• 제목/요약/키워드: Energy barrier model

검색결과 133건 처리시간 0.029초

三原子 置煥反應의 反應確率. 간단한 古典力學的 取扱 (Reaction Probabilities for Three-atom Rearrangement Reaction. A + B - C = A - B + C : An Idealized Classical Approach)

  • 김유항;신형규
    • 대한화학회지
    • /
    • 제19권5호
    • /
    • pp.294-303
    • /
    • 1975
  • 直線 衝突모형을 써서 三原子 置換反應 $A+B-C{\to}A-B+C$의 反應確率을 全體 에너지의 函數로 計算하였다. 使用한 포텐셜 에너지 亦是 極히 單純한 理想的인 것이다. 세原子의 質量이 모두 같은 경우에 대하여 數値로 結果를 얻어서 더욱 더 간단한 모형을 쓴 다른 硏究者들의 結果와 比較하여 定性的으로 더 나음을 알았다.

  • PDF

태양전지 어레이의 임피던스를 이용한 서지특성분석 (Impedance and Surge Characteristics Analysis of PV Array)

  • 이기옥;최주엽;유권종
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
    • /
    • pp.208-211
    • /
    • 2004
  • Photovoltaic(PV) array, which is generally installed outside, has the possibility to be damaged by high voltage due to lightning. Because the electrical characteristics of PV array have not been fully identified by lightning yet, there is a very important issue whether PV array should be connected with ground or not. In this paper, a basic model of PV array is provided considering the PV cell's barrier capacitance and ground capacitance for analysis of electrical characteristics by lightning using PSCAD/EMTDC.

  • PDF

MOS 구조에서의 Avalanche Injection에 관한 연구 (Characteristics of the Avalanche Injection on SiO2Layer in MOS Structures)

  • 성영권;김성진;백우현;박찬원
    • 대한전기학회논문지
    • /
    • 제34권6호
    • /
    • pp.244-252
    • /
    • 1985
  • A model is presented to explain charging phenomena into the oxide layer when a metal-oxide-silicon(MOS) capacitor is driven by a large amplitude and high frequency ac signal sufficient to produce avalanche injection in the silicon. During avalanche, minority carriers are injected. It is assumed that some of these minority carriers attain sufficient energy to surmount the potential barrier at the interface, and then inter the oxide. Measurements of C-V curves are made for the MOS capacitor with p-type silicon substrates before and after avalanche injection. This paper studies how charging in the oxide and the interface depends on oxide properties. It is concluded that this charging effect is related to the presence of water in the oxide.

  • PDF

Nonactivaed adsorption of $CH_3_Cl$ on Si(100)-2$\times$1 studied by LEED, AES and semiempirical method.

  • Lee, Junyoung;Kim, Sehun
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
    • /
    • pp.157-157
    • /
    • 2000
  • The adsorption processes of methyl chloride on Si(100)-2$\times$1 have been studied by low energy electron diffraction (LEED), Auger electron spectroscopy (AES) and semiempirical PM3 calculations. The dissociative adsorption of the methyl chloride on Si(100) takes place without breaking of the silicon dimer with high efficiency. For adsorption at the room temperature, the existence of a precursor state is confirmed by the behavior of the sticking probability depending on the coverage and temperature. From AES measurements, the determined activation barrier of adsorption ($\Delta$ Hads) is -28.4 kj/mol. This results indicate that the dissociative process is nonactivated. The optimized precursor state of CH3Cl on the Si(100)-2$\times$1 surface was determined by PM3 calculations based on a cluster model.

  • PDF

촉매가 충진된 플라즈마 반응기에서의 Toluene 제거특성 (Characteristics of Toluene Destruction by Non-thermal Plasma in Packed with Catalyst Reactor)

  • 한소영;송영훈;차민석;김석준;최경일;신동준
    • 한국대기환경학회지
    • /
    • 제18권1호
    • /
    • pp.51-58
    • /
    • 2002
  • Destruction process of toluene using a wire-cylindrical BBD (Dielectric Barrier Discharge) reactor packed with catalysts was investigated to characterize the synergetic effects of non-thermal plasma and catalyst process. The catalysts used in the present study were ${\gamma}$-Al$_2$BO$_3$ and Pt/${\gamma}$-Al$_2$O$_3$. Under the numerous test conditions, specific energy density (SED (J/L)) and the conversion of toluene, defined as (1 -[C$_{f}$]/[C$_{i}$]), were measured. The test results showed that toluene decomposition efficiency followed the pseudo-first order in the case of plasma only process. The pseudo-first order process, however, was modified to pseudo-zeroth order reaction in the case of catalyst-assisted plasma process. This modification of the reaction order was verified based on a simple kinetic model proposed in the present study. Owing to the modification of reaction order, which resulted from the catalytic process, the specific energy to achieve the high removal efficiencies, i.e. 80~90%, was reduced significantly.y.y.

Development of a Computer Code for Low-and Intermediate-Level Radioactive Waste Disposal Safety Assessment

  • Park, J.W.;Kim, C.L.;Lee, E.Y.;Lee, Y.M.;Kang, C.H.;Zhou, W.;Kozak, M.W.
    • Journal of Radiation Protection and Research
    • /
    • 제29권1호
    • /
    • pp.41-48
    • /
    • 2004
  • A safety assessment code, called SAGE (Safety Assessment Groundwater Evaluation), has been developed to describe post-closure radionuclide releases and potential radiological doses for low- and intermediate-level radioactive waste (LILW) disposal in an engineered vault facility in Korea. The conceptual model implemented in the code is focused on the release of radionuclide from a gradually degrading engineered barrier system to an underlying unsaturated zone, thence to a saturated groundwater zone. The radionuclide transport equations are solved by spatially discretizing the disposal system into a series of compartments. Mass transfer between compartments is by diffusion/dispersion and advection. In all compartments, radionuclides ate decayed either as a single-member chain or as multi-member chains. The biosphere is represented as a set of steady-state, radionuclide-specific pathway dose conversion factors that are multiplied by the appropriate release rate from the far field for each pathway. The code has the capability to treat input parameters either deterministically or probabilistically. Parameter input is achieved through a user-friendly Graphical User Interface. An application is presented, which is compared against safety assessment results from the other computer codes, to benchmark the reliability of system-level conceptual modeling of the code.

100kW급 대용량 PV-SPE 시스템의 운전방법에 관한 연구 (A study on the various operating methods of 100kW class PV-SPE system)

  • 이석주;이동한;김종현;박민원;유인근
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 B
    • /
    • pp.1167-1168
    • /
    • 2006
  • Recently, the concern for environmental issue has been rising in the world such as global warming and breaking of ozone barrier by exhausting carbon dioxide(CO2) and Freon. In this situation, Photovoltaic(PV) and hydrogen energy system for utilizing clean and renewable energy was highlighted to contribute very much against the global warming prevention. Until now, authors have studied EMTDC model Development of Solar-powered Hydrogen production system and manufactured the 600W class actual PV-SPE system. Which was established in 2004 to produce highly pure hydrogen energized by PV power generation system. Sooner, authors will establish 100kW class PV-SPE system. Economically, this system produce large amount of hydrogen. In this paper, all data of 100kW class PV-SPE system will be simulated by using PSCAD/EMTDC.

  • PDF

Resonance tunneling phenomena by periodic potential in type-II superconductor

  • Lee, Yeong Seon;Kang, Byeongwon
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제16권1호
    • /
    • pp.1-5
    • /
    • 2014
  • We calculated the resonance tunneling energy band in the BCS gap for Type-II superconductor in which periodic potential is generated by external magnetic flux. In this model, penetrating magnetic flux was assumed to be in a fixed lattice state which is not moving by an external force. We observed the existence of two subbands when we used the same parameters as for the $Nd_{1.85}Ce_{0.15}CuO_X$ thin film experiment. The voltages at which the regions of negative differential resistivity (NDR) started after the resonant tunneling ended were in a good agreement with the experimental data in the field region of 1 T - 2.2 T, but not in the high field regions. Discrepancy occurred in the high field region is considered to be caused by that the potential barrier could not be maintained because the current induced by resonant tunneling exceeds the superconducting critical current. In order to have better agreement in the low field region, more concrete designing of the potential rather than a simple square well used in the calculation might be needed. Based on this result, we can predict an occurrence of the electromagnetic radiation of as much difference of energy caused by the 2nd order resonant tunneling in which electrons transit from the 2nd band to the 1st band in the potential wells.

중공트랙단면 에코필라 사방댐의 비선형 충돌해석 (Nonlinear Impact Analysis for Eco-Pillar Debris Barrier with Hollow Cross-Section)

  • 김현기;김범준
    • 한국산학기술학회논문지
    • /
    • 제20권7호
    • /
    • pp.430-439
    • /
    • 2019
  • 본 연구는 친환경 에코필라 사방댐의 시공성과 경제성을 향상시키기 위해 제안된 중공트랙형 단면의 프리캐스트 에코필라 사방댐에 대하여 산사태 발생시 토석류에 동반되는 암석이 충돌할 경우 구조체의 안전성과 손상도를 평가하기 위해 비선형 충돌해석을 수행하였다. 최근에는 콘크리트를 이용한 에코필라 사방댐의 설치가 늘고 있으나, 콘크리트 투과형 사방댐 설계의 기준이 전무하여 경험적으로 설계되고 있을 뿐 아니라 산사태로 인한 피해가 지속적으로 늘고 있는 상황임에도 불구하고 극한환경을 적용한 성능평가나 연구를 찾아보기 어렵다. 따라서 본 연구에서는 선행연구를 통해 적정성과 성능에 대해 검증된 중공트랙형 단면의 에코필라 사방댐에 대하여 급경사지에서 발생한 우면산 산사태의 토석류 속도로 암석이 충돌할 경우로 가정하였다. 암석의 규모는 ETAG 27의 성능평가 기준을 참조하여 유사한 규모로 설정하였고, 최대 충격력이 작용할 수 있는 조건과 작용위치, 암석직경을 변수로 고려하였으며, 콘크리트 비선형 재료모델을 적용하였다. 재료 비선형해석이 가능한 ABAQUS 소프트웨어를 이용하여 해석적 방법으로 구조체의 강도와 손상도 평가를 수행하였다. 해석결과, 암석직경 0.3m와 0.5m가 충돌했을 경우는 구조체의 변위나 응력이 허용치 이내로 안전한 것으로 평가 되었으나, 0.7m 직경의 암석이 충돌할 경우 중공트랙형 기둥부가 에너지를 충분히 흡수하지 못하여 파괴되는 것으로 예측되었다. 또한, 콘크리트 손상도 평가결과 암석직경 0.3m와 0.5m에서는 손상비가 1.0이하로 나타났으나 0.7m 직경일 경우는 1.39로 평가되어 일정수준 이상에서는 사방댐 기능수행 적합성이 제고되어야 할 것으로 판단된다. 본 연구 결과는 사방댐 단면설계 시 고려해야 할 충격력에 대한 기초자료로 활용할 수 있으며, 향후 실험적 연구가 추가적으로 필요할 것으로 판단된다.

대형트럭 승객거동과 상해치 해석을 위한 유한요소모델의 개발 (Development of a finite Element Model for Studying the Occupant Behavior and Injury Coefficients of a Large-sized Truck)

  • 오재윤;김학덕;송주현
    • 대한기계학회논문집A
    • /
    • 제26권8호
    • /
    • pp.1577-1584
    • /
    • 2002
  • This paper develops a finite element model for studying the occupant behavior and injury cofficients of a large-sized cab-over type truck. Since it does not have a room to absorb collision energy and deformation in front of the passenger compartment the deformation is directly transmitted to the passenger compartment. Moreover, since its steering column is attached on the frame, severe deformation of the frame directly affects on the steering wheel's movement. Therefore, if the occupant behavior and injury coefficients analysis is performed using a finite element model developed based on a sled test, it is very difficult to expect acquiring satisfactory results. Thus, the finite element model developing in this paper is based on the frontal crash test in order to overcome the inherent problems of the sled test based model commonly used in the passenger car. The occupant behavior and injury coefficients analysis is performed using PAM-CRASH installed in super-computer SP2. In order to validate the reliability of the developed finite element model, a frontal crash test is carried out according to a test method used fur developing truck occupant's secondary safety system in european community and japan. That is, test vehicle's collision direction is vertical to the rigid barrier and collision velocity is 45kph. Thus, measured vehicle pulses at the lower parts of the left and right B-pilla., dummy chest and head deceleration profiles, HIC(head injury criterial) and CA(chest acceleration) values, and dummy behavior from the frontal crash test are compared to the analysis results to validate reliability of the developed model.