• 제목/요약/키워드: Electrochemical system

검색결과 944건 처리시간 0.021초

하폐수처리에서 질소 제거를 위한 미생물 전기화학 기술의 동향 (Trends of microbial electrochemical technologies for nitrogen removal in wastewater treatment)

  • 채형원;최용훈;김명운;김영진;정석희
    • 상하수도학회지
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    • 제34권5호
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    • pp.345-356
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    • 2020
  • The removal of organic carbon and nutrients (i.e. N and P) from wastewater is essential for the protection of the water environment. Especially, nitrogen compounds cause eutrophication in the water environment, resulting in bad water quality. Conventional nitrogen removal systems require high aeration costs and additional organic carbon. Microbial electrochemical system (MES) is a sustainable environmental system that treats wastewater and produces energy or valuable chemicals by using microbial electrochemical reaction. Innovative and cost-effective nitrogen removal is feasible by using MESs and increasing attention has been given to the MES development. In this review, recent trends of MESs for nitrogen removal and their mechanism were conclusively reviewed and future research outlooks were also introduced.

이온 마이그레이션 발생에 대한 수분온도의 영향 (Effect of Water Temperature on Generation of Ion Migration)

  • 이덕보;김정현;강수근;김상도;장석원;임재훈;유동수
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제5권2호
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    • pp.261-272
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    • 2005
  • In evaluation of electronic reliability on the PCB(Printed Circuit Board), electrochemical migration is one of main test objects. The phenomenon of electrochemical migration occurs In the environment of the high humidity and the high temperature under bias through a continuous aqueous electrolyte. In this paper, the generating mechanism of electrochemical migration is investigated by using water droll acceleration test under various waters. The waters used in the water drop test are city water, distilled water and ionic water. It found that the generated velocity of electrochemical migration depended on the temperature of water and the electrolyte quantity which included in the various waters.

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Electrochemical Characterization of Lithium Polyelectrolyte Based on Ionic Liquid

  • Cha, E.-H.;Lim, S.-A.;Kim, D.-W.;Choi, N.-S.
    • 전기화학회지
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    • 제12권3호
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    • pp.271-275
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    • 2009
  • Five novel lithium polyelectrolyte-ionic liquid systems, using poly (lithium 2-acrylamido-2-methyl propanesulfonate; PAMPSLi) were prepared and their electrochemical properties were measured. The ionic conductivity of the PAMPSLi/1-ethyl-3-methylimidazolium tricyano methanide (emImTCM) system was exhibited high conductivity (1.28 $\times$ $10^{-3}$ $S/cm^{-1}$). The high conductivity and low viscosity of PAMPSLi/emImTCM system is due to the high flexibility of imidazolium cation and dissociation of lithium cation from the polymer chains. The PAMPSLi/N,N-dimethyl-N-propyl-Nbutylammonium tricyanomethanide ($N_{1134}TCM$) and PAMPSLi/N, N-dimethyl-N-propyl-N-butylammonium dicyanamide ($N_{1134}DCA$) systems showed fairly high conductivity (6.3 $\times$ $10^{-4}$ $S/cm^{-1}$, 6.0 $\times$ 10.4 S/cm.1). PAMPSLi/Trihexyl (tetradecyl) phosphonium bis (trifluoromethane sulfonyl) amide ($P_{66614}TFSA$) exhibited low conductivity (2.22 $\times$ $10^{-5}$ $Scm^{-1}$) and thermally stable over 400$^{\circ}C$.

Cu ECMP 공정에서 전해액이 연마거동에 미치는 영향 (The Effect of Electrolytes on Polshing Behavior in Cu ECMP)

  • 권태영;김인권;김태곤;조병권;박진구
    • 한국재료학회지
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    • 제18권6호
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    • pp.334-338
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    • 2008
  • The purpose of this study is to characterize various electrolytes on electrochemical mechanical planarization (ECMP). The ECMP system was modified from conventional CMP system to measure the potentiodynamic curve and removal rate of Cu. The potentiodynamic curves were measured in static and dynamic states in investigated electrolytes using a potentiostat for the evaluation of the polishing behavior on ECMP. KOH (alkaline) and $NaNO_3$ (salt) were selected as electrolytes which have high conductivity. In static and dynamic states, the corrosion potential decreased and the corrosion current increased as a function of the electrolyte concentration. But, the electrochemical reaction was prevented by mechanical polishing effect in the dynamic state. The static etch and removal rate were measured as functions of concentration and applied voltage. When $NaNO_3$ was used, the dissolution was much faster than that of KOH. It was concluded that the removal rate was strongly depended on electrochemical dissolution. The removal rate increased up to 350 nm/min in $NaNO_3$ based electrolyte.

이온 마이그레이션 발생에 대한 수분온도의 영향 (Effect of Water Temperature on Generation of Ion Migration)

  • 이덕보;김정현;강수근;김상도;장석원;임재훈;유동수
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2005년도 학술발표대회 논문집
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    • pp.339-348
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    • 2005
  • In evaluation of electronic reliability on the PCB(Printed Circuit Board),electrochemical migration is one of main test objects. The phenomenon of electrochemical migration occurs In the environment of the high humidity and the high temperature under bias through a continuous aqueous electrolyte. In this paper, the generating mechanism of electrochemical migration is investigated by using water drop acceleration test under various waters. The waters used in the water drop test are city water, distilled water and ionic water. It found that the generated velocity o of electrochemical migration depended on the temperature of water and the electrolyte quantity which included in the various waters.

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Synthesis of Mesostructured Conducting Polymer-Carbon Nanocomposites and Their Electrochemical Performance

  • Choi, Moon-Jung;Lim, Byung-Kwon;Jang, Jyong-Sik
    • Macromolecular Research
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    • 제16권3호
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    • pp.200-203
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    • 2008
  • A conducting polymer layer was introduced into the pore surface of mesoporous carbon via vapor infiltration of a monomer and subsequent chemical oxidative polymerization. The polypyrrole, conducting polymer has attracted considerable attention due to the high electrical conductivity and stability under ambient conditions. The mesoporous carbon-polypyrrole nanocomposite exhibited the retained porous structure, such as mesoporous carbon with a three-dimensionally connected pore system after intercalation of the polypyrrole layer. In addition, the controllable addition of pyrrole monomer can provide the mesoporous carbon-polypyrrole nanocomposites with a tunable amount of polypyrrole and texture property. The polypyrrole layer improved the electrode performance in the electrochemical double layer capacitor. This improved electrochemical performance was attributed to the high surface area, open pore system with three-dimensionally interconnected mesopores, and reversible redox behavior of the conducting polypyrrole. Furthermore, the correlation between the amount of polypyrrole and capacitance was investigated to check the effect of the polypyrrole layer on the electrochemical performance.

리튬이차전지와 슈퍼커패시터로 구성된 하이브리드 셀의 전기화학적 특성 (Electrochemical Characteristics of Hybrid Cell Consisting of Li Secondary Battery and Supercapacitor)

  • 김상길;길보민;황갑진;유철휘
    • 한국수소및신에너지학회논문집
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    • 제30권1호
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    • pp.43-48
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    • 2019
  • This study investigates the electrochemical characteristics of the hybrid cell that combined the advantageous characteristics of Li secondary battery and supercapacitor, high energy density and high power density, respectively. Electrochemical behaviors of the hybrid cell was characterized by charge/discharge, cycle and impedance tests. The hybrid cell using Li secondary battery and supercapacitor had better discharge capacity and cycle performance than that of using Li secondary battery only. Proper design of such a hybrid cell system is expected to result in substantial benefits to the well being of the Li secondary battery. The hybrid cell involving Li secondary battery for high energy density and supercapacitor for high power density may be the possible solution for future energy storage system.

Zn-Sn 합금을 이용한 강구조물의 금속용사공법 방식성능평가 연구 (Corrosion Protection of Steel by Applying a Zn-Sn Metal Spray System)

  • 류화성;정동근;이한승
    • 한국건축시공학회지
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    • 제14권6호
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    • pp.505-513
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    • 2014
  • 본 연구에서는 전기화학적인 시험 및 CASS Test(염수분무시험)을 실시하여 중방식도장 시험체와 용융아연도금 시험체, Zn-Al 시험체와의 비교를 통해 Zn-Sn 금속용사의 방식 성능을 평가하였다. 시험 결과, 전기화학 시험을 통하여 Zn-Sn / Zn-Al 상온금속용사 시스템 공법의 방식원리는 방식전위에 의하여 확보되는 것을 확인하였으며 강구조물의 방식 공법으로서 상온금속용사 공법은 용융아연도금 공법과 중방식 도장공법과 비교하여 매우 우수한 방식성능을 가지고 있는 것이 CASS 시험을 통하여 검증되었다. 특히 Zn-Sn 금속용사와 Zn-Al 금속용사를 비교해본 결과 그 방식성이 현저하게 차이가 있지는 않았으나 Zn-Sn(65:35) 비율의 시험체가 가장 우수하였다. 또한 중방식 도장은 손상된 부분에서 현저하게 녹이 발생하고 도막이 박리되지만, Zn-Sn / Zn-Al 상온금속용사 시스템 공법은 갈바닉 희생방식에 의하여 매우 높은 부식 방지 특성을 가지고 있음을 확인 하였다.

Adaptive On-line State-of-available-power Prediction of Lithium-ion Batteries

  • Fleischer, Christian;Waag, Wladislaw;Bai, Ziou;Sauer, Dirk Uwe
    • Journal of Power Electronics
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    • 제13권4호
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    • pp.516-527
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    • 2013
  • This paper presents a new overall system for state-of-available-power (SoAP) prediction for a lithium-ion battery pack. The essential part of this method is based on an adaptive network architecture which utilizes both fuzzy model (FIS) and artificial neural network (ANN) into the framework of adaptive neuro-fuzzy inference system (ANFIS). While battery aging proceeds, the system is capable of delivering accurate power prediction not only for room temperature, but also at lower temperatures at which power prediction is most challenging. Due to design property of ANN, the network parameters are adapted on-line to the current battery states (state-of-charge (SoC), state-of-health (SoH), temperature). SoC is required as an input parameter to SoAP module and high accuracy is crucial for a reliable on-line adaptation. Therefore, a reasonable way to determine the battery state variables is proposed applying a combination of several partly different algorithms. Among other SoC boundary estimation methods, robust extended Kalman filter (REKF) for recalibration of amp hour counters was implemented. ANFIS then achieves the SoAP estimation by means of time forward voltage prognosis (TFVP) before a power pulse occurs. The trade-off between computational cost of batch-learning and accuracy during on-line adaptation was optimized resulting in a real-time system with TFVP absolute error less than 1%. The verification was performed on a software-in-the-loop test bench setup using a 53 Ah lithium-ion cell.

미세 레이저 가공의 표면코팅 후 전해 에칭 (Laser Micro Machining and Electrochemical Etching After Surface Coating)

  • 김태풍;박민수
    • 한국정밀공학회지
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    • 제30권6호
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    • pp.638-643
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    • 2013
  • Laser beam machining (LBM) is fast, contactless and able to machine various materials. So it is used to cut metal, drill holes, weld or pattern the imprinted surface. However, after LBM, there still leave burrs and recast layers around the machined area. In order to remove these unwanted parts, LBM process often uses electrochemical etching (ECE). But, the total thickness of workpiece is reduced because the etching process removes not only burrs and recast layers, but also the entire surface. In this paper, surface coating was performed using enamel after LBM on metal. The recast layer can be selectively removed without decreasing total thickness. Comparing with LBM process only, the surface quality of enamel coating process was better than that. And edge shape was also maintained after ECE.