• 제목/요약/키워드: Energy Diffusion

검색결과 1,547건 처리시간 0.026초

TiC-$Cr_3C_2$ 계 확산구동 재결정에 미치는 ZrC와 VC 첨가영향 (Effects of ZrC and VC Addition on the Diffusion Induced Recrystallization of TiC--$Cr_3C_2$)

  • 채기웅
    • 한국세라믹학회지
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    • 제33권2호
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    • pp.223-227
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    • 1996
  • The effect of ZrC and VC addition on the diffusion induced recrystallization (DIR) of TiC-Cr3C2 has been investigated. With in creasing the amount of added ZrC to Cr3C2 the DIR of TiC was suppressed at the begining and then occurred. On the contrary the DIR was accelerated with the addition of VC to Cr3C2 Because the lattice parameters of (Ti, Cr)C and (Ti,V)C are smaller and that of (Ti, Zr)C is larger than that of TiC the lattice parameter of (Ti,Cr,Zr)C is expected to be similar to that of TiC,. The results indicate that the strain energy due to lattice mismatch between TiC and solid-solution carbide is the driving force of the observed energy due to lattice mismatch between TiC and solid-solution carbide is the driving force of the observed DIR.

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직접메탄올연료전지에서 메탄올 크로스오버에 미치는 인자 연구 (Investigation of Factors Influencing Methanol Crossover in Direct Methanol Fuel Cell)

  • 현민수;김상경;임성엽;이병록;백동현;정두환
    • 전기화학회지
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    • 제11권1호
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    • pp.6-10
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    • 2008
  • 직접메탄올연료전지의 운전 변수에 따른 메탄올 크로스오버를 메탄올 농도센서를 이용하여 정량적으로 측정하였으며 실제 셀 운전 시 메탄올크로스오버 저감의 측면에서 유리한 운전조건을 분석하였다. 메탄올 농도, 전극 양단의 압력차, 전류의 크기, 온도, stoichiometry등을 변화시켜 diffusion, convection, electro-osmosis의 메커니즘별 기여도와 실제 전지 운전 조건의 영향을 함께 분석하였다. 이상의 세 가지 메커니즘 중에서 농도 차이에 의한 diffusion이 가장 큰 영향을 미쳤으며 electro-osmosis에 의한 영향은 고농도에서만 관찰할 수 있었다.

란탄족 원소와 Ferritic-Martensitic 강의 반응 거동 (Interaction Behavior between Lanthanide Element and Ferritic-Martensitic Steel)

  • 김준환;백종혁;이병운;이찬복;윤영수
    • 대한금속재료학회지
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    • 제48권8호
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    • pp.691-698
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    • 2010
  • A study has been carried out to evaluate the interaction behavior between a lanthanide element and clad material in order to analyze the effect of the lanthanide element on the fuel cladding chemical interaction (FCCI). A diffusion couple test between Misch metal (70Ce-30La) and ferritic-martensitic steel (Gr.92) was performed at $660^{\circ}C$, followed by a microstructural analysis of the coupled sample. The results showed that Ce in the Misch metal, rather than La, reacted with the ferritic-martensitic steel (FMS) to form an interaction layer that penetrated the clad thickness. Fe diffused outside the clad interface to form an $Fe_2Ce$ compound, leaving a depletion of Fe caused by excess diffusion as well as by the formation of Cr-rich precipitation inside the interaction layer. The rate of growth followed the cubic rate law, which indicated that Fe depletion was caused by the diffusion of Fe and that the associated Cr-rich phase formation controlled the whole diffusion process.

BIFURCATION ANALYSIS OF A SINGLE SPECIES REACTION-DIFFUSION MODEL WITH NONLOCAL DELAY

  • Zhou, Jun
    • 대한수학회지
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    • 제57권1호
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    • pp.249-281
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    • 2020
  • A reaction-diffusion model with spatiotemporal delay modeling the dynamical behavior of a single species is investigated. The parameter regions for the local stability, global stability and instability of the unique positive constant steady state solution are derived. The conditions of the occurrence of Turing (diffusion-driven) instability are obtained. The existence of time-periodic solutions, the existence and nonexistence of nonconstant positive steady state solutions are proved by bifurcation method and energy method. Numerical simulations are presented to verify and illustrate the theoretical results.

백금 확산 실리콘의 깊은 에너지 준위의 농도분포에 대한 열처리효과 (Annealing Effects on Concentration Profiles of Deep Energy Levels in Platinum-diffused Silicon)

  • 권영규
    • 한국전기전자재료학회논문지
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    • 제20권3호
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    • pp.207-212
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    • 2007
  • The concentration profiles of deep energy levels($E_c$ -0.23e V, $E_v$+0.36e V and $E_c$ -0.23e V) in platinum-diffused silicon have generally a sharp gradient in the vicinity of the surface of the silicon wafer. In this work two efficient methods are proposed to obtain the uniform concentration profiles throughout the silicon wafer. One is that the platinum diffusion is carried out at $1000^{\circ}C$ for 1h in oxygen atmosphere. In this case the values of obtained uniform concentration, $1{\times}10^{15}cm^{-3}$ for the $E_c$ -0.23e V level, and 1{\times}10^{14}cm^{-3}$ for the $E_c$ -0.52e V level, are very restricted, respectively. The other is two-step annealing process. The platinum diffusion is carried out at $850{\sim}1100^{\circ}C$ in a nitrogen ambient for 1h and then the annealing is performed at $1000^{\circ}C$ in oxygen ambient after removing platinum-source from the platinum diffused samples. The advantage of this method is that the uniform concentration of these levels required power devices can be controlled by setting the desired temperatures when the platinum diffusion is carried out in nitrogen ambient.

Analysis of radon depth profile in soil air after a rainfall by using diffusion model

  • Maeng, Seongjin;Han, Seung Yeon;Lee, Sang Hoon
    • Nuclear Engineering and Technology
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    • 제51권8호
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    • pp.2013-2017
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    • 2019
  • The radon concentrations in soil air were measured before and after a rainfall. 226Ra concentration, porosity, moisture content and temperature in soil were measured at Kyungpook National University in Daegu. As the results of measurement and analysis, the arithmetic mean of measured 222Rn concentration increased from 12100 ± 500 Bq/㎥ to 16200 ± 600 Bq/㎥ after the rainfall. And the measured 226Ra concentration was 61.4 ± 5.7 Bq/kg and the measured porosity was 0.5 in soil. The estimated values of 226Ra concentration and porosity using diffusion model of 222Rn in soil were 60.3 Bq/kg and 0.509, respectively. The estimated values were similar to the measured values. 222Rn concentration in soil increased with depth and moisture content. The estimations were obtained through fitting based on the diffusion model of 222Rn using the measurement values. The measured depth profiles of 222Rn were similar to the calculated depth profiles of 222Rn in soil. We hope that the results of this study will be useful for environmental radiation analysis.