• Journal of the Korean Chemical Society
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• v.8 no.2
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• pp.47-56
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• 1964

When a developed paper partition chromatogram was irradiated by means of the pneumatic tube system of the Korean research reactor (neutron flux: 1.5 ${\times}10^{12}n/cm^2$sec.) the qualitative confirmation of the developed spot on the chromatogram was possible. In the case of an organic halogen compounds (chloro-acid, chloro-ester, iodide, and fluoride) the spot analysis was possible by the present method whereas the same spot could not give the distinct coloring with a common coloring reagents. Filterpaper thickness calibration and activity calibration induced by irradiation of the components of the filter paper, which were a source of erraneous interpretation of the spot, were searched and an average filterpaper calibration method and filter paper activity were improvised to obtain a good qualitative analysis of the spot. Finally the use and applicability of this method for the analysis identification of an organic halogen compound were evaluated. As the filter paper phase an ordinary phase (Whatmann #1, filter paper) and reversed phase (liquid paraffin impregnated) were used.

• Journal of the Korean Chemical Society
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• v.8 no.2
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• pp.68-74
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• 1964

Water has the melting point, the boiling point, the heat of fusion, and the heat of vaporization all much higher than would be normally expected from the hydrogen compounds of the other members of the oxygen family. Another unique characteristic of ice-Ⅰ is its volume decrease which takes place in its melting. A number of significant efforts have been made in the past to explain these properties quantitatively. The authors, reasoning from the unusually great free surface energy of water and the characteristic volume change on melting, propose the structural model of liquid water as follows. On melting, fluidized vacancies of a molecular size are introduced. Thereupon, for the unusually great surface energy density, molecules surrounding the vacancies become to have close packed arrangement. But molecules not in direct contact with vacancies should still possess the original structure i. e., ice-Ⅰ. When a molecule adjacent to a vacancy jumps into the vacancy, the molecule attains the gaslike degree of freedom. Using the above model, the authors had developed the liquid partition function of water by applying the theory of significant structures in liquids. Molar volume, vapor pressure, entropy of fusion and entropy of vaporization were calculated over a wide temperature range. The results show good agreement with experimental observations.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.10 no.6
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• pp.2504-2526
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• 2016

Wireless sensors are always deployed in brutal environments, but as we know, the nodes are powered only by non-replaceable batteries with limited energy. Sending, receiving and transporting information require the supply of energy. The essential problem of wireless sensor network (WSN) is to save energy consumption and prolong network lifetime. This paper presents a new communication protocol for WSN called Dynamical Threshold Control Algorithm with three-parameter Particle Swarm Optimization and Ant Colony Optimization based on residual energy (DPA). We first use the state of WSN to partition the region adaptively. Moreover, a three-parameter of particle swarm optimization (PSO) algorithm is proposed and a new fitness function is obtained. The optimal path among the CHs and Base Station (BS) is obtained by the ant colony optimization (ACO) algorithm based on residual energy. Dynamical threshold control algorithm (DTCA) is introduced when we re-select the CHs. Compared to the results obtained by using APSO, ANT and I-LEACH protocols, our DPA protocol tremendously prolongs the lifecycle of network. We observe 48.3%, 43.0%, and 24.9% more percentages of rounds respectively performed by DPA over APSO, ANT and I-LEACH.

• Polymer(Korea)
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• v.36 no.3
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• pp.338-343
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• 2012

Interfacial properties of commercially available soft contact lens hydrogels were studied to understand thermodynamic phenomena of protein adsorption. Hydrogel particles ($1{\times}1mm^2$) with varying water wettability were exposed to bovine serum albumin solutions for an hour. The remained albumin solutions were analyzed with Bradford assay method. The amount of protein adsorbed to hydrogels increased with protein solution concentrations following Langmuir isotherm. The partition coefficient ($P$) and Gibbs free energy cost of dehydrating the surface region by protein displacement upon adsorption increased with increasing hydrophilicity of contact lens. Understanding of physical chemistry in protein adsorption to contact lens materials enabled elucidating relationships between surface energy and albumin adsorption capacity.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2010.10a
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• pp.531-534
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• 2010

In this paper, we introduce an efficient energy management using a notion of virtual energy system for shared solar-powered sensor network. Virtual energy system is an abstraction that allows sensor network applications on a node to reserve their own fractions of the shared solar cell and the shared rechargeable battery, hence achieving logically partition of a shared renewable power source with no change in design and implementation. Our results show that our design and implementation are reliable, lightweight and efficient, allowing proper isolation of energy consumption among applications.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1131-1131
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• 2001

To develop a nondestructive quality evaluation technique of fruits, a K-mean algorism is applied to near infrared (NIR) spectroscopy of apples. The K-mean algorism is one of neural network partition methods and the goal is to partition the set of objects O into K disjoint clusters, where K is assumed to be known a priori. The algorism introduced by Macqueen draws an initial partition of the objects at random. It then computes the cluster centroids, assigns objects to the closest of them and iterates until a local minimum is obtained. The advantage of using neural network is that the spectra at the wavelengths having absorptions against chemical bonds including C-H and O-H types can be selected directly as input data. In conventional multiple regression approaches, the first wavelength is selected manually around the absorbance wavelengths as showing a high correlation coefficient between the NIR $2^{nd}$ derivative spectrum and Brix value with a single regression. After that, the second and following wavelengths are selected statistically as the calibration equation shows a high correlation. Therefore, the second and following wavelengths are selected not in a NIR spectroscopic way but in a statistical way. In this research, the spectra at the six wavelengths including 900, 904, 914, 990, 1000 and 1016nm are selected as input data for K-mean analysis. 904nm is selected because the wavelength shows the highest correlation coefficients and is regarded as the absorbance wavelength. The others are selected because they show relatively high correlation coefficients and are revealed as the absorbance wavelengths against the chemical structures by B. G. Osborne. The experiment was performed with two phases. In first phase, a reflectance was acquired using fiber optics. The reflectance was calculated by comparing near infrared energy reflected from a Teflon sphere as a standard reference, and the $2^{nd}$ derivative spectra were used for K-mean analysis. Samples are intact 67 apples which are called Fuji and cultivated in Aomori prefecture in Japan. In second phase, the Brix values were measured with a commercially available refractometer in order to estimate the result of K-mean approach. The result shows a partition of the spectral data sets of 67 samples into eight clusters, and the apples are classified into samples having high Brix value and low Brix value. Consequently, the K-mean analysis realized the classification of apples on the basis of the Brix values.

• Applied Chemistry for Engineering
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• v.29 no.5
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• pp.581-588
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• 2018

In this article, electrochemical investigation of the transfer reaction of ionizable cefotiam (CTM), an antibiotic molecule across a polarized water/1,2-dichloroethane (water/1,2-DCE) interface was studied. Ion partition diagram providing the preferred charged form of CTM in either water or 1,2-DCE phase was established via the voltammetric evaluation of the transfer process of differently charged CTM species depending upon the pH variation of aqueous solutions. Thermodynamic information including the formal transfer potential and formal Gibbs transfer energy values in addition to important pharmacokinetics including partition coefficients of ionizable CTM were also evaluated. In particular, the current associated with the transfer of CTM present at pH 3.0 aqueous solution proportionally increased with respect to the CTM concentration which was further used for developing CTM sensitive ion sensor. In order to improve the portability and convenient usage, a single microhole interface fabricated in a supportive polyethylene terephthalate film was used of which hole was filled with a polyvinylchloride-2-nitrophenyloctylether (PVC-NPOE) gel replacing 1,2-DCE, a toxic organic solvent. A dynamic range of $1-10{\mu}M$ CTM was obtained.

• The Korean Journal of Nuclear Medicine
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• v.3 no.1
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• pp.69-72
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• 1969

In 1968 total 94,660 mc of radioactive iodocompound were prepared and distributed to the urers. In order to obtain an effective liver scanning In-113 m colloidal of even particle size from a $^{113}Sn-^{113m}In$ cow, the eluate(pH; 1.5) was examined by a radio paper partition chromatography. It was found that the eluate was composed of two components, ionic form and colloidal form. The ionid form could be eliminated by cation exchange resine and the eluate from the ion exchange resine was of even particle size to give an excellent liver scanning result. Labelling of $^{113m}In$ to human serum albumine was attempted.

• Proceedings of the Korea Society for Industrial Systems Conference
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• 2008.10b
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• pp.507-511
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• 2008

Supporting energy efficiency and load balancing in wireless sensor network is the most important issue in devising the hierarchical routing protocols. Recently, the dual layered clustering scheme with GPS was proposed for the supporting of load balancing for cluster heads but there would be many collided messages in the overlapped area between two layers. Thereby, the purpose of this paper is to reduce the collision rate in the overlapped layer by concisely distinguish them with the same number of nodes in them. For the layer partition, this paper uses an equation $x^2+ y^2{\le}(\frac{R}{\sqrt{2\pi}})^2$ to distinguish layers. By using it, the scheme could efficiently distinguish two layers and gets the balanced number of elements in them. Therefore, the proposed routing scheme could prolong the overall network life cycle about 10% compared to the previous two layered clustering scheme.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.119-125
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• 1998

The modified statistical-mechanical theory for dense fluid mixtures of rigid spheres has been applied to rigid sphere fluids in the nonoverlapping pore model. The resulting expressions for the partition coefficient and diffusivity illustrate the influence of steric hindrance on the thermodynamic and transport properties in such systems. The open membrane model without the size-exclusion and shielding effects shows considerable overestimation of the diffusion flux when the effective mean pore radii of the order of $20{\AA}$ or less are involved. Theoretical predictions investigated here were also compared with experimental data for hydrogen gases in inorganic porous membranes and it was observed a qualitative agreement in the low pressure limit.