• Title/Summary/Keyword: Emerald

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Single Crystal Growth of Synthetic Emerald by Reflux Method of Temperature Gradient used Natural Beryl (천연베릴을 이용한 온도구배 환류법에 의한 합성 Emerald 단결정 육성)

  • 최의석;김무경;이종민;안영필;서청교;안찬준
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.519-521
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    • 1996
  • Emerald (3BeO.Al2O3.6SiO2 : Cr3+) single crystals were crystals were grown by reflux method of temperature gradient in the flux solution of Li2O-MoO3-V2O5 system. The composition of flux materials were 3 mole ratio of MoO3-V2O5/Li2O, subtituted 0.2 mole% of K2O, Na2O, Nb2O5 etc to Li2O content, solved 10-15% of beryl to flux quantity and doped 1% of Cr2O3 to emerald amount. Those of mixing were melted at 110$0^{\circ}C$ in Pt containers of the 3 zone furnace of melt-growth-return to circulate continniously, specially it has been grown large emerald single crystal when thermal fluctuation was treated for 2hrs of once time a day at 1050-95$0^{\circ}C$ in growth zone, substitutional solid solution effect of Cr+3 ion for Al+3 to the growth of emerald single crystal was good. Emerald single crystals were c(0001) hexagonal crystal face of preferencial growth direction and m(1010) post side. When it had been durated for 5 months emerald single crystals of the firet size of 0.6mm thickness of seed crystal were grown 32$\times$65mm(c x m) of maximum size and 6.2mm thickness.

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Single crystal growth of synthetic emerald by flux method of Vandadium - Molybdenum - Lithium oxide system (산화 바나디움, 몰리브데늄, 리티움계 융제법에 의한 합성 Emerald 단결정 육성)

  • 최의석;김무경;이종민;안영필;서청교;안찬준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.1
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    • pp.44-55
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    • 1996
  • Emerald (3BeO{\cdot}Al$_{2}$O_{3}{\cdot}6SiO_2 : Cr^{3+}$) single crystals were grown by flux method of $Li_2O-MoO_3 - V_2O_5$ system. The composition of starting materials were 1, 3, 5 mole ratio of $MoO_3 - V_2O_5/$Li_2O$, 20 - 15% of emerald content to flux composition and 1% of $Cr_2O_3$ colordopant to emerald composition. After mixing those were melted at $1100^{\circ}C$ in Pt crucible of electric furnace. Single crystal growth was cooled down slowly rate of $3^{\circ}C$/hr from $1100^{\circ}C$ to $650^{\circ}C$, for the cooling period it was controlled and prevented the nucleation of microcrystallite from variation of each thermal fluctuation range. Specially it has been obtained plenty of large emerald single crystal when thermal fluctuation was treated for cooling period at $1050 ~ 950^{\circ}C$, in 3 mole ratio of $V_2O_5 - MoO_3/Li_2O$ flux. Emerald single crystal growing effect and $Cr_{+3}$ ion of substitutional solid solution effect for $Al_{+3}$ ion was good than mole ratio of 5. Emerald single crystals were c (0001) hexagonal rystal face of preferencial direction and m (1010) post side. Emerald was hexagonal columnar greenish transparent and 2.65 ~ 2.66 of specific gravity.

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Application of FTIR on the Study of Spectroscopic Characteristics on Emerald from Itabira, Brazile (FTIR을 이용한 브라질 Itabira 지역 에메랄드의 분광학적 특성 연구)

  • Lim, Ye-Won;Jang, Yun-Deuk;Kim, Jong-Rang;Kim, Hyeong-Soo;Kim, Jong-Gun;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.355-364
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    • 2008
  • Emerald deposit located on Itabira, Brazil is one of the major one in the world. We applied three different analytical approaches on Itabira emerald samples, (1) perpendicular to the c-axis, (2) parallel to the c-axis, (3) emerald pallet mixed with KBr, using Fourier Transform Infrared (FTIR) spectroscopy, to understand and compare spectroscopic characteristics of three Itabira emerald samples. Occurrence of $5,271\;cm^{-l}$ and $1,638\;cm^{-l}$ absorption peaks within $H_2O$-related range indicates that the samples belong to Type-II emerald. These emerald samples also display strong absorption peak generated from Type-IIa emerald preserving $H_2O-Na-H_2O$ sequence. $CO_2$- and Cl-related absorption peaks observed within specific range except for $H_2O$-related range. These observations and results suggest that FTIR analysis can be used for not on1y classification of emerald types, but also prediction of $Na_2O$ content within the emerald through comparison of relative peak intensity.

Effect of Cell Size and Seedling Raising Stage on Growth of Cuttings form Euonymus fortunei 'Emerald and Gold' Seedlings in a Plug Tray (플러그 트레이를 이용한 황금줄사철(Euonymus fortunei 'Emerald and Gold') 삽목 시 셀 크기 및 육묘기가 생장에 미치는 영향)

  • Park, Jae-Hyeon;Yoon, Yong-Han;Ju, Jin-Hee
    • Journal of Environmental Science International
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    • v.30 no.8
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    • pp.685-691
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    • 2021
  • This study aimed to find a suitable size and a seedling raising stage for growing cuttings of Euonymus fortunei 'Emerald and Gold' using plug trays. The experimental method, involved cutting two nodes from a solitary branch of E. fortunei 'Emerald and Gold', and the use of 32 (143 mL/cell), 50 (70 mL/cell), 105 (18 mL/cell), 200 (13 mL/cell) plug trays. The cuttings were transplanted to trays after they were filled with a universal horticultural medium. To compare the growths, plant heights, the numbers of leaves, longest root lengths, thickness/radius ratios, dry weights, and fresh weights were measured from July to October, and statistical analyses were performed using both the two-way repeated-measures analysis of variance (ANOVA) and Tukey's post-test. The results confirmed that the size of the plug tray and the seedling raising stage had a significant effect on the growth of E. fortunei 'Emerald and Gold.' In addition, the overall growth was high and the change in growth was relatively rapid in districts 50 and 105. Therefore, it can be considered appropriate to use 50 and 105 trays when growing cuttings of E. fortunei 'Emerald and Gold' on plug trays.

Studies on the substitution pigment of Dan-Chung (양록단청 대체안료 개발 연구)

  • Kim, Sa-Dug;Kim, Soon-Kwan;Hong, Jung-Ki;Kang, Da-Il;Lee, Myong-Hee
    • 보존과학연구
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    • s.20
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    • pp.121-137
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    • 1999
  • Among pigment used at work of Dan-Chung, Emerald Green is specific illuminating fluorescent light of green. It is very difficult to change other organic or inorganic pigment. All of the internal high class pigment has rare light. But Emerald Green is superior to fresh color and stability out of industrial chemical products. It forms over 50% of quantity and importance of a pattern painting. Emerald Green prohibited to produce because of its toxicpollutants, so required to changing pigment development. It is characterized to excellent color, convenient work, economical, against-sunlight, against-air pollutant and durability. The result of a test is follows; 1. We are investigated into producing internal natural Emerald Green, import external pigment and industrial synthesis method etc. but unable to buy because of its toxic pollutant. 2. We are made six samples by yellowish and green is hpigment mixing. We tested on against sunlight and air pollutant. The best mixing ratio is follows. Titanium Dioxide R760 : 18g- Chalk, White Wash : 10g- Permanent Yellow : 7g- Cyanine Green : 8g- Chrome Yellow : 3g- Resin(Vehicle) : Acryl Emulsion(Styrene + 2-Ethyl HexylAcrylate + Methyl Meth Acrylate) 8%

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Growth of Synthetic Emerald Single Crystal by Flux Method (Flux법에 의한 합성 에메랄드 단결정 육성)

  • Park, Sun-Min;Lee, Chul-Tae;Kim, Ho-Kun
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.34-42
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    • 1996
  • Growth of synthetic emerald [($(BeO)_3(Al_{2-x}Cr_xO_3)(SiO_2)_6$] single crystals was carried out by flux method. In this study, the starting materials were prepared by stoichiometric mixing of BeO, $Al_2O_3$ and $SiO_2$ as reaching components. The conditions for the growth of synthetic emerald single crystals are as follows : temperature range ; $1150{\sim}900^{\circ}C$, cooling rate ; 2, 4, $10^{\circ}C/hr$, flux ; $Li_2CO_3$, $V_2O_5$, dopant ; $Cr_2O_3$. The sizes of $Cr_2O_3$emerald single crystals depending on 2, 4, $10^{\circ}C/hr$ cooling rates. The obtained emerald single crystal was characterized and the following results were obtained : lattice parameter : a=0.921nm, c=0.917nm, crystal system ; hexagonal, crystal size ; max. $0.80{\times}0.95mm^2(c{\times}m)$, orientation ; (1000), $m(10{\bar{1}}0)$.

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Spectroscopic Characteristics of synthetic and natural emerald by heat treatment (열처리에 따른 합성과 천연 에메랄드의 분광특성분석)

  • Hwoang, Hye-Kyung;Ahn, Yong-Kil;Seo, Jin-Gyo;Park, Jong-Wan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.1
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    • pp.29-36
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    • 2010
  • The spectroscopic characteristics of synthetic and natural emeralds were investigated by UV-Vis and FTIR spectroscopy before and after heat treatment. The Mo and Co for synthetic flux and C1 for synthetic hydrothermal emeralds have been detected by X-ray fluorescence analysis. In the region of UV-Visible, the absorption of emerald from Colombia was generally increased after the heat treatment. The peak which related to C1 component in the $3000-2600cm^{-1}$ was shown in the hydrothermal synthetic emeralds by FTIR spectroscopy. The $2358cm^{-1}$ peak which originates from $CO_2$ was decreased after the heat treatment in the natural emerald. This was corresponded with the changes of gas element after heat treatment.

Korean Native Landscape Woody Plants planted at JC Raulston Arboretum in USA (미국 JC Raulston 식물원에 식재된 한국자생 조경수목)

  • Seo, Byung-Key
    • The Journal of Natural Sciences
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    • v.11 no.1
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    • pp.137-142
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    • 1999
  • JC Raulston Arboretum of the North Carolina State University houses 113 species of Korean native landscape woody plants. Styrax japonicus 'Emerald Pagoda'[formerly 'Sohuksan'] is native to Korea, China, and Japan. 'Emerald pagoda' is a special cultivar found by DR. J.C. Raulston during the United States National Arboretum plant collection expedition of the island of Sohuksan at the Western end of the Korea in 1985. Incredible, thick, glossy, large-leafed form of this beautiful white flowering tree found in Korea in 1985. It was probably the most outstanding ornamental plant to come from the expedition after his trip to Sohuksan and Chindo in the harsh perilous islands of the coast of Korea. He brought this one back in his suitcase. Viburnum awabuki 'Chindo' is and evergreen broadleaf shrub. It is for screening and as fire resistant trees in the southern region of Korea, because of its compact, leathery leaves. 'Chindo' was discovered on the island of Chindo by the U.S. National arboretum plant exploration team including J.C. Raulston during its 1985 Korean trip. Cuttings were taken from this plant, and liners were produced over subsequent years. These liners are now being evaluated for hardiness and fruit production throughout the Southeast of USA.

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Feasibility of Value-added Utilization of Ash Trees Infested with Emerald Ash Borer

  • Kim, Jae-Woo;Matuana, Laurent M.
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.5
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    • pp.79-87
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    • 2006
  • Value-added utilization of the disposed ash trees due to the infestation by Emerald Ash Borer (EAB) was explored by converting them into particleboards (PBs) and wood-plastic composites (WPCs). The experimental result showed that PB panels could be successfully manufactured from the ash wood but compaction ratio need to be higher than 1.3 in order to meet the standard requirements listed by American National Standards Institute (ANSI). Ash wood plastic composites with high density polyethylene (HDPE) and polypropylene (PP) were also prepared with additives by extrusion. Physical and mechanical properties of ash wood plastic composite compared favorably to those made of pine and maple.

Characteristics of Introduced Sweet Peppers (도입(導入) 감미종(甘味種) 고추의 특성(特性))

  • Kim, Byung Soo;Lee, Woo Sung;Park, Hyun Kyu
    • Current Research on Agriculture and Life Sciences
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    • v.7
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    • pp.47-53
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    • 1989
  • Cultivars of bell and other types of pepper introduced from United States of America and from Japan were planted in the Kyungpook National University experiment farm to investigate their characteristics. Such introductions from Japan as 'Oojishi', 'Saitama Wase', 'Beianeiko', and 'Ichiba' were leading in fresh fruit yield, followed by such introductions from America as 'Keystone Resistant Giant # 3' and 'Emerald Giant'. The introductions from Japan were high yielding and with good fruit set but their fruits were smaller than those of introductions from America. Cultivars introduced from America were inferior to those from Japan in yield and vigor but produced large fruits. Fruits of 'Keystone Resistant Giant #3', 'Yolo Wonder' selections, 'Emerald Giant', and 'Mercury' were the largest. among them Other cultivars such as 'Cubanelle', 'Sweet Banana', 'Anaheim' selections, and 'Cherry Sweet' were also included in the experiment, their characteristics were investigated and their usage was discussed.

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