• 제목/요약/키워드: Electronic conduction

검색결과 575건 처리시간 0.031초

카본 나노튜브의 표면 처리에 의한 수퍼캐패시터 용량 변화 (Capacity Change of Supercapacitor by Surface Treatment of Carbon Nanotubes)

  • 김용태
    • 한국전기전자재료학회논문지
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    • 제22권6호
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    • pp.532-536
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    • 2009
  • In this study, the capacity change of supercapacitor was investigated by surface treatments of carbon nanotubes as electrode materials with various methods, such as ball-milling, $KMnO_4$ and $H_2SO_4/HNO_3$ acid mixture. Surface treatments generated a number of defects on the surface of carbon nanotubes by attacking on $\pi$ bond in graphene layer, at which carboxyl groups were introduced. These hydrophilic groups could enhance the capacity by increasing the wettability of carbon nanotube surfaces. However, a drawback of the surface treatment was the decrease of conductivity by the loss of conduction path in graphene layer due to the defect formation. The surface treatment condition should be therefore optimized between hydrophilicity increase and conductivity decrease.

중합도에 따른 저점도 실리콘유의 유전 특성 (Dielectric Properties of Low Viscosity Silicone Oils with Degree of Polymerization)

  • 조경순
    • 한국전기전자재료학회논문지
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    • 제27권12호
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    • pp.847-851
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    • 2014
  • The characteristics of dielectric constant and $tan{\delta}$ of low viscosity silicone oils with changing degree of polymerization were investigated. The result shows dipole loss mechanism at low temperature range. The dielectric loss in the range of low frequencies are predominantly of ionic nature with temperature increase. The peak of dielectric loss is the detrapping of the electrons which is were trapped in the localized level of the silicone oils at the frequency of 30 kHz. The increase of ionic conduction is attributed to the presence of ionizable oxidation products and their increased dissociation feature. The activation energy ${\Delta}H$ and dipole moment ${\mu}_d$ were increased whit increasing degree of polymerization.

전도중심에 따른 비대칭 이중게이트 MOSFET의 차단전류 분석 (Analysis of Off Current for Conduction Path of Asymmetric Double Gate MOSFET)

  • 정학기;권오신
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2014년도 추계학술대회
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    • pp.759-762
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    • 2014
  • 비대칭 이중게이트(double gate; DG) MOSFET는 단채널 효과를 감소시킬 수 있는 새로운 구조의 트랜지스터이다. 본 연구에서는 비대칭 DGMOSFET의 전도중심에 따른 차단전류를 분석하고자 한다. 전도중심은 채널 내 캐리어의 이동이 발생하는 상단게이트에서의 평균거리로써 상하단 게이트 산화막 두께를 달리 제작할 수 있는 비대칭 DGMOSFET에서 산화막 두께에 따라 변화하는 요소이며 상단 게이트 전압에 따른 차단전류에 영향을 미치고 있다. 전도중심을 구하고 이를 이용하여 상단 게이트 전압에 따른 차단전류를 계산함으로써 전도중심이 차단전류에 미치는 영향을 산화막 두께 및 채널길이 등을 파라미터로 분석할 것이다. 차단전류를 구하기 위하여 포아송방정식으로부터 급수 형태의 해석학적 전위분포를 유도하였다. 결과적으로 전도중심의 위치에 따라 차단전류는 크게 변화하였으며 이에 따라 문턱전압 및 문턱전압이하 스윙이 변화하는 것을 알 수 있었다.

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A Theoretical Study on the Electrode Structure of MOCl (M=Ti, V and Fe) and Their Relationship with Physical Properties

  • 김상호;강준군;황선구;김호징
    • Bulletin of the Korean Chemical Society
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    • 제16권4호
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    • pp.299-304
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    • 1995
  • In order to find out the relationship between electronic structures of metal oxychlorides (MOCl) and their physicochemical properties, we have carried out the tight-binding band electronic structure calculations with Extended Huckel (EH) method for TiOCl, VOCl and FeOCl. The relative contribution of metal atom to DOS at Fermi level increases in the order of Ti, V and Fe, which is parallel to the reactivities of MOCl toward guest species. The M2+ ion plays a crucial role in the electric conductivity of MOCl and its intercalation compounds. Hopping conduction theory is applied to explain the increase of conductivity after intercalation.

$SnO_{2}$ 초미세 입자의 CO 감지 특성 (CO sensing Properties of $SnO_{2}$ fine particles)

  • 박진성;박보석;노효섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.55-61
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    • 2002
  • Ultra-fine particles of $SnO_{2}$ was synthersized by the sol-gel powder processing using tin(II) chloride dihydrate$(SnCl_{2}{\cdot}2H_{2}O)$ and ethanol$(C_{2}H_{5}OH)$ as raw materials. Gel powders can be obtained by drying of sol at $120^{\circ}C$ after aging 72hrs and 168hrs. The amount of $SnO_{2}$ phase was increased with temperature because of the evaporation of volatile components, and the creation of $SnO_{2}$ phase was almost done by the heat treatment at $700^{\circ}C/30min$ The grain sizes after firing are about 20-30nm, and it showed the narrow distribution of grain size. The specimens to measure electrical properties were fabricated by the thick film screen printing technique on the alumina substrates. The conductance of $SnO_{2}$ was increased with temperature up to $380^{\circ}C$ by the typical conduction mechanism of semiconducting ceramics. There was a region of constant conductance between about $200^{\circ}C$ and $380^{\circ}C$ due to the increment of electron concentration with temperature and the annihilation of conduction carriers by the absorption and electron trapped-ionization of oxygen on the surface of $SnO_{2}$, It was finally showed the intrinsic behaviors above $450^{\circ}C$. The sensing properties of response time, recovery, and sensitivity of CO were improved with aging time.

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초고집적반도체의 커패시터용 강유전 박막의 전기적 특성 개선 (Improvement of Electrical Property in Ferroelectric Thin Films for ULSI's Capacitor)

  • 마재평;박삼규
    • 마이크로전자및패키징학회지
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    • 제11권3호
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    • pp.91-97
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    • 2004
  • PZT 박막을 rf-마그네트론 스퍼터링으로 $Pt/Ti/SiO_2/Si$ 기판 위에 형성시켰다. $5\%$ 과잉 PbO 를 포함한 bulk PZT 타겟을 사용하였다. 상온에서 PZT 박막을 얇게 입힌 후 나머지 두께를 $650^{\circ}C$에서 in-situ 방법으로 형성시켰다. 강유전 특성을 갖는 PZT 상은 $650^{\circ}C$에서 형성되었다. 2단계 스퍼터링에 의해 누설전류 특성을 크게 증진시킬 수 있었고, 적절한 두께의 상온층을 포함시킨 경우 $2{\times}10^{-7}A/cm^2$의 매우 작은 누설전류를 나타냈다. 누설전류 기구에 대한 조사 결과, 여러 조건에서 제조된 PZT 박막의 전기전도는 모두 bulk-limit 기구에 의한 것임을 알 수 있었다.

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AI 이온 주입된 p-type 4H-SiC에 형성된 Ni/AI 오믹접촉의 전기 전도 특성 (Conduction Properties of NitAI Ohmic Contacts to AI-implanted p-type 4H-SiC)

  • 주성재;송재열;강인호;방욱;김상철;김남균;이용재
    • 한국전기전자재료학회논문지
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    • 제22권9호
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    • pp.717-723
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    • 2009
  • Ni/Al ('/' denotes deposition sequence) contacts were deposited on Al-implanted 4H-SiC for ohmic contact formation, and the conduction properties were characterized and compared with those of Ni-only contacts. The thicknesses of the Ni and Al thin film were 30 nm and 300 nm, respectively, and the films were sequentially deposited bye-beam evaporation without vacuum breaking. Rapid thermal anneal (RTA) temperature was varied as follows : $840^{\circ}C$, $890^{\circ}C$, and $940^{\circ}C$. The specific contact resistivity of the Ni contact was about $^{\sim}2\;{\pm}\;10^{-2}\;{\Omega}{\cdot}cm^2$, However, with the addition of Al overlayer, the specific contact resistivity decreased to about $^{\sim}2\;{\pm}\;10^{-4}\;{\Omega}{\cdot}cm^2$, almost irrespective of RTA temperature. X-ray diffraction (XRD) analysis of the Ni contact confirmed the existence of various Ni silicide phases, while the results of Ni/Al contact samples revealed that Al-contaning phases such as $Al_3Ni$, $Al_3Ni_2$, $Al_4Ni_3$, and $Ab_{3.21}Si_{0.47}$ were additionally formed as well as the Ni silicide phases. Energy dispersive spectroscopy (EDS) spectrum showed interfacial reaction zone mainly consisting of Al and Si at the contact interface, and it was also shown that considerable amounts of Si and C have diffused toward the surface. This indicates that contact resistance lowering of the Ni/Al contacts is related with the formation of the formation of interfacial reaction zone containing Al and Si. From these results, possible mechanisms of contact resistance lowering by the addition of Al were discussed.

Y2O3가 1 wt% 첨가된 AlN 세라믹의 전기절연성에 미치는 TiO2 첨가의 효과 (The Effects of TiO2 Addition on the Electrical Insulation of AlN Ceramics with 1 wt% Y2O3)

  • 이진욱;이원진;이성민
    • 한국전기전자재료학회논문지
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    • 제29권12호
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    • pp.791-795
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    • 2016
  • The effects of $TiO_2$ addition on the electrical insulation of AlN ceramics with 1 wt% $Y_2O_3$ as a sintering aid have been investigated. Some of $TiO_2$ has reacted with AlN powders and transformed to fine TiN particles during sintering, which was uniformly dispersed along grain boundaries of AlN. At a high electrical field (500 V/mm), the resistivity of AlN ceramics with $TiO_2$ addition of 0.2 wt% increased about 1000 times from $3{\times}10^{10}{\Omega}cm$ to $3.1{\times}10^{13}{\Omega}cm$. Based on the impedance spectroscopy measurement, it was found that $TiO_2$ addition increased dramatically electrical resistivity of AlN grains much more than that of grain boundaries. Thus, $TiO_2$ was believed to dissolve inside AlN grains to suppress ionic conduction of Al vacancies. This suppressed ionic conduction by Ti incorporation into AlN grains seems to contribute to more electrically insulating AlN ceramics.

디지털 제어 기반의 경계점모드 브릿지리스 PFC 컨버터 (Critical Conduction Mode Bridgeless PFC Converter Based on a Digital Control)

  • 김태훈;이우철
    • 전기학회논문지
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    • 제65권12호
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    • pp.2000-2007
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    • 2016
  • Generally, in order to implement the CRM(Critical Conduction Mode), the analog controller is used rather than a digital controller because the control is simple and uses less power. However, according to the semiconductor technology development and various user needs, digital control system based on a DSP is on the rise. Therefore, in this paper, the CRM bridgeless PFC converter based on a digital control is proposed. It is necessary to detect the inductor current when it reaches zero and peak value, for calculating the on time and off time by using the current information. However, in this paper, the on-time and off-time are calculated by using the proposed algorithm without any current information. If the switching-times are calculated through the steady-state analysis of the converter, they do not reflect transient status such as starting-up. Therefore, the calculated frequency is out of range, and the transient current is generated. In order to solve these problems, limitation method of the on-time and off-time is used, and the limitation values are varied according to the voltage reference. In addition, in steady state, depending on the switching frequency, the inductance is varied because of the resonance between the inductor and the parasitic capacitance of the switching elements. In order to solve the problem, inductance are measured depending on the switching frequency. The measured inductance are used to calculate the switching time for preventing the transient current. Simulation and experimental results are presented to verify the proposed method.

초고온초전도 SMES의 절연특성 (The Electrical Insulation Characteristics of HTS SMES)

  • 천현권;최재형;김해종;성기철;김상현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.623-626
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    • 2005
  • Toward the practical applications, on operation of conduction-cooled HTS SMES at temperatures well below 77 K should be investigated, in order to take advantage of a greater critical current density of HTS and considerably reduce the size and weight of the system. Recently, research and development concerning application of the conduction-cooled HTS SMES that is easily movement are actively progressing in Korea. Electrical insulation under cryogenic temperature is a key and an important element in the application of this apparatus. Using multi wrapped copper by polyimide film for HIS SMES, the breakdown characteristics of models for turn-to-turn, that is surface contact model, were investigated under ac and impulse voltage at 77 K. A material that is Polyimide film (Kapton) 0.025 mm thickness is used for multi wrapping of the electrode. Statistical analysis of the results using Weibull distribution to examine the wrapping number effects on breakdown voltage under ac and impulse voltage in $LN_2$ was carried.

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