• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.263-263
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• 2013

This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.4
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• pp.293-301
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• 2013

Borehole Disposal Concept (BDC) was initiated by the South African Nuclear Energy Corporation (NECSA) with the view to improve the radioactive waste management practices in Africa. At a time when geological disposal of radioactive waste is being considered, the need to protect ground water from possible radioactive contamination and the investigation of radionuclides migration through soil and rocks of zone of aeration into ground water has becomes very imperative. This is why the Borehole Disposal Concept (BDC) is being suggested to address the problem. The concept involves the conditioning and emplacement of disused sealed radioactive sources in an engineered facility of a relatively narrow diameter borehole (260 mm). Tanzania is operating a Radioactive Waste Management Facility where a number of spent sealed radioactive sources with long and short half lives are stored. The activity of spent sealed radioactive sources range from (1E-6 to 8.8E+3 Ci). However, the long term disposal solution is still a problem. This study therefore proposing the country to adopt the BDC, since the repository requires limited land area and has a low probability of human intrusion due to the small footprint of the borehole.

• Journal of Microbiology and Biotechnology
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• v.26 no.3
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• pp.572-578
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• 2016

Communication between endothelial cells (ECs) and smooth muscle cells (SMCs) via miR-143/145 clusters is vital to vascular stability. Previous research demonstrates that miR-143/145 released from ECs can regulate SMC proliferation and migration. In addition, a recent study has found that SMCs also have the capability of manipulating EC function via miR-143/145. In the present study, we artificially increased the expression of miR-143/145 in ECs, to mimic a similar change caused by miR-143/145 released by SMCs, and applied untargeted metabolomics analysis, aimed at investigating the consequential effect of miR-143/145 overexpression. Our results showed that miR-143/145 overexpression alters the levels of metabolites involved in energy production, DNA methylation, and oxidative stress. These changed metabolites indicate that metabolic pathways, such as the SAM cycle and TCA cycle, exhibit significant differences from the norm with miR-143/145 overexpression.

• Journal of the Korean Ceramic Society
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• v.40 no.8
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• pp.739-745
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• 2003

In $N_{x}$ films were deposited on soda-lime glass without substrate heating by reactive dc magnetron sputtering using indium (In) metal target. Depositions were carried out under various total gas pressures ( $P_{tot}$) of mixture gases (Ar+$N_2$ or He+$N_2$). He gas was introduced to $N_2$ gas in order to enhance the reactivity of nitrogen on film surface by the "penning ionization". Plasma impedance decreased greatly when 20% or more introduced the $N_2$ gas. This is due to the In $N_{x}$ layers formed on target surface because a secondary electron emission rate of InN is small compared with In metal. XRD patterns of the films revealed that <001> preferred oriented polycrystalline In $N_{x}$ films, where the crystallinity of the films was improved with decrease of $P_{tot}$ and with increase of $N_2$ flow ratio. The improvement of the crystallinity and stoichimetry of the In $N_{x}$ films were considered to be caused by an increase in the activated nitrogen radicals and also by an increase in the kinetic energy of sputtered In atoms arriving at growing film surface, which should enhance the chemical reaction and surface migration on the growing film surface, respectively. Furthermore, the films deposited using mixture gases of He+$N_2$ showed higher crystallinity compared with the film deposited by the mixture gases of Ar+$N_2$.$.EX>.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.489-493
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• 2013

The most common carbonaceous anode materials of lithium ion batteries (natural graphite, artificial graphite, hard carbon, and mesocarbon microbeads) were utilized as an electrode in lithium ion capacitors. It could be able to enhance the energy density of capacitors due to the intercalation of lithium ion. In this work, the properties of capacitors using the symmetric electrode were measured by organizing coin cell typed capacitors. Also, we made other capacitors having pre-intercalated lithium ions at one side of the electrode. The results of electrochemical measurements for these capacitors show that the storage capacitance was appeared. In other words, if the migration of lithium ions is supplied continuously in the electrolytes, lithium ions can be diffused into the carbonaceous materials. And it results in the improvement of capacitance compared to only using symmetric carbonaceous electrodes. Also, we conducted the same measurement with graphene oxide having a the large specific area in the same condition. Herein, we recognized that the large specific area is extremely important for supercapacitors.

• Journal of the Korean Chemical Society
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• v.24 no.4
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• pp.295-301
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• 1980

The electrical conductivity of solid electrolyte $RbAg_4I_5$ single crystal was studied at various temperatures. The four-probe method was used in measuring the conductance with an ac signal imposed on the specimen. The ionic conductivity was $0.284 ohm^{-1} cm^{-1}\;at\;25^{\circ}C$, and the activation energy for $Ag^+$ ion migration was calulated to be 1.70 kcal/mole. These values agree well with those reported for polycrystalline samples. Reactions at $Ag/RbAg_4I_5$ interface were studied by cyclic voltammetry with a silver reference electrode. It was found that silver ion is reversibly reduced at silver surfaces below zero volt, and iodide was oxidized above +0.67 volt.The anodic current arising from the oxidation of the electrode was small in magnitude initially over a wide range of potential, but, after silver was cathodically deposited on the electrode, reversing the potential sweep to the anodic direction resulted in a sharp peak of anodic current.

• Economic and Environmental Geology
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• v.24 no.4
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• pp.435-446
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• 1991

Ductile shear zones developed in Jurassic granites in the Yonggwang area show NE trend at the eastern part and nearly EW trend at the western part, respectively. Judged from shear sense indicators, they have resulted from dextral strike-slip movement. The intersection of both trends is thought to be due to the truncation and offset of NE shear zone Chonju Shear zone by the brittle Yonggwang fault which runs in near EW direction with sinistral movement sense. The simple shear deformation was predominate through the deformation in this ductile shear zone. Based on this deformation mechanism, the shear strain (${\gamma}$) estimated in domain 1 increases from 0.14 at the shear zone margin to 9.41 toward the center of shear zone. Total displacement obtained only from this measured section(JK 59 to JK14) appecars to be 1434.5 meters. The sequential development of microstructures can be divided into three stages; weakly-foliated, well-foliated and banded-foliated stages. In the weakly-foliated stage dislocation glide mechanism might be predominant. In the well-foliated stage grain boundary migration and progressive misorientation of subgrains was remarkable during dynamic recovery and recrystallization. In the banded-foliated stage grain boundary sliding and microfracturing mechanisms accompanied with crushing and cracking were marked. According to strain analysis from quartzites of the metasedimentary rocks, strain intensity (${\gamma}$) of the samples within the ductile shear zone ranges from 2.7 to 5.7, while that of the samples out of the ductile shear zone appears to be about 1.7.

• International Journal of Concrete Structures and Materials
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• v.8 no.4
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• pp.289-299
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• 2014

Alkali-activated slag concretes are being extensively researched because of its potential sustainability-related benefits. For such concretes to be implemented in large scale concrete applications such as infrastructural and building elements, it is essential to understand its early and long-term performance characteristics vis-a'-vis conventional ordinary portland cement (OPC) based concretes. This paper presents a comprehensive study of the property and performance features including early-age isothermal calorimetric response, compressive strength development with time, microstructural features such as the pore volume and representative pore size, and accelerated chloride transport resistance of OPC and alkali-activated binder systems. Slag mixtures activated using sodium silicate solution ($SiO_2$-to-$Na_2O$ ratio or $M_s$ of 1-2) to provide a total alkalinity of 0.05 ($Na_2O$-to-binder ratio) are compared with OPC mixtures with and without partial cement replacement with Class F fly ash (20 % by mass) or silica fume (6 % by mass). Major similarities are noted between these binder systems for: (1) calorimetric response with respect to the presence of features even though the locations and peaks vary based on $M_s$, (2) compressive strength and its development, (3) total porosity and pore size, and (4) rapid chloride permeability and non-steady state migration coefficients. Moreover, electrical impedance based circuit models are used to bring out the microstructural features (resistance of the connected pores, and capacitances of the solid phase and pore-solid interface) that are similar in conventional OPC and alkali-activated slag concretes. This study thus demonstrates that performance-equivalent alkali-activated slag systems that are more sustainable from energy and environmental standpoints can be proportioned.

• Journal of the Korean association of regional geographers
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• v.19 no.4
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• pp.580-599
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• 2013

After the unification of Three Kingdoms, Silla Dynasty had been on the prosperity with continuous population growth during approximately 120 years. However, Unified Silla Dynasty experienced 11 times of famine and bad year by frequent droughts during 50 years since the late 8th century, and these caused to political, economic and social changes. It is evident that Silla Dynasty slowly declined by the droughts and famines, although ancient records described as still on glory days. Since then, national power of Unified Silla Dynasty was abruptly weakened by migration of residents, and 9 times of rebellion or revolt occurred during 50 years in the late 9th century. As a result, political and social agitations reached the maximum. These led to the collapse of the Unified Silla Dynasty, and King Gyeongsoon handed over the dynasty to King Wanggeon, a founder of Goryeo Dynasty. These resulted from the 500-year-cycle droughts and human activities that seriously devastated the vegetations by using trees as an energy source for hundreds of thousands people during several centuries. The devastation of vegetation destroyed farm lands and led to large changes in river and groundwater systems, and eventually, increased damages by droughts.

• Economic and Environmental Geology
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• v.18 no.1
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• pp.55-63
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• 1985

Studies based on field observation and laboratory analysis of the littoral sands of beaches in Jeju Island indicate that the shores exhibit a great variation in both the beach geometry and the composition in terms of geological agents. Most of the beaches around the Island are developed in relatively small patches and discontinuous, as the result of intervening sea cliffs and rocky headlands. The sand quality and the dimensions of the beaches in the Island are relatively poor; for example, these beaches are 220~2,780m in length, 41~313m in width, and $7^{\circ}$ steepness in average foreshore slope. According to the textural parameters analysis, the beach sediments in study portion shows medium grained ($average\;1.42{\phi}$), moderately well sorted ($average\;0.65{\phi}$) and negative skewed ($average\;0.34{\phi}$), which seems to reflecting a high energy marine depositional environment. The heavy and light minerals of te beach sediments are composed of quartz, volcanic fragments, Na-Ca feldspar, olivine, augite as major constituents, along with apatite, biotite and other minor components, which originates from the adjacent geology. The content of CaO-MgO in shell fragments of the littoral sands ranged from 4.69~51.96%, suggesting that the high CaO-MgO content in some of the Island's beaches is attributable to geologic environments conducive to the growth of shell organisms and sediments migration. The provenance of the sediments studied are derived predominantly from adjacent continental shelves and/or terrigenous older river portion, Which sediments were transported mostly by rolling or bottom suspension. The depositional environments of the Jeju beaches can be divided into two types: beaches distributed in the North and the Northeastern parts of the Island are dominated by marine enviroment, whereas beaches in the Southwestern portion are characterized by terrigenous agencies.