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Experimental Study on the Adsorption Characteristics of Methane Gas Considering Coalbed Depth in Coalbed Methane Reservoirs (석탄층 메탄가스 저류층에서 탄층 심도를 고려한 메탄가스의 흡착 특성에 관한 실험 연구)

  • Chayoung Song;Dongjin Lee;Jeonghwan Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.39-48
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    • 2023
  • This study presents the experimental results to measure the adsorption amount of methane gas by coal according to the conditions of a coalbed methane (CBM) reservoir. Adsorbed gas to coal seam particles was measured under reservoir conditions (normal pressure ~ 1,200 psi pressure range, temperature range15 ~ 45℃) using coal samples obtained from random mines in Kalimantan Island, North Indonesia. The obtained amount of absolute adsorbed gas was applied to triangular with linear interpolation to calculate the maximum amount of adsorbed gas according to temperature and pressure change, at which no experiment was performed. As a result, it was revealed that the amount of adsorbed gas to coal particles increased as the pressure increased and temperature decreased, but the increase of the amount of adsorbed gas decreased at more than an appropriate depth(1,000 ft). In the cleat permeability and cleat porosity for each depth of the coal bed considering the effective stress, the cleat permeability was 28.86 ~ 46.81 md, and the cleat porosity was 0.83 ~ 0.98%. This means that the gas productivity varies significantly with the depth because the reduction of the permeability according to the depth in the coal seam is significant. Therefore, a coalbed depth should be considered essential when designing the spacing of production wells in a coalbed methane reservoir in further study.

The Removal of Impurities from Domestic Graphite Concentrate by H2SO4 Solution and NaOH Solution Leaching (황산용액과 수산화나트륨용액의 침출에 의한 국내산 흑연 정광으로부터 불순물 제거)

  • Junseop Lee;Kyoungkeun Yoo;Hyunkyoo Park
    • Resources Recycling
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    • v.32 no.3
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    • pp.38-44
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    • 2023
  • Leaching tests were conducted using sulfuric acid and sodium hydroxide solutions to remove impurities from domestic graphite concentrate. As a result of the leaching experiment using sulfuric acid solution and sodium hydroxide solution, respectively, the difference of removal efficiency was insignificant when the concentration of sodium hydroxide or sulfuric acid was 2 mol/L or more. The fixed carbon content increased with increasing the temperature in the sulfuric acid solution leaching, while it remains constant above 150℃ in sodium hydroxide solution. For the repeated sequential leaching tests, the leaching conditions were 2 mol/L NaOH, 200℃, 1 hour in the sodium hydroxide solution leaching and 2 mol/L H2SO4, 100℃, 1 hour in the sulfuric acid solution leaching, respectively. When sulfuric acid leaching followed by sodium hydroxide solution leaching was repeated 5 times, the fixed carbon increased to 99.95% and ash content decreased to 0.048%, while the fixed carbon increased to 99.98% and ash content was reduced to 0.018 when sodium hydroxide solution leaching followed by sulfuric acid solution leaching was repeated 5 times.

Improving the Performance of Deep-Learning-Based Ground-Penetrating Radar Cavity Detection Model using Data Augmentation and Ensemble Techniques (데이터 증강 및 앙상블 기법을 이용한 딥러닝 기반 GPR 공동 탐지 모델 성능 향상 연구)

  • Yonguk Choi;Sangjin Seo;Hangilro Jang;Daeung Yoon
    • Geophysics and Geophysical Exploration
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    • v.26 no.4
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    • pp.211-228
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    • 2023
  • Ground-penetrating radar (GPR) surveys are commonly used to monitor embankments, which is a nondestructive geophysical method. The results of GPR surveys can be complex, depending on the situation, and data processing and interpretation are subject to expert experiences, potentially resulting in false detection. Additionally, this process is time-intensive. Consequently, various studies have been undertaken to detect cavities in GPR survey data using deep learning methods. Deep-learning-based approaches require abundant data for training, but GPR field survey data are often scarce due to cost and other factors constaining field studies. Therefore, in this study, a deep- learning-based model was developed for embankment GPR survey cavity detection using data augmentation strategies. A dataset was constructed by collecting survey data over several years from the same embankment. A you look only once (YOLO) model, commonly used in computer vision for object detection, was employed for this purpose. By comparing and analyzing various strategies, the optimal data augmentation approach was determined. After initial model development, a stepwise process was employed, including box clustering, transfer learning, self-ensemble, and model ensemble techniques, to enhance the final model performance. The model performance was evaluated, with the results demonstrating its effectiveness in detecting cavities in embankment GPR survey data.

A Study on the Production Well Spacing Design Considering Coalbed Depth in Coalbed Methane Reservoirs (석탄층 메탄가스 저류층에서 탄층 심도를 고려한 생산정 간격 설계 연구)

  • Chayoung Song;Dongjin Lee;Jeonghwan Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.98-107
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    • 2023
  • This study presents a well spacing design for coalbed methane(CBM) reservoirs using the experimental results of methane gas adsorption measurement of coal samples obtained from North Kalimantan Island, Indonesia. The gas productivity analysis shows that the cumulative gas production increases as the Langmuir volume increases. This indicates that the maximum gas adsorption directly affects the gas production. In addition, the maximum gas production increases with the increase of reservoir permeability, and the dewatering period is shortened. In particular, the cumulative gas production increases as the production influence area increases. However, when comparing productivity per unit well, the maximum cumulative gas production is found between 2,000 ft of depth and 80-160 acres of the influence area. When reservoir depth and production influence area are considered simultaneously, the results of the appropriate well depth and spacing calculations show that gas productivity is highest between 600-2,000 ft. In this case, it is appropriate to design well spacing in the range of 80-160 acres. Therefore, well spacing design considering coalbed depth in undeveloped CBM reservoirs can be accomplished using gas sorption test results from coal samples.

A Study on the Geochemical Clogging for the Assessment of the Hydrological Safety of the Underground Oil Storage Carvern (지하유류비축기지 수리안정성 평가를 위한 광물학적 클로깅 가능성 연구)

  • Kim, Geon-Young;Bae, Dae-Seok;Choi, Byeong-Young;Oh, Se-Joong;Koh, Yong-Hwon
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.2
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    • pp.139-159
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    • 2008
  • Geochemical analysis of the various kinds of water including observation borehole groundwater was carried out for the assessment of the hydrological safety of the underground oil storage cavern and the potentiality of mineralogical and microbiological clogging was estimated. Most of water samples belonged to $Ca-HCO_3$ and $Ca-HCO_3-SO_4$ types. There was no distinct chemical difference in the various kinds of water. All kinds of water are undersaturated with the calcite which is the major clogging mineral. Most water samples have low Fe and Mn concentrations. However, they are saturated or oversaturated with the iron-oxide/hydroxide minerals and have high dissolved oxygen contents which suggests the possibility of clogging by the iron-oxide/hydroxide minerals as a long-term aspect. Several water samples from the ground observation borehole also show the high saturation indices far the clay minerals, which can fill up the fractures, indicating the possibility of clogging by the clay minerals. Statistical analysis shows the degree of mineral precipitation or dissolution is mainly controlled by pH, Eh and DO of water samples. According to the microbial analysis, the aerobic microbes and slime forming bacteria are dominant in most water samples and anaerobic microbes including sulfate reducing bacteria are very low or not detected. Although the slime forming bacteria which are known as a main microbial cause of the clogging is lower than $10^5\;CFUs/mL$ in all water samples, because the slime forming bacteria are dominant microbe in several observation boreholes, the clogging can be caused by it as a long-term aspect. In addition, the possibility of clogging can be increased if the microbial effect is combined with the mineralogical effect such as iron oxide/hydroxide minerals for the possibility of clogging. Therefore, the systematic and long-term program for the assessment of clogging is required for the safe operation of underground oil storage cavern.

The Effects of Solidified Sewage Sludge as a Soil Cover Material for Cultivation of Bioenergy Crops in Reclaimed Land (에너지작물 재배를 위한 간척지 토양의 토양복토재로써 하수슬러지 고화물의 이용효과)

  • An, Gi-Hong;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Cha, Young-Lok;Bark, Surn-Teh;Kim, Jung-Kon;Yoon, Yong-Mi;Park, Kwang-Guen;Kim, Jang-Taeck
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.3
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    • pp.238-247
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    • 2012
  • To determine the possibility of solidified se wage sludge for use as a soil cover material in reclaimed land, the growth of energy crops and soil chemical properties investigated in each experimental plots during 2 years (2010 and 2011). The experimental plots consisted of the mixing with solidified sewage sludge plot (SS50), the covering with solidified sewage sludge plot (SS100), and the original reclaimed land plot (ORL) on reclaimed land for the intended landfill in Sudokwon Landfill Site Management Corporation (SLC). Plant height, measured in the second year (2011), was highest in the Geodae 1 grown at plots treated with solidified sewage sludge. The growth of energy crops cultivated in both SS50 and SS100 were better than in ORL. The contents of organic matter (OM) and total nitrogen (T-N) at both SS50 and SS100 were considerably higher than that of the ORL over 2 years. However, the soil from ORL showed higher salinity with high contents of exchangeable $Na^+$ cation than that of SS50 and SS100 over 2 years. We consider that soil chemical and physical properties on reclaimed land used in this study could be improved by the application of solidified sewage sludge due to following reasons. Firstly, the application of solidified sewage sludge may provide soil nutrients on reclaimed land i.e. the growth of energy crops better than in ORL, resulted in more OM and T-N contents in SS50 and SS100. Secondly, the top layers mixed or covered with solidified sewage sludge on reclaimed land may be prevented the salinity accumulation due to capillary rise to surface soil, and improved the cultivation layer for effectively propagating the rhizomes of energy crops. Thus the solidified sewage sludge may be a great soil cover materials for cultivation of bioenergy crops in reclaimed land.

A Study for the Methodology of Analyzing the Operation Behavior of Thermal Energy Grids with Connecting Operation (열 에너지 그리드 연계운전의 운전 거동 특성 분석을 위한 방법론에 관한 연구)

  • Im, Yong Hoon;Lee, Jae Yong;Chung, Mo
    • KIPS Transactions on Computer and Communication Systems
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    • v.1 no.3
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    • pp.143-150
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    • 2012
  • A simulation methodology and corresponding program based on it is to be discussed for analyzing the effects of the networking operation of existing DHC system in connection with CHP system on-site. The practical simulation for arbitrary areas with various building compositions is carried out for the analysis of operational features in both systems, and the various aspects of thermal energy grids with connecting operation are highlighted through the detailed assessment of predicted results. The intrinsic operational features of CHP prime movers, gas engine, gas turbine etc., are effectively implemented by realizing the performance data, i.e. actual operation efficiency in the full and part loads range. For the sake of simplicity, a simple mathematical correlation model is proposed for simulating various aspects of change effectively on the existing DHC system side due to the connecting operation, instead of performing cycle simulations separately. The empirical correlations are developed using the hourly based annual operation data for a branch of the Korean District Heating Corporation (KDHC) and are implicit in relation between main operation parameters such as fuel consumption by use, heat and power production. In the simulation, a variety of system configurations are able to be considered according to any combination of the probable CHP prime-movers, absorption or turbo type cooling chillers of every kind and capacity. From the analysis of the thermal network operation simulations, it is found that the newly proposed methodology of mathematical correlation for modelling of the existing DHC system functions effectively in reflecting the operational variations due to thermal energy grids with connecting operation. The effects of intrinsic features of CHP prime-movers, e.g. the different ratio of heat and power production, various combinations of different types of chillers (i.e. absorption and turbo types) on the overall system operation are discussed in detail with the consideration of operation schemes and corresponding simulation algorithms.

Optimal Operation of Gas Engine for Biogas Plant in Sewage Treatment Plant (하수처리장 바이오가스 플랜트의 가스엔진 최적 운영 방안)

  • Kim, Gill Jung;Kim, Lae Hyun
    • Journal of Energy Engineering
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    • v.28 no.2
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    • pp.18-35
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    • 2019
  • The Korea District Heating Corporation operates a gas engine generator with a capacity of $4500m^3 /day$ of biogas generated from the sewage treatment plant of the Nanji Water Recycling Center and 1,500 kW. However, the actual operation experience of the biogas power plant is insufficient, and due to lack of accumulated technology and know-how, frequent breakdown and stoppage of the gas engine causes a lot of economic loss. Therefore, it is necessary to prepare technical fundamental measures for stable operation of the power plant In this study, a series of process problems of the gas engine plant using the biogas generated in the sewage treatment plant of the Nanji Water Recovery Center were identified and the optimization of the actual operation was made by minimizing the problems in each step. In order to purify the gas, which is the main cause of the failure stop, the conditions for establishing the quality standard of the adsorption capacity of the activated carbon were established through the analysis of the components and the adsorption test for the active carbon being used at present. In addition, the system was applied to actual operation by applying standards for replacement cycle of activated carbon to minimize impurities, strengthening measurement period of hydrogen sulfide, localization of activated carbon, and strengthening and improving the operation standards of the plant. As a result, the operating performance of gas engine # 1 was increased by 530% and the operation of the second engine was increased by 250%. In addition, improvement of vent line equipment has reduced work process and increased normal operation time and operation rate. In terms of economic efficiency, it also showed a sales increase of KRW 77,000 / year. By applying the strengthening and improvement measures of operating standards, it is possible to reduce the stoppage of the biogas plant, increase the utilization rate, It is judged to be an operational plan.

Effects of Application of Solidified Sewage Sludge on the Growth of Bioenergy Crops in Reclaimed Land (간척지토양에서 하수슬러지 고화물 처리가 에너지작물의 생육에 미치는 영향)

  • An, Gi-Hong;Lee, Sun-Il;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Cha, Young-Lok;Bark, Surn-Teh;Kim, Jung-Kon;Kim, Byung-Chul;Kim, Sang-Pyeong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.56 no.4
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    • pp.299-307
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    • 2011
  • This study was carried out to obtain the basic data for selecting the cultivatable bioenergy crops through application of solidified sewage sludge in reclaimed lands. The experimental plots consisted of the mixing with solidified sewage sludge plot (SS50), the covering with solidified sewage sludge plot (SS100), and the original reclaimed land plot (ORL) on reclaimed land for the intended landfill in Sudokwon Landfill Site Management Corporation (SLC). The growth of energy crops (Geodae-Uksae 1, Miscanthus sacchariflorus, and Phragmites australis) were investigated from May to October, 2010 in each experimental plot. The soil from ORL showed higher salinity with high contents of exchangeable $Na^+$ cation than that of SS50 and SS100. Soil properties on reclaimed land used in this study must be improved by increasing the buffering capacity of saline with the treatment of solidified sewage sludge due to the fact that the contents of organic matter (OM) in both of SS50 and SS100 were higher than that of the ORL. Thus the growth of energy crops cultivated in the solidified sewage sludge plots were better than in ORL. Geodae-Uksae 1 which showed an excellent adaptability on reclaimed land treated with the solidified sewage sludge has considerably higher biomass than those of other energy crops (M. sacchariflorus and P. australis). This study suggested that Geodae-Uksae 1 is the most suitable biomass feedstock crop for bioenergy productions, and the solidified sewage sludge may be possible to utilize as a soil cover materials for cultivation of bioenergy crops in reclaimed land.

Estimation of Groundwater Table using Ground Penetration Radar (GPR) in a Sand Tank Model and at an Alluvial Field Site (실내 모형과 현장 충적층에서 지하투과레이더를 이용한 지하수면 추정)

  • Kim, Byung-Woo;Kim, Hyoung-Soo;Choi, Doo-Houng;Koh, Yong-Kwon
    • The Journal of Engineering Geology
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    • v.23 no.3
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    • pp.201-216
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    • 2013
  • Ground penetrating radar (GPR) surveys were conducted in a sand tank model in a laboratory and at an alluvial field site to detect the groundwater table and to investigate the influence of saturation on GPR response in the unsaturated zone. In the sand tank model, the groundwater table and saturation in the sand layer were altered by injecting water, which was then drained by a valve inserted into the bottom of the tank. GPR vertical reflection profile (VRP) data were obtained in the sand tank model for rising and lowering of the groundwater table to estimate the groundwater table and saturation. Results of the lab-scale model provide information on the sensitivity of GPR signals to changes in the water content and in the groundwater table. GPR wave velocities in the vadose zone are controlled mainly by variations in water content (increased travel time is interpreted as an increase in saturation). At the field site, VRP data were collected to a depth of 220 m to estimate the groundwater table at an alluvial site near the Nakdong river at Iryong-ri, Haman-gun, South Korea. Results of the field survey indicate that under saturated conditions, the first reflector of the GPR is indicative of the capillary fringe and not the actual groundwater table. To measure the groundwater table more accurately, we performed a GPR survey using the common mid-point (CMP) method in the vicinity of well-3, and sunk a well to check the groundwater table. The resultant CMP data revealed reflective events from the capillary fringe and groundwater table showing hyperbolic patterns. The normal moveout correction was applied to evaluate the velocity of the GPR, which improved the accuracy of saturation and groundwater table information at depth. The GPR results show that the saturation information, including the groundwater table, is useful in assessing the hydrogeologic properties of the vadose zone in the field.