a multi-unit probabilistic safety assessment model. The results revealed the conditions that reduced the multi-unit and site conditional core damage probabilities, indicating the optimal strategy of MACST. The results of this study can be used as a reference for establishing an optimal strategy that utilizes domestic safety equipment in the future.

Analysis of Photovoltaic Potential of Unused Space to Utilize Abandoned Stone Quarry (폐채석장 부지 활용을 위한 유휴 공간의 태양광 발전 잠재량 분석)

  • Kim, Hanjin;Ku, Jiyoon;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.31 no.6
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    • pp.534-548
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    • 2021
  • In this paper, the feasibility of generating solar power near an abandoned quarry is examined with the objectives of resolving the essential problems that quarries encounter, such as rockfalls and space usage issues. On an abandoned quarry site in Sadang, Seoul, Republic of Korea, two different PV installation methods were analyzed. The first is attaching PV directly on the quarry slope. Since there are no corresponding safety standards and precedents for installing solar panels directly on slopes, the power generation potential was calculated by using topographic data and reasonable assumptions. The surface area of cut slope section was extracted from the Digital Elevation Model(DEM) via ArcGIS and Python programming to calculate the tilt and power capacity of installable panels. The other approach is installing PV as a rockfall barrier, and the power generation potential was analyzed with the assumption that the panel is installed in the direction of facing solar irradiation. For the derivation of power generation, the renewable energy generation analysis program SAM(System Advisor Model) was used for both methods. According to the result, quarries that have terminated resource extraction and remain devastated have the potential to be transformed into renewable energy generation sites.

Ultimate Capacity of Guardrail Supporting Pile Subjected to Lateral Impact Load Using Centrifuge Model Test (원심모형실험을 통한 차량방호울타리 지지말뚝의 수평방향 충격하중에 대한 극한지지력)

  • Yun, Jong Seok;Lee, Min Jy;Choo, Yun Wook
    • Journal of the Korean Geotechnical Society
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    • v.35 no.11
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    • pp.25-36
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    • 2019
  • The safety barrier is installed on road embankment to prevent vehicles from falling into road side slope. Among the safety barrier, flexible guardrails are usually installed. The flexible guardrail generally consists of a protection cross-beam and supporting in-line piles. These guardrail piles are installed nearby slope edge of road embankment because the side area of the road is much narrow. The protection cross-beam absorbs impact energy caused by vehicle collision. The pile-soil interaction also absorbs the rest of the impact energy and then, finally, the flexible guardrail system resists the impact load. This paper aims to investigate the pile-soil interaction subjected to impact load using centrifuge model tests. In this study, a single pile was installed in compacted residual soil and loaded under lateral impact load. An impact loading system was designed and developed available on centrifuge tests. Using this loading system, a parametric study was performed and the parameters include types of loading and ground. Finally, the ultimate bearing capacity of supporting pile under impact load was analyzed using load-displacement curve and soil reaction pressure distributions at ultimate were evaluated and compared with previous studies.

Study on Design of Darrieus-type Tidal Stream Turbine Using Parametric Study (파라메트릭 스터디를 통한 조류발전용 다리우스 터빈의 설계연구)

  • Han, Jun-Sun;Hyun, Beom-Soo;Choi, Da-Hye;Mo, Jang-Oh;Kim, Moon-Chan;Rhee, Shin-Hyung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.4
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    • pp.241-248
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    • 2010
  • This paper deals with the performance analysis and design of the Darrieus-type vertical axis turbine to evaluate the effect of key design parameters such as number of blade, blade chord, pitch and camber. The commercial CFD software FLUENT was employed as an unsteady Reynolds-Averaged Navier-Stokes (RANS) solver with k-e turbulent model. Grid system was modelled by GAMBIT. Basic numerical methodology of the present study is appeared in Jung et al. (2009). Two-dimensional analysis was mostly adopted to avoid the barrier of massive calculation required for parametric study. It was found that the highly efficient turbine model could be designed through the optimization of design parametrrs.