• 제어로봇시스템학회:학술대회논문집
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• 1987.10a
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• pp.882-885
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• 1987

The path of an industrial manipulator in a crowded workspace generally consists of 8 set of Cartesian straight line path connecting a set of two adjacent points. To achieve the Cartesian straight line path is, however, a nontrivial task and an alternative approach is to place enough intermediate points along a desired path and linearly interpolate between these points in the joint space. A method is developed that determines the subtravelling- and the transition-time such that the total travelling time for this path is minimized subject to the maximum joint velocities and accelerations constraint. The method is based on the application of nonlinear programming technique, i.e., FTM (Flexible Tolerance Method). These results are simulated on a digital computer using a six-joint revolute manipulator to show their applications.

• Journal of KIISE:Computing Practices and Letters
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• v.16 no.8
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• pp.825-836
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• 2010

The advancement of electronic records brought great changes of the records management system. One of the biggest changes is the transition from passive to automatic management system, which manages massive records more efficiently. The integrated Rule-Oriented Data System (iRODS) is a rule-oriented grid system S/W which provides an infrastructure for building massive archive through virtualization. It also allows to define rules for data distribution and back-up. Therefore, iRODS is an ideal tool to build an electronic record management system that manages electronic records automatically. In this paper we describe the issues related to design and implementation of the electronic record management system using iRODS. We also propose a system that serves automatic processing of distribution and back-up of records according to their types by defining iRODS rules. It also provides functions to store and retrieve metadata using iRODS Catalog (iCAT) Database.

• Proceedings of the Korean Society of Surveying, Geodesy, Photogrammetry, and Cartography Conference
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• 2002.04a
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• pp.17-24
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• 2002

Mechanization is the characteristic of the industrial era and computerization is the characteristic of the Information Era. Now we are facing on the transition from Industrial Era to information Era. Established the National Geo-spatial Data Infrastructures is the fundamental base for information society and is one part of the national basic economic development plan. From 1980's China started his successful transition from traditional methods to high-tech based mapping. China has laid out a high accuracy national GPS (global Positioning System) network, and completed the geographic information databases for scale of 1:1million and 1:250,000. Now it is working on the databases for scales of 1:50,000 and 1:10,000, the world highest level. The massive national programmed has been dubbed "Digital China," since it involves massive quantities of digitized geographical information. Simultaneity, GIS technology and the geo-spatial data have been used widely in electronic government affair, environmental protection, disaster control, ITS and etc. The users have realized the benefits more and more widely. Internet is an efficient way to distribute the geo-information, the State Bureau of Surveying and Mapping has give great effort to settle down the rules and standards to establish the clearing house. Some National Geo-standards have issued, and some of them are on the way. The GIS software is another important factor in the GIS industry. Chinese government working-out some good policy to supports the GIS software developer to have their own copyright. This paper is based on the above to introduce the status and development of Geomatics in China. in China.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1199-1203
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• 2010

Second-order rate constants ($k_N$) have been measured spectrophotometrically for Michael-type reactions of 1-(X-substituted phenyl)-2-propyn-1-ones (2a-f) with a series of alicyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The $k_N$ value increases as the incoming amine becomes more basic and the substituent X changes form an electron-donating group (EDG) to an electron-withdrawing group (EWG). The Br${\o}$nsted-type plots are linear with ${\beta}_{nuc}$ = 0.48 - 0.51. The Hammett plots for the reactions of 2a-f exhibit poor correlations but the corresponding Yukawa-Tsuno plots result in much better linear correlations with ${\rho}$ = 1.57 and r = 0.46 for the reactions with piperidine while ${\rho}$ = 1.72 and r = 0.39 for those with morpholine. The amines employed in this study are less reactive in MeCN than in water for reactions with substrates possessing an EDG, although they are ca. 8 pKa units more basic in the aprotic solvent. This indicates that the transition state (TS) is significantly more destabilized than the ground state (GS) in the aprotic solvent. It has been concluded that the reactions proceed through a stepwise mechanism with a partially charged TS, since such TS would be destabilized in the aprotic solvent due to the electronic repulsion between the negative-dipole end of MeCN and the negative charge of the TS. The fact that primary deuterium kinetic effect is absent supports a stepwise mechanism in which proton transfer occurs after the rate-determining step.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.519-523
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• 2012

A kinetic study is reported on nucleophilic displacement reactions of benzyl 2-pyridyl carbonate 6 with alkalimetal ethoxides, EtOM (M = Li, Na, and K), in anhydrous ethanol at $25.0{\pm}0.1^{\circ}C$. The plots of pseudo-firstorder rate constant $k_{obsd}$ vs. [EtOM] curve upward, a typical phenomenon reported previously for alkaline ethanolysis of esters in which alkali-metal ions behave as a Lewis-acid catalyst. The kobsd value for the reaction of 6 with a fixed EtOK concentration decreases rapidly upon addition of 18-crown-6-ether (18C6), a complexing agent for $K^+$ ion up to [18C6]/[EtOK] = 1.0 and then remains constant thereafter, indicating that the catalytic effect exerted by K+ ion disappears in the presence of excess 18C6. The reactivity of EtOM towards 6 increases in the order $EtO^-$ < EtOLi < EtONa < EtOK, which is contrasting to the reactivity order reported for the corresponding reactions of 2-pyridyl benzoate 4, i.e., $EtO^-$ < EtOK < EtONa < EtOLi. Besides, 6 is 1.7 and 3.5 times more reactive than 4 towards dissociated $EtO^-$ and ion-paired EtOK, respectively. The reactivity difference and the contrasting metal-ion selectivity are discussed in terms of electronic effects and transition-state structures.

• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.356-363
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• 1995

The chemical behavior of the transition metal (Nb4+ and Mo4+) complexes with organoligand (dichloro-bis(η-cyclopentadienyl) has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemical method. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pairing energy and bond strength was obtained from the spectra of the complexes. These are found to be delocalization, low-spin state, and strong bonding strength. The magnetic dipolemoment are found to be paramagnetic and diamagnetic complexes. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic media. As a result the redox reaction proceses of Nb-C complex was couple-single reaction with diffusion and reaction current one electron process, and also Mo-C complex was couple-single reaction with reaction current of one electron process.

• JSTS:Journal of Semiconductor Technology and Science
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• v.16 no.5
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• pp.657-663
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• 2016

In this work, a novel silicon (Si) based floating body synaptic transistor (SFST) is studied to mimic the transition from short-term memory to long-term one in the biological system. The structure of the proposed SFST is based on an n-type metal-oxide-semiconductor field-effect transistor (MOSFET) with floating body and charge storage layer which provide the functions of short- and long-term memories, respectively. It has very similar characteristics with those of the biological memory system in the sense that the transition between short- and long-term memories is performed by the repetitive learning. Spike timing-dependent plasticity (STDP) characteristics are closely investigated for the SFST device. It has been found from the simulation results that the connectivity between pre- and post-synaptic neurons has strong dependence on the relative spike timing among electrical signals. In addition, the neuromorphic system having direct connection between the SFST devices and neuron circuits are designed.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.5
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• pp.210-215
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• 2006

Mechanical alloying (MA) by high energy ball mill of pure copper and niobium powders was carried out under the Ar gas atmosphere. The supersaturated solid solution can be produced in the range up to $Cu_xNb_{100-x}$(x=5-30) by MA for 120 hrs, as demonstrated by X-ray diffraction, DSC analysis and the electronic studies through a change in the superconducting transition in the low-temperature specific heat. The $Cu_{30}Nb_{70}$ samples ball-milled for 120 hrs exhibit only a broad exothermic heat release. The total energy, ${\Delta}H_t$ accumulated during MA far the mixture of $Cu_{30}Nb_{70}$ powders increased with milling time and approached the saturation value of 7.5 kJ/mol after 120 h of milling. It can be seen that the free energy difference between the supersaturated solid solution and the mixture of $Cu_{30}Nb_{70}$ powders is estimated to be 7 kJ/mol by Miedema et al. Hence it is thermodynamically possible to assume the formation of a supersaturated solid solution phase in this system.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.17 no.5
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• pp.187-192
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• 2017

We investigated the effects of the CSRR-metamaterial on microstrip comb-line array antennas. Microstrip comb-line array antennas was designed with 12 radiators, gain of 16.09dBi and bandwidth of 0.24GHz in the 24GHz ISM band. The designed antenna had radiation beam perpendicular to the antenna plane, co-polarization gain of 16.09dBi and cross-polarization gain of -10.86dBi. the CSRR-metamaterial increased largely the impedance bandwidth of the antenna from 0.24GHz to 3.6GHz. however as co-polarization gain became 10.08dBi and cross-polarization gain became 14.1dBi, co-polarization was mixed with cross-polarization. And the antenna gain lowered by 1.99dB. On the investigation of the dependence on the split-direction of the CSRR rings, it showed nearly the same characteristics for up-splitted ring used case and down-splitted ring used case. However in the case of arranging up-splitted ring and down-splitted ring in alternation, co-polarization gain decreased to -1.29dBi and cross-polarization gain increased to 13.9dBi, which meant the wave was transited to cross-polarization majority wave.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.361.2-361.2
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• 2014

Transition metal dichalcogenides (MoS2, WS2, WSe2, MoSe2, NbS2, NbSe2, etc.) are layered materials that can exhibit semiconducting, metallic and even superconducting behavior. In the bulk form, the semiconducting phases (MoS2, WS2, WSe2, MoSe2) have an indirect band gap. Recently, these layered systems have attracted a great deal of attention mainly due to their complementary electronic properties when compared to other two-dimensional materials, such as graphene (a semimetal) and boron nitride (an insulator). However, these bulk properties could be significantly modified when the system becomes mono-layered; the indirect band gap becomes direct. Such changes in the band structure when reducing the thickness of a WS2 film have important implications for the development of novel applications, such as valleytronics. In this work, we report for the controlled synthesis of large-area (~cm2) single-, bi-, and few-layer WS2 using a two-step process. WOx thin films were deposited onto a Si/SiO2 substrate, and these films were then sulfurized under vacuum in a second step occurring at high temperatures ($750^{\circ}C$). Furthermore, we have developed an efficient route to transfer these WS2 films onto different substrates, using concentrated HF. WS2 films of different thicknesses have been analyzed by optical microscopy, Raman spectroscopy, and high-resolution transmission electron microscopy.