• Title/Summary/Keyword: Energy & fuel technology

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Problems and Solutions of Anion Exchange Membranes for Anion Exchange Membrane Fuel Cell (AEMFC) (음이온교환막연료전지용 음이온교환막의 문제점과 해결방안)

  • Son, Tae Yang;Kim, Tae Hyun;Kim, Hyoung Juhn;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.489-496
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    • 2018
  • Fuel cells are seen as eco-friendly energy resources that convert chemical energy into electrical energy. However, proton exchange membrane fuel cells (PEMFCs) have problems such as the use of expensive platinum catalysts for the reduction of conductivity under high temperature humidification conditions. Thus, an anion exchange membrane fuel cell (AEMFC) is attracting a great attention. Anion exchange fuel cells use non - Pt catalysts and have the advantage of better efficiency because of the lower activation energy of the oxygen reduction reaction. However, there are various problems to be solved including problems such as the electrode damage and reduction of ion conductivity by being exposed to the carbon dioxide. Therefore, this mini review proposes various solutions for different problems of anion exchange fuel cells through a wide range of research papers.

Thermal-fluid-structure coupling analysis for plate-type fuel assembly under irradiation. Part-I numerical methodology

  • Li, Yuanming;Yuan, Pan;Ren, Quan-yao;Su, Guanghui;Yu, Hongxing;Wang, Haoyu;Zheng, Meiyin;Wu, Yingwei;Ding, Shurong
    • Nuclear Engineering and Technology
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    • v.53 no.5
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    • pp.1540-1555
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    • 2021
  • The plate-type fuel assembly adopted in nuclear research reactor suffers from complicated effect induced by non-uniform irradiation, which might affect its stress conditions, mechanical behavior and thermal-hydraulic performance. A reliable numerical method is of great importance to reveal the complex evolution of mechanical deformation, flow redistribution and temperature field for the plate-type fuel assembly under non-uniform irradiation. This paper is the first part of a two-part study developing the numerical methodology for the thermal-fluid-structure coupling behaviors of plate-type fuel assembly under irradiation. In this paper, the thermal-fluid-structure coupling methodology has been developed for plate-type fuel assembly under non-uniform irradiation condition by exchanging thermal-hydraulic and mechanical deformation parameters between Finite Element Model (FEM) software and Computational Fluid Dynamic (CFD) software with Mesh-based parallel Code Coupling Interface (MpCCI), which has been validated with experimental results. Based on the established methodology, the effects of non-uniform irradiation and fluid were discussed, which demonstrated that the maximum mechanical deformation with irradiation was dozens of times larger than that without irradiation and the hydraulic load on fuel plates due to differential pressure played a dominant role in the mechanical deformation.

Characteristics of Reduced Metal from Spent Oxide Fuel by Lithium

  • Kim Ik-Soo;Seo Chung-Seok;Shin Hee-Sung;Hwang Yong-Soo;Park Seong-Won
    • Nuclear Engineering and Technology
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    • v.35 no.4
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    • pp.309-317
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    • 2003
  • The mass balance of the unit processes of the Advanced spent fuel Conditioning Process was calculated to obtain basic information. Based on this mass balance, the changes in decay heat and radioactivity of the spent fuel due to the metallization in the high temperature molten salt system were estimated. The decay heat and the radioactivity were calculated by using the ORIGEN2 computer code, and the result showed that the decay heat and the radioactivity of the metallized spent fuel ingot were $24.27\%\;and\;24.24\%$, respectively, compared to those of oxide spent fuel.

Towards a physics-based description of intra-granular helium behaviour in oxide fuel for application in fuel performance codes

  • Cognini, L.;Cechet, A.;Barani, T.;Pizzocri, D.;Van Uffelen, P.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.562-571
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    • 2021
  • In this work, we propose a new mechanistic model for the treatment of helium behaviour which includes the description of helium solubility in oxide fuel. The proposed model has been implemented in SCIANTIX and validated against annealing helium release experiments performed on small doped fuel samples. The overall agreement of the new model with the experimental data is satisfactory, and given the mechanistic formulation of the proposed model, it can be continuously and easily improved by directly including additional phenomena as related experimental data become available.

A surrogate model for the helium production rate in fast reactor MOX fuels

  • D. Pizzocri;M.G. Katsampiris;L. Luzzi;A. Magni;G. Zullo
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3071-3079
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    • 2023
  • Helium production in the nuclear fuel matrix during irradiation plays a critical role in the design and performance of Gen-IV reactor fuel, as it represents a life-limiting factor for the operation of fuel pins. In this work, a surrogate model for the helium production rate in fast reactor MOX fuels is developed, targeting its inclusion in engineering tools such as fuel performance codes. This surrogate model is based on synthetic datasets obtained via the SCIANTIX burnup module. Such datasets are generated using Latin hypercube sampling to cover the range of input parameters (e.g., fuel initial composition, fission rate density, and irradiation time) and exploiting the low computation requirement of the burnup module itself. The surrogate model is verified against the SCIANTIX burnup module results for helium production with satisfactory performance.

The developments of heavy hydrocarbon reformer for SOFC

  • Bae, Jung-Myeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.58.2-58.2
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    • 2012
  • Heavy hydrocarbon reforming is a core technology for "Dirty energy smart". Heavy hydrocarbons are components of fossil fuels, biomass, coke oven gas and etc. Heavy hydrocarbon reforming converts the fuels into $H_2$-rich syngas. And then $H_2$-rich syngas is used for the production of electricity, synthetic fuels and petrochemicals. Energy can be used efficiently and obtained from various sources by using $H_2$-rich syngas from heavy hydrocarbon reforming. Especially, the key point of "Dirty energy smart" is using "dirty fuel" which is wasted in an inefficient way. New energy conversion laboratory of KAIST has been researched diesel reforming for solid oxide fuel cell (SOFC) as a part of "Dirty energy smart". Diesel is heavy hydrocarbon fuels which has higher carbon number than natural gas, kerosene and gasoline. Diesel reforming has difficulties due to the evaporation of fuels and coke formation. Nevertheless, diesel reforming technology is directly applied to "Dirty fuel" because diesel has the similar chemical properties with "Dirty fuel". On the other hand, SOFC has advantages on high efficiency and wasted heat recovery. Nippon oil Co. of Japan recently commercializes 700We class SOFC system using city gas. Considering the market situation, the development of diesel reformer has a great ripple effect. SOFC system can be applied to auxiliary power unit and distributed power generation. In addition, "Dirty energy smart" can be realized by applying diesel reforming technology to "Dirty fuel". As well as material developments, multidirectional approaches are required to reform heavy hydrocarbon fuels and use $H_2$-rich gas in SOFC. Gd doped ceria (CGO, $Ce_{1-x}Gd_xO_{2-y}$) has been researched for not only electrolyte materials but also catalysts supports. In addition, catalysts infiltrated electrode over porous $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_3-{\delta}$ and catalyst deposition at three phase boundary are being investigated to improve the performance of SOFC. On the other hand, nozzle for diesel atomization and post-reforming for light-hydrocarbons removal are examples of solving material problems in multidirectional approaches. Likewise, multidirectional approaches are necessary to realize "Dirty energy smart" like reforming "Dirty fuel" for SOFC.

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Laser Welding of Seal Tube for Instrumented Irradiation Fuel Test (계장핵연료 조사시험용 실튜브 레이저용접기술)

  • Kim Soo-Sung;Lee Chul-Yong;Kim Woong-Ki;Park Geun-Il;Koh Jinh-Yun;Seo Jun-Seok
    • Journal of Welding and Joining
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    • v.23 no.6
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    • pp.43-48
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    • 2005
  • This work was carried out to obtain sound welds and to select a most suitable binary metal joint among three different dissimilar binary metal combinations such as Zr-4/Ta, Mo/Ta and Ti/Ta(seal tube/sensor sheath) joints fur the instrumented nuclear fuel irradiation test. To do this, Taguchi experimental method was employed to optimize the experimental data. In addition, metallography, micro-focus x-ray radiography and hardness test were conducted to examine the welds. From the weld bead appearance, penetration depth and bead width as well as weld defects standpoint, Zr-4/Ta joint is suggested for the circumferential joining between a seal tube and a sensor sheath. The optimized welding parameters based on Zr-4/Ta joint are suggested as well.

Automation design of spent fuel rod consolidation

  • Yun, Ji-Sup;Lee, Jae-Sol;Park, Hyun-Soo
    • 제어로봇시스템학회:학술대회논문집
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    • 1987.10b
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    • pp.613-618
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    • 1987
  • Rod consolidation is a method of increasing spent nuclear fuel storage capacity by disassembling fuel assemblies thus storing the fuel rods in a tighter array. It involves some basic operations which closely resemble to the material handling of a manufacturing process. But all the operations must be controlled remotely in shielded environment from outside due to the highly radioactive nature of the workpiece. In this study the status of the rod consolidation technology in other countries has been surveyed and a feasibility study for the conceptual design of this process have been made.

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Research and Development of Polymer Electrolyte Fuel Cells in Japan

  • Miyata, Seizo
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.60-61
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    • 2006
  • New Energy and Industrial Technology Development Organization (NEDO) promotes R&D that individual private sector enterprises can not undertake by themselves. To do this, it utilizes an extensive network that supports cooperation between industries, universities, and public research organizations. NEDO's government-funded R&D budget for FY2005 totals approximately 148.8 billion yen. Fuel cells and hydrogen technology development project is one of NEDO's emphasizing projects. The budget size was ${\yen}$20.8 billion, corresponding to about 60% of annual expenditure of Japanese government for fuel cells in FY2005. These projects consist of 8 programs as follows.

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Impact of experience on government policy toward acceptance of Hydrogen fuel cell vehicles (정부정책에 대한 경험이 수소 연료전지 자동차의 수용에 미치는 영향)

  • Gang, Min-Jeong;Park, Hui-Jun
    • Proceedings of the Korean Society for Quality Management Conference
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    • 2010.04a
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    • pp.465-470
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    • 2010
  • Korea government declared that "low carbon, green growth" through green technologies and clean energy to be the new national vision for the next 60 years(President's Liberation Day speech on Aug. 15, 2008). And succeeding "Green New Deal" plan involves nine core projects including energy saving, recycling, clean energy development. It is because hydrogen fuel cell vehicles, using electricity from chemical reaction of hydrogen and oxygen, let out water which is a by-product of such chemical reaction instead of emitting harmful particulate and gases such as NOX, SOX and CO2 that hydrogen fuel cell vehicles and its technology are drawing public attention as one of the sensible solutions in accomplishing "low carbon, green growth" agenda. Nevertheless There are many chances that let the people have a practical experience of hydrogen fuel cell vehicles. Sometimes new products, including hydrogen fuel cell vehicles, made by advanced technology can not penetrate through the market when it faces public skepticism that is stimulated from lack of knowledge and experience. That is the reason why not only cost benefit analyses and scientific risk assessments but also public acceptance studies toward hydrogen fuel cell vehicles have to be performed [Schulte, 2004]. This research address a need for comprehensive study on factors influencing public acceptance of hydrogen fuel cell car, specifically focusing on impacts of personal experience related to governmental science and technology policy toward public acceptance.

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