• Title/Summary/Keyword: Electrochemical damage

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A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids (LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

Developing Artificial Neurons Using Carbon Nanotubes Smart Composites (탄소나노튜브 스마트 복합소재를 이용한 인공뉴런 개발 연구)

  • Kang, In-Pil;Baek, Woon-Kyung;Choi, Gyeong-Rak;Jung, Joo-Young
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.136-141
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    • 2007
  • This paper introduces an artificial neuron which is a nano composite continuous sensor. The continuous nano sensor is fabricated as a thin and narrow polymer film sensor that is made of carbon nanotubes composites with a PMMA or a silicone matrix. The sensor can be embedded onto a structure like a neuron in a human body and it can detect deteriorations of the structure. The electrochemical impedance and dynamic strain response of the neuron change due to deterioration of the structure where the sensor is located. A network of the long nano sensor can form a structural neural system to provide large area coverage and an assurance of the operational health of a structure without the need for actuators and complex wave propagation analyses that are used with other methods. The artificial neuron is expected to effectively detect damage in large complex structures including composite helicopter blades and composite aircraft and vehicles.

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Corrosion control of drinking water pipes by corrosion inhibitor (부식억제제에 의한 상수도관의 부식제어)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2306-2310
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    • 2010
  • Corrosion is a complex series of oxidation/reduction reactions between at the water-metal surfaces and materials in which the water is stored or transported. With respect to the corrosion potential of drinking water, the primary concerns include the potential presence of toxic metals, such as lead and copper; deterioration and damage to the household plumbing, and aesthetic problems such as stained laundry, and bitter taste. This study was performed to evaluate the effects of corrosion inhibitors on corrosion rates, Fe and Cu release concentration in water distribution pipes. Decrease of corrosion rates were strongly related to phosphate corrosion inhibitors. Considering that typical corrosion processes consists of a series of electrochemical reaction at the metal surface in contact with water, corrosion rates were positively correlated with Fe release.

Electrochemical Characteristics of Zn-mesh Cathodic Protection Systems in Concrete in Natural Seawater at Elevated Temperature

  • Kim, Ki-Joon;Jung, Jin-A;Lee, Woo-Cheol;Jang, Tae-Seub
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.269-274
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    • 2007
  • The corrosion of steel in concrete is significant in marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood so far. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100 cm column specimens with eight of 10 cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both $10^{\circ}C$ and $40^{\circ}C$ in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode.

Study on the Corrosion and Cavitation Erosion Control of Glass Flake Lining for Mild Steel in Marine Environment (해양환경 중에서 Glass Flake 라이닝 강재의 부식과 캐비테이션 침식 방지에 관한 연구)

  • Lim, Uh Joh;Kim, Seong Hoon
    • 유체기계공업학회:학술대회논문집
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    • 2000.12a
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    • pp.359-365
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    • 2000
  • Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of $Cl^-$. Generally, to protect these accidents, mainly applied anti-corrosion paint and epoxy coating. But it was still remained erosion-corrosion damage such as impingement erosion, cavitation erosion, deposit attack. There was needs to develope the new coating materials to protective those corrosion damages. This paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS were investigated electrochemical tests and cavitation erosion test for corrosion behaviour under sea water. The main results obtained are as follows, 1) Surface of epoxy coating appear erosion pin hole but surface of polyester glass flake and vinylester glass flake lining do not appear erosion pin hole after impingement-cavitation erosion test in sea water. 2) Weight loss of polyester glass flake and vinylester glass flake lining do not occur after impingement-cavitation erosion test in sea water. 3) Corrosion current density of polyester glass flake lining less drained than epoxy coating and substrate under corrosion potential.. 4) Corrosion current density of vinylester glass flake lining with three coating less drained than that of polyester glass flake lining with two coating.

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The thermal impedance spectroscopy on Li-ion batteries using heat-pulse response analysis

  • Barsoukov Evgenij;Jang Jee Hwan;Lee Hosull
    • 한국전기화학회:학술대회논문집
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    • 2001.11a
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    • pp.145-161
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    • 2001
  • Novel characterization of thermal properties of a battery has been introduced by defining its frequency-dependent thermal impedance function. Thermal impedance function can be approximated as a thermal impedance spectrum by analyzing experimental temperature transient which is related to the thermal impedance function through Laplace transformation. In order to obtain temperature transient, a process has been devised to generate external heat pulse with heating wire and to measure the response of battery. This process is used to study several commercial Li-ion batteries of cylindrical type. The thermal impedance measurements have been performed using potentionstat/galvanostate controlled digital signal processor, which is more commonly available than flow-meter usually applied for thermal property measurements. Thermal impedance spectra obtained for batteries produced by different manufactures are found to differ considerably. Comparison of spectra at different states of charge indicates independence of thermal impedance on charging state of battery. It is shown that thermal impedance spectrum can be used to obtain simultaneously thermal capacity and thermal conductivity of battery by non-linear complex least-square fit of the spectrum to thermal impedance model. Obtained data is used to simulate a response of the battery to internal heating during discharge. It is found that temperature inside the battery is by one-third larger that on its surface. This observation has to be considered to prevent damage by overheating.

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A Study on the Development of Rotary Ultrasonic Machining Spindle (회전 초음파가공 주축 개발에 관한 연구)

  • Li, Chang-Ping;Kim, Min-Yeop;Park, Jong-Kweon;Ko, Tae-Jo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.4
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    • pp.160-166
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    • 2015
  • Ultrasonic machining (USM) has been considered a new, cutting-edge technology that presents no heating or electrochemical effects, with low surface damage and small residual stresses on brittle workpieces. However, nowadays, many researchers are paying careful attention to the disadvantages of USM, such as low productivity and tool wear. On the other hand, in this study, a high-performance rotary ultrasonic drilling (RUD) spindle is designed and assembled. In this system, the core technology is the design of an ultrasonic vibration horn for the spindle using finite element analysis (FEA). The maximum spindle speed of RUM is 9,600 rpm, and the highest harmonic displacement is $5.4{\mu}m$ noted at the frequency of 40 kHz. Through various drilling experiments on glass workpieces using a CVD diamond-coated drill, the cutting force and cracking of the hole entrance and exit side in the glass have been greatly reduced by this system.

Food Preservation Technology at Subzero Temperatures: A Review

  • Shafel, Tim;Lee, Seung Hyun;Jun, Soojin
    • Journal of Biosystems Engineering
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    • v.40 no.3
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    • pp.261-270
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    • 2015
  • Purpose: Cold storage is the most popular method used to preserve highly perishable foods such as beef and fish. However, at refrigeration temperatures, the shelf life of these foods is limited, and spoilage leads to massive food waste. Moreover, freezing significantly affects the food's properties. Ice crystallization and growth during freezing can cause irreversible textural damage to foods through volumetric expansion, moisture migration induced by osmotic pressure gradients, and concentration of solutes,which can lead to protein denaturation. Methods: Although freezing can preserve perishable foods for months, these disruptive changes decrease the consumer's perception of the food's quality. Therefore, the development and testing of new and improved cold storage technologies is a worthwhile pursuit. Results: The process of maintaining a food product in an unfrozen state below its equilibrium freezing temperature is known as supercooling. As supercooling has been shown to offer a considerable improvement over refrigeration for extending a perishable product's shelf life, implementation of supercooling in households and commercial refrigeration units would help diminish food waste. Conclusions: A commercially viable supercooling unit for all perishable food items is currently being developed and fabricated. Buildup of this technology will provide a meaningful improvement in the cold storage of perishable foods, and will have a significant impact on the refrigeration market as a whole.

Effect of Surface Contaminants Remained on the Blasted Surface on Epoxy Coating Performance and Corrosion Resistance

  • Baek, Kwang Ki;Park, Chung Seo;Kim, Ki Hong;Chung, Mong Kyu;Park, Jin Hwan
    • Corrosion Science and Technology
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    • v.5 no.1
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    • pp.27-32
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    • 2006
  • One of the critical issues in the coating specification is the allowable limit of surface contaminant(s) - such as soluble salt(s), grit dust, and rust - after grit blasting. Yet, there is no universally accepted data supporting the relationship between the long-term coating performance and the amount of various surface contaminants allowed after grit blasting. In this study, it was attempted to prepare epoxy coatings applied on grit-blasted steel substrate dosed with controlled amount of surface contaminants - such as soluble salt(s), grit dust, and rust. Then, coating samples were subjected to 4,200 hours of cyclic test(NORSOK M-501), which were then evaluated in terms of resistance to rust creepage, blistering, chalking, rusting, cracking and adhesion strength. Additional investigations on the possible damage at the paint/steel interface were carried out using an Electrochemical Impedance Spectroscopy(EIS) and observations of under-film-corrosion. Test results suggested that the current industrial specifications were well matched with the allowable degree of rust, whereas the allowable amount of soluble salt and grit dust after grit blasting showed a certain deviation from the specifications currently employed for fabrication of marine vessels and offshore facilities.

An Overview of New Progresses in Understanding Pipeline Corrosion

  • Tan, M. YJ;Varela, F.;Huo, Y.;Gupta, R.;Abreu, D.;Mahdavi, F.;Hinton, B.;Forsyth, M.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.271-280
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    • 2016
  • An approach to achieving the ambitious goal of cost effectively extending the safe operation life of energy pipeline to 100 years is the application of health monitoring and life prediction tools that are able to provide both long-term remnant pipeline life prediction and in-situ pipeline condition monitoring. A critical step is the enhancement of technological capabilities that are required for understanding and quantifying the effects of key factors influencing buried steel pipeline corrosion and environmentally assisted materials degradation, and the development of condition monitoring technologies that are able to provide in-situ monitoring and site-specific warning of pipeline damage. This paper provides an overview of our current research aimed at developing new sensors and electrochemical cells for monitoring, categorising and quantifying the level and nature of external pipeline and coating damages under the combined effects of various inter-related variables and processes such as localised corrosion, coating cracking and disbondment, cathodic shielding, transit loss of cathodic protection.