• Title/Summary/Keyword: Energy Spectra

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Surface analysis of CuSn thin films obtained by rf co-sputtering method

  • Gang, Yu-Jin;Park, Ju-Yeon;Jeong, Eun-Gang;Gang, Yong-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.175.1-175.1
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    • 2015
  • CuSn thin films were deposited by rf magnetron co-sputtering method with pure Cu and Sn metal targets with a variety of rf powers. CuSn thin films were studied with a surface profiler (alpha step), X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), X-ray diffraction (XRD), and contact angle measurement. The thickness of CuSn thin films was fixed at $200{\pm}10nm$ and deposition rate was calculated by the measured with a surface profiler. From the survey XPS spectra, the characteristic peaks of Cu and Sn were observed. Therefore, CuSn thin films were successfully synthesized on the Si (100) substrate. The oxidation state and chemical environment of Cu and Sn were investigated with the binding energy regions of Cu 2p XPS spectra, Sn 3d XPS spectra, and Cu LMM Auger spectra. Change of the crystallinity of the films was observed with XRD spectra. Using contact angle measurement, surface free energy (SFE) and wettability of the CuSn thin films were studied with distilled water (DW) and ethylene glycol (EG).

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A Study on the Ignition and Molten Mark Analysis of Ballast for Fluorescent Lamp (형광등용 안정기의 발화 및 용융흔 분석에 관한 연구)

  • 최충석;박창수;김혁수;김향곤;정재희
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1998.11a
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    • pp.173-177
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    • 1998
  • In this paper, we reported an outbreak of fire hazard of ballast for fluorescent lamp. The surface structure and composition of ballast coil analyzed by using metallurgical microscope, scanning electron microscope(SEM) and energy dispersive x-ray spectroscopy(EDX). The surface of molten mark appeared columnar structure and void. EDX analysis indicated that the molten mark spectra were composed not only of the corresponding original spectra but also of several new lines.

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C 1s photoelectron energy loss spectra of organic electroluminescent materials

  • Lee, J.W.;Kim, T.H.
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.1
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    • pp.1-5
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    • 2000
  • The C 1s photoelectron energy loss spectra of tris (8-hydroxy-quinoline) aluminum (Alq$_3$) and N,N'-diphenyl-N,N'-bis (3-methyl phenyl)-1,1'-bi-phenyl-4,4'-diamine (TPD) thin films have been investigated. Two major loss structures, namely the plasmon dominated loss lines and shake-up satellites, have been observed. The shake-up spectrum of the C 1s photoelectron line is directly related to the $\pi$-$\pi$$\^$*/ energy gap of the molecule which plays an important role in organic electroluminescent materials. The molecular orbitals of Alq$_3$ and TPD and their major components, quinolime and benzene, have been calculated with the AMI semi-empirical method. The amount of the plasma-dominated loss of Alq$_3$ and TPD, which has to do with the delocalization of electrons through the molecule, was about 24 eV, alike in both cases. The main peak of the C 1s shake-up spectrum of Alq$_3$ and TPD, however, was 5.2 eV and 6.8 eV respectively. It was found that the main shake-up peak reflects more the local $\pi$\longrightarrow$\pi$$\^$*/ transition of quinoline and benzene component rather than the excitation of the whole molecule of Alq$_3$ and TPD. The C 1s shake-up spectra, however, revealed some correlation with the optical energy gap of the organic eletroluminescent materials.

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Diagnostic X-ray Spectra Detection by Monte Carlo Simulation (진단용 X-선 스펙트럼의 몬테칼로 전산모사 측정)

  • Baek, Cheol-Ha;Lee, Seung-Jae;Kim, Daehong
    • Journal of the Korean Society of Radiology
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    • v.12 no.3
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    • pp.289-295
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    • 2018
  • Most diagnostic devices in the medical field use X-ray sources, which emit energy spectra. In radiological diagnosis, the quantitative and qualitative analyses of X-rays are essential for maintaining the image quality and minimizing the radiation dose to patients. This work aims to obtain the X-ray energy spectra used in diagnostic imaging by Monte Carlo simulation. Various X-ray spectra are simulated using a Monte Carlo simulation tool. These spectra are then compared to the reference data obtained with a tungsten anode spectral model using the interpolating polynomial (TASMIP) code. The X-ray tube voltages used are 50, 60, 80, 100, and 110 kV, respectively. CdTe and a-Se detector are used as the detectors for obtaining the X-ray spectra. Simulation results demonstrate that the various X-ray spectra are well matched with the reference data. Based on the simulation results, an appropriate X-ray spectrum, in accordance with the tube voltage, can be selected when generating an image for diagnostic imaging. The dose to be delivered to the patient can be predicted prior to examination in the diagnostic field.

CHARACTERISTICS OF THE KAERI NEUTRON REFERENCE FIELDS FOR THE CALIBRATION OF NEUTRON MONITORING INSTRUMENTS

  • Kim, Bong-Hwan;Kim, Jang-Lyul;Chang, Si-Young;Cho, Gyu-Seong
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.243-248
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    • 2001
  • Neutron reference fields of Korea Atomic Energy Research Institute (KAERI) for calibrating neutron measuring devices to be used in radiation workplace monitoring consist of two kinds of neutron spectra, the direct and the scattered neutron fields, which are produced by using radionuclide neutron sources, 252Cf and 241AmBe sources. Necessary parameters for calibration such as the anisotropy factor of each neutron source and the room-scattered fraction of some neutron surveymeters in the KAERI calibration facility were determined by calculation or measurement. Spectral measurement of scattered neutron fields were performed at each reference calibration point using a Bonner Multi-sphere Spectrometer (BMS) and the dosimetric quantities for calibration also estimated from the neutron energy spectra which were unfolded using the BUNKI code.

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Beta-spectra for the Radionuclides in Medicine

  • Yi, Chul-Young;Kim, Kyung-Hwa;Park, Kyung-Bae;Han, Hyon-Soo;Jun, Jae-Shik;Chai, Ha-Seok
    • Progress in Medical Physics
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    • v.9 no.1
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    • pp.37-46
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    • 1998
  • Beta-particle energy distributions of the radionuclides in medicine are calculated for the medical physics applications. The radial component solutions of Dirac wave equations are evaluated for a point-nucleus un screened Coulomb potential. The WKB method is employed to correct the screening due to the orbital-electron cloud. Fierz interference terms are ignored. The radionuclides considered are $\^$32/P, $\^$90/Y, $\^$131/I, $\^$166/Ho, $\^$192/Ir, $\^$198/Au, $\^$153/Sm, $\^$169/Er and $\^$188/Re. A total of 9 beta-spectra for the radionuclides, currently in domestic use or potential use in the near future, are calculated with enough accuracy and presented in graphs and tables.

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Determination of the Isotope Ratio for Metal Samples Using a Laser Ablation/Ionization Time-of-flight Mass Spectrometry

  • Song, Kyu-Seok;Cha, Hyung-Ki;Kim, Duk-Hyeon;Min, Ki-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.101-105
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    • 2004
  • The laser ablation/ionization time-of-flight mass spectrometry is applied to the isotopic analysis of solid samples using a home-made instrument. The technique is convenient for solid sample analysis due to the onestep process of vaporization and ionization of the samples. The analyzed samples were lead, cadmium, molybdenum, and ytterbium. To optimize the analytical conditions of the technique, several parameters, such as laser energy, laser wavelength, size of the laser beam on the samples surface, and high voltages applied on the ion source electrodes were varied. Low energy of laser light was necessary to obtain the optimal mass resolution of spectra. The 532 nm light generated mass spectra with the higher signal-to-noise ratio compared with the 355 nm light. The best mass resolution obtained in the present study is ~1,500 for the ytterbium.

Excitation and Emission Properties of Adsorbed U(VI) on Amorphous Silica Surface

  • Jung, Euo Chang;Kim, Tae-Hyeong;Kim, Hee-Kyung;Cho, Hye-Ryun;Cha, Wansik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.497-508
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    • 2020
  • In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.