• 제목/요약/키워드: Elementary reaction

검색결과 139건 처리시간 0.027초

DME연료 디젤 엔진에서의 연소특성 해석 (Numerical Studies on Combustion Characteristics of Diesel Engines using DME Fuel)

  • 유용욱;이정원;김용모
    • 한국자동차공학회논문집
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    • 제16권2호
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    • pp.143-149
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    • 2008
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and spray combustion processes in DI diesel engine using DME and n-heptane. In order to realistically simulate the dimethyl ether (DME) spray dynamics and vaporization characteristics in high-pressure and high-temperature environment, the high-pressure vaporization model has been utilized. The interaction between chemistry and turbulence is treated by employing the Representative Interaction Flamelet (RIF) model. The detailed chemistry of 336 elementary steps and 78 chemical species is used for the DME/air reaction. Based on numerical results, the detailed discussion has been made for the distinctly different combustion characteristics of DME diesel engine in term of vaporization, ignition delay, pollutant formation, and heat release rate.

Adsorption Characteristics of Al (III), Ni (II), Sm (III) Ions on Resin with Styrene Hazardous Material in Reinforcement Water Fire Extinguishing Agent

  • Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제6권3호
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    • pp.151-157
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    • 2013
  • The ion exchange resins were synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous material) divinylbenzene (DVB) copolymer with crosslinks of 1%, 6%, and 15% by substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, surface area, and IR-spectrum. The object of this study was to seperate the metal ion absorbed in reinforcement water fire extinguishing agent. As the results of the effects of pH, equilibrium arrival time, and crosslink of synthetic resin on metal ion adsorption for resin adsorbent, the metal ions were showed high adsorption at pH 3 or over and adsorption equilibrium of metal ions was about 2 hours. In addition, adsorption selectivity for the resin in water was the order of Al (III) > Ni (II) > Sm (III) ions, adsorbability of the metal ions was in the crosslinks order of 1%, 6%, and 15%.

Adsorption Characteristics of U ranium (VI) Ion on Cryptand Synthetic Resin Adsorbent

  • Kim, Hae-Jin
    • 통합자연과학논문집
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    • 제10권4호
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    • pp.225-231
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    • 2017
  • Cryptand resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 5%, and 10% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > calcium ($Ca^{2+}$) > neodymium ($Nd^{3+}$) ion, adsorbability of the uranium ion was the crosslink in order of 1%, 2%, 5%, and 10% and it was increased with the lower dielectric constant.

자녀의 부정적 정서에 대한 부모의 반응과 아동의 스트레스 대처행동 간의 관계에서 자기조절능력의 매개효과 (The Relationship between Parental Response to Children's Negative Emotion and Children's Stress-Coping Behavior : The Mediating Effects of Self-Regulation)

  • 김지연;남은영
    • 아동학회지
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    • 제32권5호
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    • pp.13-28
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    • 2011
  • This study explored the relationship between parental reaction to children's negative emotions, child's self-regulation and stress-coping behaviors. This study also examined the mediating effect of a child's self-regulation between parental reactions to children's negative emotions and a child's stress-coping behaviors. The sample included 407 elementary school 5th-6th grades and their parents (comprising 407 couples) in Seoul. The research results are summarized as follows. First, parental reactions to children's negative emotions were significantly related to the child's self-regulation and stress-coping behaviors. Secondly, it was also found that parental reactions to children's negative emotion were both partially and indirectly related to a child's stress-coping behaviors through the child's use of self-regulation.

고압 분무 연소장에서 연료 분무의 자발화 및 연소 과정 해석 (Numerical Modeling for Auto-ignition and Combustion Process of Fuel Sprays in High-Pressure Environment)

  • 유용욱;강성모;김용모
    • 한국분무공학회지
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    • 제5권4호
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    • pp.66-71
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    • 2000
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in the high-pressure engine conditions. The high-pressure vaporization model is developed to realistically simulate the spray dynamics and vaporization characteristics in high-pressure and high-temperature environment. The interaction between chemistry and turbulence is treated by employing the Representative Interactive Flamelet (RIF) Model. The detailed chemistry of 114 elementary steps and 44 chemical species is adopted for the n-heptane/air reaction. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the multiple RIFs are introduced. Numerical results indicate that the RIF approach together with the high-pressure vaporization model successfully predicts the ignition delay time and location as well as the essential features of a spray ignition and combustion processes.

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Phenazine Ring을 가진 界面活性劑의 合成과 그 抗菌性 (제1보) (Synthesis and Antimicrobial Properties of Surfactants Containing Phenazine Ring (Ⅰ))

  • 김종대;박영훈
    • 대한화학회지
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    • 제25권3호
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    • pp.199-205
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    • 1981
  • Aniline과 alcohol류에서 4-aminoalkylbenzene을 合性하여, 이것을 아세틸化, 니트로化, 加水分解하여 3-nitro-4-aminoalkylbenzene을 얻고 아미노기 이탈반응을 통해 3-nitroalkylbenzene을 合成하여 anthranilic acid와 반응시켜 7-alkyl-1-carboxyphenazine 유도체를 合成하였다. 生成物은 元素分析, IR, NMR 스펙트럼으로 確認하였다. 이들 誘導體들의 水溶液에 대한 表面張力을 測定하였고, 아울러 Gram 陽性菌, Gram 陰性菌, 眞性菌에 대한 抗菌性을 調査하였다. 試驗結果 alkyl기가 치환된 phenazine 誘導體의 抗菌性은 alkyl기가 없는 1-carboxyphenazine 보다 强한 것으로 나타났다.

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상세 화학 반응 모델 및 RIF 모델을 이용한 디젤 분무의 자발화 과정 해석 (Numerical Simulation of Auto-ignition Process of Diesel Sprays Using Detailed Chemistry and Representative Flamelet Model)

  • 유용욱;김성구;김용모;손정락
    • 한국분무공학회지
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    • 제5권2호
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    • pp.61-67
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    • 2000
  • The interaction between chemistry and turbulence is treated by employing the Representative Interactive Flamelet (RIF) Model. The detailed chemistry of 114 elementary steps and 44 chemical species is adopted for the n-heptane/air reaction. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the multi-RIF is used. The effect of the number of RIF on ignition delay is discussed in detail. Numerical results indicate that the present RIF approach successfully predicts the ignition delay time as well as the essential features of a spray auto-ignition process.

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대장균의 장내 독소 생성 균주에 관한 연구 (A study on Enterotoxigenic Escherichia coli)

  • 이영남
    • 미생물학회지
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    • 제16권4호
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    • pp.161-169
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    • 1978
  • Escherichiae-like organisms were isolated from rectal specimens of 56 children who were either in preschool age or in elementary school. The isolated strains were subjected to tests to screen enteropathogens producing heat-labile enterotoxin and susceptibility test to various antibiotics by disc diffusion method on agar plates. Production of heat-labile enterotoxin by the strains was assyed in the sensitive and reproducible cultured adrenal tumor cell system. The assay was sterodogenesis of the cell in the presence of heat-labile enterotoxin. Among 56 strains, gave positive reaction in the test of toxin production. This meant that about 10% of the children population objected to the study harbored the toxigenic strain of enteropathogenes. Some of these toxigenic strains were resistant to the antibiotics employed in the test. This study suggested that considerable population in Korea may harbor entertoxigenic E. coli as a part of intestinal normal flora. The toxigenic strains which are resistant to antibiotics may bring issue of public health in the future.

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산소부화된 메탄 예혼합 화염에서 CF4 분해에 대한 연구 (The Investigation of CF4 Decomposition in Methane Premixed Flames on Oxygen Enrichment)

  • 이기용
    • 한국연소학회지
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    • 제22권4호
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    • pp.51-56
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    • 2017
  • The decomposition of tetrafluoromethane has been investigated with the reaction mechanism proposed for freely propagating $CH_4/CF_4/O_2/N_2$ premixed flames on the oxygen enrichment. The factors affecting on the removal efficiency of tetrafluoromethane were analyzed. The increase in flame temperature due to oxygen enrichment has a great influence on the removal efficiency of tetrafluoromethane. At the same oxygen enrichment condition, the removal efficiency in the rich flame is higher than one in the lean flame. The increase of the F/H ratio leads to decrease the flame temperature and the removal efficiency of tetrafluoromethan is decreased at the flame temperature of 2600 K or lower, The elementary reactions that dominate the consumption of tetrafluoromethane are (R1) $CF_4+M=CF_3+F+M$ and (R2) $CF_4+H=CF_3+HF$. (R1) has the greatest effect on the consumption of tetrafluoromethane under the oxygen enhanced flames.

Adsorption and Separation of U (VI), Co (II), and Dy (III) Metal Ions on Crown Synthetic Resin

  • Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제10권1호
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    • pp.43-50
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    • 2017
  • Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.