• 제목/요약/키워드: Electronic conduction

검색결과 575건 처리시간 0.035초

유기 발광 소자에서 정공 주입 버퍼층의 효과 (Effects of Hole-Injection Buffer Layer in Organic Light-Emitting Diodes)

  • 정동희;김상걸;오현석;홍진웅;이준웅;김영식;김태완
    • 한국전기전자재료학회논문지
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    • 제16권9호
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    • pp.816-825
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    • 2003
  • Current-voltage-luminance characteristics of organic light-emitting diodes (OLEDs) were measured in the temperature range of 10 K~300 K. Indium-tin-oxide (ITO) was used as an anode and aluminum as a cathode in the device. Organic of N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) was used for a hole transporting material, and tris (8-hydroxyquinolinato) aluminum (Alq$_3$) for an electron transporting material and emissive material. And copper phthalocyanine (CuPc), poly(3,4-ethylenedi oxythiophene);poly(styrenesulfonate) (PEDOT:PSS), and poly(N-vinylcarbazole) (PVK) were used for hole-injection buffer layers. From tile analysis of electroluminescence (EL) and photoluminesccnce (PL) spectra of the Alq$_3$, the EL spectrum is more greenish then that of PL. And the temperature-dependent current-voltage characteristics were analyzed in the double and multilayer structure of OLEDS. Electrical conduction mechanism was explained in the region of high-electric and low-electric field. Temperature-dependent luminous efficiency and operating voltage were analyzed from the current-voltage- luminance characteristics of the OLEDS.

$HgGa_2S_4$ 단결정의 광학적 특성 (Optical properties of $HgGa_2S_4$ single crystal)

  • 김형곤;김남오;김병철;최영일;김덕태;현승철;방태환;이경섭;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집
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    • pp.47-52
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    • 2004
  • $HgGa_2S_4$ single crystals were grown by the chemical transport reaction method. The $HgGa_2S_4$ single crystal crystallized into a defect chalcopyrite structure $(I\bar{4})$. The lattice constants of the single crystal were found to be a=5.635 ${\AA}$ and c=10.473 ${\AA}$. The direct and indirect optical energy gaps were found to be 2.84 eV and 2.78 eV, respectively. Photoluminescence peaks of $HgGa_2S_4$ single crystal were observed at 2.37 eV, 2.18 eV, and 1.81 eV. In the single crystal, the donor level of 0.25 eV, the acceptor levels of 0.97 eV and 0.41 eV were obtained by TSC, PICTS, and absorption measurements. The photoluminescence peaks were analyzed to relate to the indirect conduction band, the donor level, and the acceptor levels.

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Anisotropy of the Electrical Conductivity of the Fayalite, Fe2SiO4, Investigated by Spin Dimer Analysis

  • Lee, Kee Hag;Lee, Jeeyoung;Dieckmann, Rudiger
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.629-632
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    • 2013
  • Many properties of inorganic compounds are sensitive to changes in the point-defect concentrations. In minerals, such changes are influenced by temperature, pressure, and chemical impurities. Olivines form an important class of minerals and are magnesium-rich solid solutions consisting of the orthosilicates forsterite $Mg_2SiO_4$ and the fayalite $Fe_2SiO_4$. Orthosilicates have an orthorhombic crystal structure and exhibit anisotropic electronic and ionic transport properties. We examined the anisotropy of the electrical conductivity of $Fe_2SiO_4$ under the assumption that the electronic conduction in $Fe_2SiO_4$ occurs via a small polaron hopping mechanism. The anisotropic electrical conductivity is well explained by the electron transfer integrals obtained from the spin dimer analysis based on tight-binding calculations. The latter analysis is expected to provide insight into the anisotropic electrical conductivities of other magnetic insulators of transition metal oxides.

A Novel Circuit for Characteristics Measurement of SiC Transistors

  • Cao, Guoen;Kim, Hee-Jun
    • Journal of Electrical Engineering and Technology
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    • 제9권4호
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    • pp.1332-1342
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    • 2014
  • This paper proposes a novel test circuit for SiC transistors. On-state resistance under practical application conditions is an important characteristic for the device reliability and conduction efficiency of SiC transistors. In order to measure the on-state resistance in practical applications, high voltage is needed, and high current is also necessary to ignite performance for the devices. A soft-switching circuit based on synchronous buck topology is developed in this paper. To provide high-voltage and high-current stresses for the devices without additional spikes and oscillations, a resonant circuit has been introduced. Using the novel circuit technology, soft-switching can be successfully realized for all the switches. Furthermore, in order to achieve accurate measurement of on-state resistance under switching operations, an active clamp circuit is employed. Operation principle and design analysis of the circuit are discussed. The dynamic measurement method is illustrated in detail. Simulation and experiments were carried out to verify the feasibility of the circuit. A special test circuit has been developed and built. Experimental results confirm that the proposed circuit gives a good insight of the devices performance in real applications.

리튬 폴리머전지용 PMMA/PVDF계 고분자 전해질의 이온 전도 특성 (Ion Conduction Properties of PMMA/PVDF based Polymer Electrolyte for Lithium Polymer Battery)

  • 이재안;김종욱;구할본;이헌수;손명모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.347-350
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PMMA/PVDF electrolytes as a function of a mixed ratio were reported for PMMA/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PMMA/PVDF, plasticizer and Li salt. The ion conductivity of PMMA/PVDF electrolytes was 10$\^$-3/S/cm, which may be applicable to a constituent of lithium secondary battery. 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and AC impedance were used for the determination of transference numbers in PMMA/PVDF electrolyte film. The transference number of 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte is 0.55.

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에폭시 복합체의 유전특성에 미치는 산무수물 경화제와 후경화 열처리의 영향 (Effects of acid-anhydride hardener and postcuring heat-treatments on dielectric properties of epoxy composites)

  • 왕종배;이성일;이준웅
    • E2M - 전기 전자와 첨단 소재
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    • 제7권3호
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    • pp.187-199
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    • 1994
  • In order to find an effect of structural changes due to variation of addition ratio of anhydride hardener and postcuring herat-treatments upon electrical properties of epoxy composites, the dielectric properties over a frequency range from 30[Hz] to l[MHz] were investigated in the temperature range of 20-180[.deg. C]. From the dielectric properties, the a peaks related with glass-transition phenomena of epoxy network appeared near 130[.deg. C], the conduction loss in high temperature region above 150[.deg. C] due to thermal dissociation of hardener started off with the low frequency side and the .betha. peak concerned with contribution of movable unreacted terminal epoxy groups and curing agents in the glass states concurred with the high-frequency side below 20[.deg. C]. And an effect of an hydride hardener upon structural changes and of postcuring heat treatments upon structural stability in epoxy composites would be explained through the estimation of the distribution of relaxation times and the activation energy for a .alpha. peak according to the WLF equations.

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버퍼층과 음전극에 따른 유기 발광 소자의 전기적 특성과 발광 효율 (Electrical Properties and Luminous Efficiency in Organic Light-Emitting Diodes Depending on Buffer Layer and Cathodes)

  • 정동회;김상걸;홍진웅;이준웅;김태완
    • 한국전기전자재료학회논문지
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    • 제16권5호
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    • pp.409-417
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    • 2003
  • We have studied electrical properties and luminous efficiency of organic light-emitting diodes(OLEDs) with different buffer layer and cathodes in a temperature range of 10 K and 300 K. Four different device structures were made. The OLEDs are based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) as a hole transport, tris(8-hydroxyquinolinato) aluminum(III) (Alq$_3$) as an electron transport and omissive layer, and poly(3,4-ethylenedioxythiophene) :poly (styrenesulfonate) (PEDOT:PSS ) as a buffer layer. And LiAl was used as a cathode. Among the devices, the ITO/PEDOT:PSS/TPD/Alq$_3$/LiAl structure has a low energy-barrier height for charge injection and show a good luminous efficiency. We have got a highly efficient and low-voltage operating device using the conductive PEDOT:PSS and low work-function LiAl. From current-voltage characteristics with temperature variation, conduction mechanisms are explained SCLC (space charge limited current) and tunneling one. We have also studied energy barrier height and luminous efficiency at various temperature.

고차구조 변화에 따른 저밀도 폴리에틸렌의 공간전하 측정 (Space Charge Measurement of Low Density Polyethylene Film due to Morphological Change)

  • 고시현;김성필;신종렬;이수원;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마
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    • pp.41-45
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    • 2000
  • As LDPE, widely used as a insulating material of power cable, has defects of treeing and space charge accumulation, various methods to improve them have been suggested. It is difficult to understand the mechanism of electrical conduction according to the complexity of molecular structure and the changes of super-structure due to various environmental parameters. Therfore in this paper, four kinds of heat-treated LDPEs(origin, slow cooled, water cooled, quenched in $LN_2$) were used as specimens to help us understand the mechanisms and space charge distributions were investigated at 60[min] just after applying the field of 1[MV/cm] and 10[min] just after short-circuiting, using LIPP method.

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저밀도 폴리에틸렌에 있어서 전압 파형의 두께 의존성 (Film Thickness Dependences of Ac High Field Dissipation Current Waveform for LDPE)

  • 윤주호;최용성;문종대;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.349-350
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    • 2007
  • Polyethylene is widely used as the insulator for power cable. To investigate the conduction mechanism for power cable insulation under ac high field, it is very important to acquire the dissipation current under actual running field. Recently, we have developed the unique system, which make possible to observe the nonlinear dissipation current waveform. In this system, to observe the nonlinear properties with high accuracy, capacitive current component is canceled by using inverse capacitive current signal instead of using the bridge circuit for canceling it. As the results of these estimations, it was found that the dissipation current will depend on not only the instantaneous value of electric field but also the time differential of applied electric field due to taking a balance between applied field and internal field. Furthermore, two large peaks of dissipation current for each half cycle were observed under certain condition. In this paper, to clarify the reason why it shows two peaks for each half cycle, the film thickness dependences of dissipation current waveforms were observed by using the three different thickness LDPE films.

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Hot Wall Epitaxy (HWE) 법에 의한 $CuInSe_2$ 단결정 박막 성장과 점결함 연구 (Study point defect and growth for $CuInSe_2$ single crystal thin film by hot wall epitaxy)

  • 유상하;홍광준
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.152-153
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    • 2007
  • $CuInSe_2$ single crystal thin film was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. After the as-grown $CuInSe_2$ single crystal thin films was annealed in Cu-, Se-, and In-atmospheres, the origin of point defects of $CuInSe_2$ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K. The native defects of $V_{Cu}$, $V_{Se}$, $Cu_{lnt}$, and $Se_{lnt}$ obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the Cu-atmosphere converted $CuInSe_2$ single crystal thin films to an optical n-type. Also, we confirmed that In in $CuInSe_2$/GaAs did not form the native defects because In in $CuInSe_2$ single crystal thin films existed in the form of stable bonds.

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