• Journal of the Korean Chemical Society
• /
• v.28 no.3
• /
• pp.170-175
• /
• 1984

The transport rates of $H^+$ ion by DBC and DCC as carrier molecules through organic liquid membranes were determined at 25$^{\circ}$C. The transport rates depend highly on the dielectric constants of membrane solvents and these results were discussed in terms of Born's potential energy barrier methods. The sizes of anions also affect the transport rates and these results were well explained theoreticlly by extended Born's equation.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.10
• /
• pp.2835-2840
• /
• 2010

A series of $MoO_3/CeO_2-ZrO_2$ catalysts with different Mo content (8 - 20 wt %) were prepared by simple co-precipitation followed by impregnation method and were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM), energy dispersive spectroscopic (EDS) techniques. The prepared materials were tested for catalytic activity by the synthesis of benzimidazole derivatives using condensation of aromatic aldehydes and o-phenylenediamine by conventional and microwave method. Obtained results reveal that the catalytic activity increases with increase in Mo wt % loading. The best catalytic activity was obtained with 20 wt % $MoO_3/CeO_2-ZrO_2$. The particle size or crystallite size was estimated using Debye-Scherrer equation. After completion of reaction, the catalyst can be recovered efficiently and reused with consistent activity.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.5 no.3
• /
• pp.212-220
• /
• 1993

A numerical model for the transformation of irregular waves in a coastal area is developed, which takes account of shoaling, refraction, diffraction, bottom friction and wave breaking. The governing equations are the usual energy conservation equation and kinematic conservation equations, but to consider the diffraction effects additional terms are included in the usual kinematic conservation or wave number equations. A linear superposition technique is used to represent the spectral formation. and an explicit formula is developed for the estimation of friction factor of irregular waves. A breaking criterion of component waves, which is the modified form of the Kitaigorodskii saturation relation, is employed to restrict the growth of shoaling waves in very shallow waters. The model was applied to a laboratory test and satisfactory agreement was obtained between the computation and measurement.

• Journal of Ocean Engineering and Technology
• /
• v.26 no.6
• /
• pp.39-45
• /
• 2012

Underwater robots are generally used for the construction of seabed structures, deep-sea ecosystem research, ocean energy development, etc. A ducted marine propulsor is widely used for the thruster of an underwater robot because of its collision protection, efficiency increase, cavitation reduction, etc. However, the flow of a ducted propeller is very complex because it involves strong flow interactions between the blade impeller and duct. The present work aimed to design a ducted propeller using 2-D strip theory and CFD analysis. The hydrodynamic forces (i.e. and ) were computed to set the local angle of attack in a spanwise direction of the propeller blade. After the propeller design, performance coefficients such as the thrust, torque, and efficiency were computed to check whether the designed performance was achieved. To validate the present analysis, the thrust was compared with experimental data and good agreement was obtained.

• Journal of the Korean Society of Safety
• /
• v.27 no.3
• /
• pp.89-95
• /
• 2012

The concentrations of Volatile Organic Compounds(VOCs) and Formaldehyde(HCHO) for interior materials of new vehicles are estimated and recognized by using the simulation program known as IAQx. The concentrations of contaminants are estimated and evaluated by the ventilation rates of new domestic vehicles and the required ventilation rates for new vehicles are estimated through the given contaminant data. This study is conducted to compare the ventilation rates for the contaminants between the discontinuously ventilated new vehicles and the continuously ventilated new vehicles using the simulation program. The equation of ventilation rate of new vehicles is acquired to be able to lower initial concentrations below the standard level under different conditions for both business and personal commuting.

• Journal of the Korean Institute of Gas
• /
• v.9 no.2 s.27
• /
• pp.22-27
• /
• 2005

In this study, we analyze computational simulation of cryogenic distillation process to separate $^{13}CH_4$ and $^{12}CH_4$ from LNG by using the cryogenic energy. Used computational simulation program is made Smoker's equation and FUG(Fenske-Underwood-Gilliland)'s method by short-cut method. Generally speaking, the technology of carbon isotope separation is studied by many methods, especially the separation by cryogenic distillation process is commercialized because of many merits.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.30 no.12C
• /
• pp.1214-1221
• /
• 2005

In this paper, we propose a digital watermarking method for still images, in which the human visual system (HVS) is used in the discrete cosine transform (DCT) domain. The modulation transfer function (MTF) of the HVS model is employed to increase the invisibility of the inserted watermark in images. The proposed watermarking method is shown to be robust to several common image processing techniques, including lowpass filtering and cropping. Also, using the energy relationship of the DCT, we derive the equation that directly computes the watermark weighting factor in the DCT domain for the specified peak signal to noise ratio (PSNR) of the still image and the length of watermark to be inserted. The difference between desired PSNR and PSNR in spatial domain is within 0.07dB for the 7 test images.

• Journal of the Korean Chemical Society
• /
• v.53 no.6
• /
• pp.635-639
• /
• 2009

Experimental work was carried out to study the combustion kinetics of the Indian coal-char in the varying mixture of carbon dioxide-oxygen ($CO_2-O_2$). The coal sample was pulverized and sieved to less than 58 microns and charred using volatile furnace by passing the nitrogen gas. The experiments were carried out using the Thermo Gravimetric Analyzer (TGA-50) at CPRI, Bangalore, different proportions of ($CO_2-O_2$) gas was allowed in to the TGA-50 (80-20, 60-40, 40-60, 20-80) mole basis were used to study the combustion kinetics of coal Isothermally, kinetic parameters like Activation energy (E) and the pre-exponential factors (A) are calculated using the unification approach and modified Arrhenius equation.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.21 no.5
• /
• pp.475-482
• /
• 2008

This paper indicates that the use of Euler angles lacks in its consistency and exactness of analysis when it was applied to incorporate the rotational equation of motion for rotor systems by previous researcher. Kinetic energy and angular velocity are different from case to case depending on the way of choosing Euler angles and thus only the linear system has been investigated even though the rotor system has a very nonlinear behavior. A new methodology is applied by using both spherical coordinate and quaternion in the rotor rotation to overcome weaknesses of Euler angles and shows its superiority It is found through numerical examples that the use of quaternion will be a more useful and valid tool to derive the numerical model of the rotor system.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2004.04a
• /
• pp.214-217
• /
• 2004

The cure kinetics of blends of epoxy(tetraglycidyl-4,4'-diaminodiphenylmethane ; TGDDM)/curing agent(diaminodiphenyl sulfone ; DDS) resin with amine terminated polyetherimide-CTBN-amine terminated polyetherimide triblock copolymer(ABA) were studied using differential scanning calorimetry under isothermal conditions to determine the reaction parameters such as activation energy and reaction constants. By increasing the amount of ABA in the blends, the final cure conversion was decreased. Lower values of the final cure conversions in the epoxy/ABA blends indicated that ABA hinders the cure reaction between the epoxy and curing agents. 1be value of the reaction order, m, for the initial autocatlytic reaction was not affected by blending ABA with epoxy resin, and the value was approximately 1.0. The value of n for the nth order component in the autocatalytic analysis was increased by increasing the amount of ABA in the blends, and the value increased from 2.0-3.4. A diffusion controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/DDS/ABA blends.