• Title/Summary/Keyword: Electrode Fabrication Condition

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Effects of electrode fabrication conditions on performance characteristics of phosphoric acid fuel cell (인산형 연료전지 성능 특성에 미치는 전극 제조 조건의 영향)

  • 송락현;김창수;신동렬
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.2
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    • pp.224-229
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    • 1996
  • Performance characteristics of single cell in phosphoric acid fuel cell were studied for various electrode fabrication parameters such as teflon content, electrode structure, thickness of electrocatalyst layer, platinum content and electrode area. The performance of single cell was decided from the measured voltage-current through a load change. The electrode of 40wt.% teflon exhibited high initial performance of single cell, but in the long term operation, the cell performance of 45 wt.% teflon was better. Also the single cell appeared good performance in case of electrodes with duplicate structure, thin electrocatalyst in thickness, more platinum content, and small area. These results of cell performance were discussed as related to the electrolyte flooding, formation of 3 phase boundary area, internal resistance of electrode, and microstructure of electrode.

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Fabrication of Ti/IrO2/Ta2O5 Electrode with High Electrochemical Activity and Long Lifetime (전기화학적 활성과 내구성이 높은 Ti/IrO2/Ta2O5 전극 제조)

  • Kim, Da-eun;Yoo, Jaemin;Lee, Yongho;Pak, Daewon
    • Journal of Korean Society on Water Environment
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    • v.33 no.1
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    • pp.34-39
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    • 2017
  • Under a corrosive environment, electrodes that are applied in the water-treatment system need not only very high electrochemical activity for fast reactions, but also high durability for cost saving. Therefore, the fabrication condition of iridium electrodes was examined to produce a more durable iridium electrode in this study. Tantalum was selected as a binder to enhance the durability of the iridium electrode. Investigation of the weight ratio between the catalyst and the binder to improve electrochemical activity was performed. Also, to compare the effect of the different coating amounts of the catalyst, the results of CV (Cyclic Voltammetry) and EIS (Electrochemical Impedance Spectroscopy) were discussed. Furthermore, an ALT(Accelerated Lifetime Test) was designed and applied to the electrodes to determine the conditions for highly durable electrode fabrication.

A Study on the Characteristics of Electrode Fabrication for Micro Hole-making (미세 구멍가공을 위한 전극성형 가공특성에 관한 연구)

  • Lee, Ju-Kyoung;Lee, Jong-Hang;Park, Cheol-Woo;Cho, Woong-Sick
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.11
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    • pp.1053-1058
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    • 2007
  • Micro-EDM technology (or the manufacture of miniature parts is used to make a micro hole. Two electrode shaping methods, mechanical electrode grinding and WEDG technique, have been studied. In this study, an electrode shaping method by using previously machined hole is introduced in order to obtain an optimal hole-making condition. Key factors such as applied voltage, capacitance, feedrate, and hole-dimension have an influence on the fabricating error of electrode shaping, which are taper ratio of a hole, electrode form accuracy, and electrode surface. Therefore, we try to investigate the optimal fabricating of electrode shaping from various experiments. Results from experiments, it was able to minimize the electrode fabricating error as voltage increases, and also applied feedrate and capacitance decreases.

Electrochemical properties of Pt electrodes fabricated by other methode as counter electrode of DSC (염료감응형 태양전지의 상대전극용 Pt의 제조방법에 따른 전기화학적 특성)

  • Kim, Hyun-Ju;Lee, Dong-Yun;Koo, Bo-Kun;Lee, Won-Jae;Song, Jae-Sung
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2016-2018
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    • 2005
  • Dye-sensitized solar cell (DSC) consist of oxidation semiconduction electrode, electrolyte and counter electrode. Among these, Pt as counter electrode of DSC plays a role in helping redox reaction of iodine ions in electrolyte, also, transferring electrons into electrolyte. In this case, it is expected that characteristics of Pt electrodes strongly depend on fabrication process and its surface condition. In this study, electrochemical behavior of the electro-plated Pt electrode was compared with that of the sputtered Pt electrode, using cyclic-voltammetry and impedance spectroscopy (PARSTATE 2273, by AMETEK). Surface morphology of Pt electrode was investigated by AFM (XE-100, by PSIA). As a result, it was considered that electrochemical properties of sputtered Pt electrode is superior to that of electro-plated Pt electrode.

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Effect of various MEA fabrication methods on the PEMFC durability testing at high and low humidity conditions (MEA 제조 방법에 따른 상대습도 변화가 PEMFC 내구성에 미치는 영향)

  • Kim, Kun-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.86.2-86.2
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    • 2010
  • In order to improve polymer electrolyte membrane fuel cell (PEMFC) durability, the durability of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, is one of the vital issues. Many articles have dealt with catalyst layer degradation of the durability-related factors on MEAs in relation to loss of catalyst surface area caused by agglomeration, dissolution, migration, formation of metal complexes and oxides, and/or instability of the carbon support. Degradation of catalyst layer during long-term operation includes cracking or delamination of the layer which result either from change in the catalyst microstructure or loss of electronic or ionic contact with the active surface, can result in apparent activity loss in the catalyst layer. Membrane degradation of the durability-related factors on MEAs can be caused by mechanical or thermal stress resulting in formation of pinholes and tears and/or by chemical attack of hydrogen peroxide radicals formed during the electrochemical reactions. All of these effects, the mechanical damage of membrane and degradation of catalyst layers are more facilitated by uneven stress or improper MEA fabrication process. In order to improve the PEMFC durability, therefore, it is most important to minimize the uneven stress or improper MEA fabrication process in the course of the fabrication of MEA. We analyzed the effects of the MEA fabrication condition on the PEMFC durability with MEA produced using CCM (catalyst coated membrane) method. This paper also investigated the effects of MEA fabrication condition on the PEMFC durability by adding additional treatment process, hot pressing and pressing, on the MEA produced using CCM method.

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A Study on Optimization of Manufacturing Condition for LiNi1/3Mn1/3Co1/3O2-based Cathode Electrode (LiNi1/3Mn1/3Co1/3O2계 정극활물질을 적용한 전극 제조조건 최적화 연구)

  • Kim Hyun-Soo;Kim Sung-Il;Lee Chang-Woo;Moon Seong-In;Kim Woo-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.139-144
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    • 2006
  • A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

Comparison of Electrode Backing Materials for Polymer Electrolyte Membrane Fuel Cells

  • Sasikumar, G.;Ryu, H.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.183-186
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    • 2003
  • In a PEM fuel cell electrode, backing layer has tremendous impact on electrode performance. The backing layer provides structural support for the porous electrode, distributes the reactants to the other layers and acts as a current collector. It has major influence on the water management in a PEM fuel cell. Selection of suitable backing layer material for the fabrication of electrode is thus very important to achieve high performance. In this paper we have compared the performance of PEM fuel cell electrodes fabricated using carbon paper EC-TPI-060T, carbon cloth EC-CCI-060T, (ElectroChem Inc.USA) and Carbon cloth from Textron, USA (CPW 003 grade). Mass transport problem was observed under non-pressurized condition, at high current densities, in the caie of EC-CC1-060T carbon cloth electrode (at $50^{\circ}C$), due to its higher thickness. The performance of carbon paper electrode was higher than EC-CCI-060T carbon cloth electrode. The performance of Textron carbon cloth was comparable to EC-TPI -060T carbon paper.

GaN Etch Process System using Parallel Plasma Source for Micro LED Chip Fabrication (병렬 플라즈마 소스를 이용한 마이크로 LED 소자 제작용 GaN 식각 공정 시스템 개발)

  • Son, Boseong;Kong, Dae-Young;Lee, Young-Woong;Kim, Huijin;Park, Si-Hyun
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.32-38
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    • 2021
  • We developed an inductively coupled plasma (ICP) etcher for GaN etching using a parallel plasma electrode source with a multifunctional chuck matched to it in order for the low power consumption and low process cost in comparison with the conventional ICP system with a helical-type plasma electrode source. The optimization process condition using it for the micro light-emitting diode (µ-LED) chip fabrication was established, which is an ICP RF power of 300 W, a chuck power of 200 W, a BCl3/Cl2 gas ratio of 3:2. Under this condition, the mesa structure with the etch depth over 1 ㎛ and the etch angle over 75° and also with no etching residue was obtained for the µ-LED chip. The developed ICP showed the improved values on the process pressure, the etch selectivity, the etch depth uniformity, the etch angle profile and the substrate temperature uniformity in comparison with the commercial ICP. The µ-LED chip fabricated using the developed ICP showed the similar or improved characteristics in the L-I-V measurements compared with the one fabricated using the conventional ICP method

Cu Electrode Fabrication by Acid-assisted Laser Processing of Cu Nanoparticles and Application with Transparent·Flexible Electrode (구리 나노 입자에 산-보조 레이저 공정을 적용한 구리 전극 제작 공정 개발 및 투명·유연 전극으로 활용)

  • Jo, Hyeon-Min;Gwon, Jin-Hyeong;Ha, In-Ho;Go, Seung-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.121-121
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    • 2018
  • Copper is a promising electronic material due to low cost and high electrical conductivity. However, the oxidation problem in an ambient condition makes a crucial issue in practical applications. In here, we developed a simple and cost-effective Cu patterning method on a flexible PET film by combining a solution processable Cu nanoparticle patterning and a low temperature post-processing using acetic acid treatment, laser sintering process and acid-assisted laser sintering process. Acid-assisted laser sintering processed Cu electrode showed superior characteristics in electrical, mechanical and chemical stability over other post-processing methods. Finally, the Cu electrode was applied to the flexible electronics applications such as flexible and transparent heaters and touch screen panels.

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