• 한국대기환경학회지
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• 제28권4호
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• pp.423-434
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• 2012

This study was carried out to develop for the emission factor of greenhouse gas (GHG) from medium and smallscaled incineration facility using RPF which is considering as a part of renewable energy in UNFCC. The actual concentration of the exhaust gas and the fuel composition of RPF were measured for the calculation of GHG emission factor in RPF incinerators, and were compared with the IPCC guideline. The $CO_2$ and $N_2O$ emission factors by the actual concentration of exhaust gas were $2.3575{\pm}1.0070tCO_2/tRPF$ and $0.0014{\pm}0.0014tN_2O/tRPF$ respectively. Also, $CO_2$ emission factor by the RPF composition was $2.7057{\pm}0.0540tCO_2/tRPF$. The GHG emission factor per energy by the actual concentration was $83.0867{\pm}26.0346tCO_2e/TJ$ which showed higher consistency with the GHG emission factor ($80.3967tCO_2e/TJ$) of waste plastic in the IPCC guideline (2006b). The $CO_2$ and $N_2O$ emission factor calculated in this study is considered as a meaningful data for GHG emission factor of RPF incineration facility because of not being developed in ROK.

• 농촌계획
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• 제19권4호
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• pp.125-135
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• 2013

Analysis and evaluation of uncertainty is adopting the advanced methodology among the methods for greenhouse gas emission assessment that was defined in GPS2000 (Good practice guideline 2000) and GPG-LULUCF (GPG Land Use, Land-Use Change and Forestry). In 2006 IPCC guideline, two approaches are suggested to explain the uncertainty for each section with a national net emission and a prediction value on uncertainty as follows; 1) Spread sheet calculation based on the error propagation algorithm that was simplified with some assumptions, and 2) Monte carlo simulation that can be utilized in general purposes. There are few researches on the agricultural field including greenhouse gas emission that is generated from livestock and cultivation lands due to lack of information for statistic data, emission coefficient, and complicated emission formula. The main objective of this study is to suggest an evaluation method for the uncertainty of greenhouse gas emission in agricultural field by means of intercomparison of the prediction value on uncertainties which were estimated by spread sheet calculation and monte carlo simulation. A statistic analysis for probability density function for uncertainty of emission rate was carried out by targeting livestock intestinal fermentation, excrements treatment, and direct/indirect emission from agricultural lands and rice cultivation. It was suggested to minimize uncertainty by means of extraction of emission coefficient according to each targeting section.

• 한국대기환경학회지
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• 제22권1호
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• pp.107-116
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• 2006

The main purpose of this study is to develop the greenhouse gas emission factor for power plant using bituminous coal. The power plant is a major source of greenhouse gases among the sectors of fossil fuel combustion, thus information of its emission factors is very essential to the establishment of control strategies for the greenhouse gas emissions. These emission factors derived in this study were compared with those of U. S. EPA, AGO and CCL. The $CO_{2}$ concentrations in the flue gas were measured using NDIR analyser and the GC-FID with a methanizer. The amount of carbon (C) and hydrogen (H) in fuel was measured using an elemental analyzer. Calorific values of fuel were also measured using a calorimeter. Caloric value of bituminous coal used in the power plants were 5,957 (as received basis), 6,591 (air-dried basis) and 6,960 kcal/kg (dry basis). Our estimates of carbon emission factors were lower than those of IPCC. The CO2 emission factors for the power plants using bituminous coal were estimated to be 0.791 Mg/MWh (by carbon contents and caloric value of the fuel) and 0.771 Mg/MWh (by $CO_{2}$ concentration of the flue gas). The $CO_{2}$ emission factors estimated in this study were $3.4\sim 5.4\%$ and $4.4\sim 6.7\%$ lower than those of CCL (2003) and U. S. EPA (2002).

• 한국전기전자재료학회논문지
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• 제14권8호
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• pp.634-639
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• 2001

We investigated the etching characteristics of chromium films by using Cl$_2$/O$_2$ gas mixtures with electron cyclotron resonance plasma. In order to examine the chemical etch characteristics of Cr films by using Cl$_2$/O$_2$ gas plasma, we obtained the etch rate with various gas mixing ratios. By X-ray photoelectron spectroscopy, the surface reaction on the chromium films during the etch was examined. From narrow scan analyses of Cr, Cl, and O, it was confirmed that a chromium oxychlorie (CrCl$_{x}$O$_{y}$) layer was formed on the surface by the etch using Cl$_2$/O$_2$ gas mixtures. We observed a new characteristic emission line during the etch of chromium films using Cl$_2$/O$_2$ gas mixtures by an optical emission spectroscopy. It was found that the peak intensity of this emission line had a tendency compatible with the etch rate. The origin of this emission line was discussed in detail. At the same time, the etched profile was also examined by scanning electron microscope.e.e.

• 반도체디스플레이기술학회지
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• 제17권4호
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• pp.97-100
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• 2018

$NF_3$ Plasma etching of silicon was conducted by injecting only $NF_3$ gas into reactive ion etching. $NF_3$ Plasma etching was done in intermediate pressure. Silicon etching by $NF_3$ plasma in reactive ion etching was diagnosed through residual gas analyzer and optical emission spectroscopy. In plasma etching, optical emission spectroscopy is generally used to know what kinds of species in plasma. Also, residual gas analyzer is mainly to know the byproducts of etching process. Through experiments, the results of optical emission spectroscopy during silicon etching by $NF_3$ plasma was analyzed with connecting the results of etch rate of silicon and residual gas analyzer. It was confirmed that $NF_3$ plasma etching of silicon in reactive ion etching accords with the characteristic of reactive ion etching.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.295-300
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• 2003

In Korea, the emission standards for air pollutants will be more tighten from Jan. 2005. Especially, the new emission standards is focused on the nitrogen oxide. From this trend of standards, nitrogen oxide emission is hot issue in energy fields. Also, we have a new environmental problem, the carbon dioxide emission, which are related to the global warming. To solve the environmental problems, we must define the situation of clean-up technologies level in Korea and decide the direction of R&D for flue gas cleaning technologies. Now, this paper discus briefly on the De-NOx R&D activities and the large scale testing facility for flue gas clean-up technologies in Korea Institute of Energy Research. These discussions are contribute to the increasing of the R&D activities for flue gas clean-up technologies in Korea.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.153-156
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• 2008

MILD combustion has been successfully applied to gaseous fuels and few commercial systems are now in operation. Extending MILD combustion applicability to solid fuel of sawdust is the focus of the present work. The MILD combustion furnace at the University of Adelaide in Australia was used in this study. A measurement of $O_2$ and CO emissions have been carried out in parallel with consideration of NOx emission and compared in each modes of conventional natural gas combustion, natural gas MILD combustion, NOx emission in natural gas MILD combustion mode can be reduced to 20% in comparison with conventional combustion. Emission in cases of air carrying sawdust combustion and $CO_2$ carrying sawdust combustion were also compared. Air and $CO_2$ were sued as a carry gas for the sawdust. It was found that MILD conditions are possible for sawdust particles of less than $355{\mu}m$ without additional air pre-heating. It was also found that when using $CO_2$ as the carry gas the flame inside the furnace was not visible anymore and that NOx emission dropped to less than two folds.

• 한국자동차공학회논문집
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• 제11권2호
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• pp.16-21
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• 2003

Natural gas is one of the promising alternative fuels because of the abundant deposits and the cleanness of emission gas. It can be used in conventional gasoline engine without major modification. Natural gas has some advantages than gasoline i.e. the high octane number, good mixing condition because of gas and wide inflamable limit. In the present study, a $1.8{\ell}$ conventional gasoline engine is modified for using the CNG as a fuel instead of gasoline. Performance and emission characteristics are compared between gasoline and CNG with 4 cylinder SI Engine which is controlled by programable ECU. Parameters of experimentation are equivalence ratio, spark timing and fuels. We analyzed the combustion characteristics of the engine using the cylinder pressure i.e. ignition delay, combustion duration and cycle variation. As a result, CNG engine shows lower exhaust emissions but brake torque is slightly reduced compared to gasoline engine. Overall combustion duration is longer than that of gasoline because of lower burning speed.

• 분석과학
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• 제12권4호
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• pp.1051-1056
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• 1999

• 한국자동차공학회논문집
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• 제10권6호
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• pp.11-18
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• 2002

Residual gas fraction in an engine cylinder affects engine performance, efficiency and emission characteristics. With high residual gas fractions, a flame speed and maximum combustion temperature are decreased and these are deeply related with combustion stability especially at idle and NOx emission at relatively high engine load. In this work, the residual gas fraction was calculated by an engine simulation code, which was validated by the experimental data (cylinder pressure and emissions) obtained from 4-cyliner spark ignition engine. A comparison between experimental and computational calculation results was made. The residual gas is generated mostly at low engine speed by the larger pressure difference between the intake and exhaust port. As the valve overlap duration was increased, the amount of residual gas in the cylinder, the amount of HC emission in the exhaust gas and the variation of power output increased.