• Title/Summary/Keyword: Electrochemical Cavitation

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Investigation on electrochemical performance of Al anode material for marine growth prevention system

  • Kim, Seong-Jong;Jang, Seok-Ki;Han, Min-Su;Lee, Seung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.8
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    • pp.968-973
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    • 2014
  • Aluminum anode of marine growth prevention system for ship is installed in seachest or sea water strainer. The Al anode is connected to a control panel that feeds a current to the anode. The dissolved ions produced by the anode are transferred in sea water, spreads through the sea water pipe system and creates a protective film in the pipelines. Thereby, corrosion in pipeline system significantly is reduced. In application on condition as a steel ship, the big accident can be caused by the corrosion. Accordingly, in this research, we evaluated influence of applied current and flow velocity on electrochemical characteristics of Al anode for marine growth prevention system (MGPS). Based on the results of the erosion-cavitation experiments, cavitation rate increased greatly until 120 min. of the experimental time and decreased a little at the point of 180 min. where pit grew and merging occurred but showed a tendency of steadily increasing consumption rates. Based on the results of the Tafel analysis, compared to static states, corrosion current densities show a rapidly increasing tendency when flow occurred.

Investigation on Galvanostatic Method to Protect Cavitation-corrosion Damage for Cu Alloy in Sea Water (해양환경 하에서 동합금의 캐비테이션-부식손상 방지를 위한 방식정전류 기법 연구)

  • Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.45 no.1
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    • pp.25-30
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    • 2012
  • The galvanostatic tests for corrosion protection are conducted at various applied current densities during 93,600 sec, and evaluated in terms of the variations in current density with time and in the potential at the applied current density. In addition, the corrosion damage depth is analyzed with 3D analysis optical microscope after galvanostatic tests. In this study, it was investigated to decide condition of the corrosion protection gavalnostatic method for Cu-Al alloy that has an excellent corrosion resistance. In the galvanostatic test under the cavitation environment, the energy was reflected or cancelled out by the collision with the oxygen gas generated by the oxygen reduction action. The surface observation showed neither the cavitation damage nor the electrochemical damage in the current density over 0.01 $A/cm^2$ in the dynamic state under the cavitation environment.

Evaluation on Potentiostatic Characteristics of Al-4.06Mg-0.74Mn Alloy with Cavitation Environment in Seawater (Al-4.06Mg-0.74Mn 합금의 해수 내 캐비테이션 환경에 따른 정전위 특성 평가)

  • Lee, Seung-Jun;Han, Min-Su;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.45 no.6
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    • pp.272-277
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    • 2012
  • The hull of a fast sailing aluminium ship are generally prone to erosion owing to the impact of seawater. At this time, synergistic effects of the erosion and the corrosion by aggressive ions such as chlorides tend to aggravate the damage. There have been various attempts, including selection of erosion-resistant materials, cathodic protection and addition of corrosion inhibitors, to overcome damage by erosion or corrosion under marine environments. These approaches, however, have limits on identifying the damage mechanism clearly, because they depend on analogical interpretation by correlating two damage behaviors after the individual studies are assessed. In this research, it was devised a hybrid testing apparatus that integrates electrochemical corrosion test and cavitation test, and thus the erosion-corrosion behavior by cavitation was investigated more reliably. As a result, the slightest damage was observed at the potentials between -1.6 V and -1.5 V. This is considered to be due to a reflection or counterbalancing effect caused by collision of the cavitation cavities and the hydrogen gas formed by activation polarization.

Characteristics of surface damage with applied current density and cavitation time variables for 431 stainless steel in seawater (431 스테인리스강의 해수 내 적용 전류밀도 및 캐비테이션 시간 변수에 따른 표면손상 특성)

  • Kim, Seong-Jong;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.883-889
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    • 2014
  • It is generated for cavitation erosion due to the local static boiling by pressure differentials in high speed rotating fluid environment. The cavitation is influenced by various elements such as pressure, velocity, temperature, pH of fluid and medium. In particular, the damage of material is accelerated due to the electrochemical corrosion by $C1^-$ and cavitation erosion due to cavities in seawater. In this paper, hence, it investigated for martensite stainless steel the damage behavior with applied current density and cavitation time in natural seawater solution. Less damage depth at the cavitation condition was observed than static condition as a result of galvanostatic experiment. Furthermore, it was shown that dramatic increase of weightloss, damage rate and damage depth after 3 hour of cavitation test.

Electrochmical Characteristics by Water Cavitation Peening of Cu Alloy (워터캐비테이션피닝된 동합금의 전기화학적 특성평가)

  • Kim, Seong-Jong;Han, Min-Su;Kim, Min-Sung
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.8
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    • pp.1083-1090
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    • 2012
  • Copper alloys are widely used for casting materials including ship's propellers and pump impellers as they provide high corrosion resistance. In addition, the demand for these alloys is increasing with rapid growth of offshore structures and exploitation of various substitute energy sources. However, they require regular maintenance because of erosion and cavitation damages induced by exposure to marine environment at high speed flows for a long period of time. Water cavitation peening have received attention as one of surface modifications for durability improvement of the copper alloys. This is a environment friendly technology without influence of heat and easily applicable to casting materials. In this research, water cavitation peening was employed in distilled water for copper alloy castings as a function of time and evaluation of corrosion resistance was followed in seawater for the modified surface by using electrochemical methods. The result suggests that the water cavitation peening for 2 minutes was found to be the optimal peening parameter in terms of durability and corrosion resistance.

Study on the Characteristics of Cavitation Erosion-Corrosion for Mild Steel ( 1 ) - Damage Behaviour of Vibration Cavitation Erosion-Corrosion - (연강의 캐비테이션 침식-부식 특성에 관한 연구 ( 1 ) - 진동 캐비네이션 침식-부식 손상 거동 -)

  • Lim, Un-Joh;Hwang, Jae-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.4
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    • pp.413-422
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    • 1995
  • Cavitation erosion-corrosion implies damage to materials due to the shock pressure or shock wave that results when bubbles form and collapse at a metal surface within a liquid. If the liquid is corrosive to the material, a condition typically encountered in industry, the component materials may suffer serious damage by a combination of mechanical and electrochemical attack. In this study, the mild steel(SS41) was tested by using the piezoelectric vibrator with 20kHz, 24$\mu$m to cavity generation apparatus. The damage behaviour of vibration cavitation erosion-corrosion and the environment characteristics were investigated in various solutions which are seawater, tap water and distilled water. The main results obtained are as follows; 1) The cavitation erosion-corrosion damage behaviour in the seawater increases to occur at the equal degree on the middle portion and the outside portion of specimen. The distilled water specimen, on other hand, occurs beginning on the outside portion across to the middle portion of specimen. 2) The cavitation erosion-corrosion damage in the tap water of low specific resistance more increases than that in the distilled water of high specific resistance at the initial testing time and more decreases than that in it by the CaCO sub(3) film with testing time. 3) Cavitation erosion-corrosion damage characteristic divides into four regions; incubation region, acceleration region, deceleration region and steady state region.

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Effect of Phase Transformation Behavior of Electroless Nickel Plating Layer on Corrosion and Cavitation-Erosion with Heat Treatment (열처리에 따른 무전해 니켈 도금 층의 상변태 거동이 부식과 캐비테이션 침식에 미치는 영향)

  • Il-Cho Park;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.64-71
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    • 2024
  • The objective of this study was to investigate corrosion and cavitation-erosion characteristics of the electroless nickel plating layer with heat treatment. The crystallization temperature of the electroless nickel plating layer was about 410 ℃. The phase transformation energy was confirmed to be 12.66 J/g. With increasing heat treatment temperature, the amorphous electroless nickel plating layer gradually changed to crystalline Ni and Ni3P. At the same time, the crystal grain size was also increased. Additionally, when heat treatment was performed at a temperature above 400 ℃, NiO phase was observed due to oxidation phenomenon. As a result of the electrochemical polarization experiment, the corrosion resistance of the heat-treated electroless nickel plating layers was superior to that of the as-deposited plating layer. This was because crystal grains became larger and grain boundaries decreased during heat treatment. The cavitation-erosion resistance of heat-treated plating layers tended to be superior to that of as-deposited plating layers due to increased microhardness.