• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.296-302
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• 2024

An ionic conjugated polymer-iron (III) chloride composite was prepared via in-situ quaternization polymerization of 2-ethynylpyridine (2EP) using iron (III) chloride. Various instrumental methods revealed that the chemical structure of the resulting conjugated polymer (P2EP)-iron (III) chloride composite has the conjugated backbone system having the designed pyridinium ferric chloride complexes. The polymerization mechanism was assumed to be that the activated triple bond of 2-ethynylpyridinium salt, formed at the first reaction step, is easily susceptible to the step-wise polymerization, followed by the same propagation step that contains the propagating macroanion and monomeric 2-ethynylpyridinium salts. The electro-optical and electrochemical properties of the P2EP-FeCl₃ composite were studied. In the UV-visible spectra of P2EP-FeCl₃ composite, the absorption maximum values were 480 nm and 533 nm, and the PL maximum value was 598 nm. The cyclic voltammograms of the P2EP-FeCl₃ composite exhibited irreversible electrochemical behavior between the oxidation and reduction peaks. The kinetics of the redox process of composites were found to be very close to a diffusion-controlled process from the plot of the oxidation current density versus the scan rate.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1703-1705
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• 2004

New luminescent material, 6.11-dihydoxy-5.12-naphtacene-dione $Alq_3$ complex($Alq_2$-Ncd), 1.4-dihydoxy-5.8-naphtaquinone $Alq_3$ complex ($Al_2Nq_4$) was synthesized. The $Alq_2-$ Ncd and $Al_2Nq_4$ has big molecular weight and many ${\pi}$-electrons more than widely known $Alq_3$. And extended efforts have been made to obtain high-performance electro luminescent(EL) devices. We used hole transfer layer of powdered TPD to improve hole transfer and characteristics of interface in OLED. This study indicates not only the sterical effect but also some other effects that would be responsible for the change of the emission wavelength. improvement of luminance and etc.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.48 no.3
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• pp.53-59
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• 2011

Charge transfer through DNA oligonucleotides has been investigated for potential applications of DNA into molecular electrooptic switching devices. Electrons were injected using gold electrode probes where DNA oligomers were adsorbed that are separated in medium. The results show that increased adsorption of DNA reduces the ionization current due to the combined effect of charge transfer through DNA and surface-limited charge transport. The probe-based charge injection was extended to examine the capability of extinguishing fluorescence of Cy3 dye molecules attached to DNA. It is expected that the results may be employed to implementing a novel electrooptic switching device based on DNA molecules.

• Journal of the Korean Electrochemical Society
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• v.10 no.3
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• pp.229-232
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• 2007

An amperometric immunosensor for the determination of rabbit IgG is proposed. The immunoassay utilizes a screen-printed carbon electrode on which osmium redox polymer is electrodeposited. This immunoassay detects 0.1 ng/ml of rabbit IgG, which is ${\sim}10^2$ fold higher than the most sensitive enzyme amplified amperometric immunoassay. The assay utilizes a screen-printed carbon electrode which was pre-coated by a co-electrodeposited film of an electron conducting redox hydrogel and a rabbit IgG. The rabbit IgG in the electron conducting film conjugates captures, when present, the anti-rabbit IgG. The captured anti-rabbit-IgG is labeled with horseradish peroxidase (HRP) which catalyzes the two-electron reduction of $H_2O_2$ to water. Because the redox hydrogel electrically connects HRP reaction centers to the electrode, completion of the sandwich converts the film from non-electrocatalytic to electro-catalytic for the reduction of $H_2O_2$ to $H_2O$ when the electrode is poised at 200 mV vs. Ag/AgCl.

• Proceedings of the KIEE Conference
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• 2002.07c
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• pp.1575-1577
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• 2002

In this study, multi layer type OLED(Organic Light Emitting Diode) has been fabricated using $Snq_2$, $Snq_4$, and $Alq_3$ for development of high efficiency, electrical and optical properties of multi layer type OLED investigated. The HTL(Hole Transfer Layer) and EML(Emitting Material Layer) were fabricated by using vacuum evaporation on ITO electrode, and its thickness controlled using thickness monitor. Al was used as a cathode. The electrical and optical properties such as J-V, brightness-V and EL spectrum of OLED device was measured using I.V.L.T system. The result, brightness of $Alq_3$, $Snq_2$ and $Snq_4$ were $3900cd/m^2$, $63cd/m^2$ and $23cd/m^2$ respectively.

• Journal of Hydrogen and New Energy
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• v.28 no.5
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• pp.433-439
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• 2017

The high temperature performance of PEM type electrolyser at $120^{\circ}C$ based on covalently cross-linked sulfonated poly ether ether ketone (SPEEK) composie membrane was investigated. Ion conductivity and other properties of SPEEK membrane were improved by adding heteropoly acid and Ceria. The membrane electrode assemblies were prepared using commercial PtC and nano-sized $IrRuO_2$ catalyst by electro-spraying and decal process. Voltage efficiency of MEA equipped with SPEEK membrane was slightly better than that of $Nafion^{(R)}$ membrane, due to its higher proton conductivity at high temperature. The cell performance of MEA with CL-SPEEK/Cs-TSiA/Ceria is 1.71 V at $1A/cm^2$ and $120^{\circ}C$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.518-521
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• 2002

New luminescent material, 6,11-Dihydroxy-5,12-naphthacenedione$(Alq_2-Ncd)$ was synthesized. And extended efforts have been made to obtain high-performance electro-luminescent(EL) devices, since the first report of organic light-emitting diodes(OLEDs) based on tris-(8-hydroxy-quinoline)aluminum$(Alq_3)$ Current-voltage characteristics, brightness-voltage characteristics, luminous efficiency and quantum efficiency were measured at room temperature. The maximum wavelength of the EL is at around 504nm and the brightness is up to $2702[cd/m^2]$ with the maximum efficiency up to 3.91 [1m/W]. This study indicates not only the sterical effect but also some other effect would be responsible for the change of the emission wavelength.

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2969-2973
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• 2014

A new process to fabricate a composite LSCF-Ag cathode material for SOFCs by electron beam (e-beam) irradiation process has been suggested for operation under intermediate temperature range of $600-700^{\circ}C$. A composite LSCF-Ag cathode with uniformly coated Ag nanoparticles on the surface of the LSCF material was prepared by a facile e-beam irradiation method at room temperature. The morphology of the composite LSCF-Ag material was analyzed using a TEM, FE-SEM, and EDS. The prepared composite LSCF-Ag material can play a significant role in increasing the electro-catalytic activities and reducing the operating temperature of SOFCs. The performance of a tubular single cell prepared using the composite LSCF-Ag cathode, YSZ electrolyte and a Ni/YSZ anode was evaluated at reduced operating temperature of $600-700^{\circ}C$. The micro-structure and chemical composition of the single cell were investigated using a FE-SEM and EDS.

• Macromolecular Research
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• v.16 no.7
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• pp.626-630
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• 2008

Poly(vinyl pyrrolidone) was used successfully to control the size and distribution of silver nanoparticles generated on inorganic silica nanofibers. The inorganic nanofibers were electro spun using sol-gel chemistry of silicates, and the diameter of the prepared nanofibers was unaffected by adding up to 7% of poly(vinyl pyrrolidone). The silver ions, in the form of silver nitrate, were introduced into the silica nanofibers and reduced to metallic silver by ultraviolet irradiation with a subsequent thermal treatment. The size of the generated silver particles was decreased dramatically by adding poly(vinyl pyrrolidone). The size of the silver nanoparticles was 73 nm when no poly(vinyl pyrrolidone) was added but 23 nm with the addition of only 1% of poly(vinyl pyrrolidone). The extent of reduction could be checked by determining the concentration of silver ions leached into water from the silica nanofibers. After thermal treatment of the silica nanofibers, more than 99% of the silver remained in the nanofibers, indicating almost complete reduction of the silver ions to silver metal.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.235-238
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• 2007

There is great interest in the applicability of generated hydrogen peroxide to a variety of industrial processes, usually involving oxidation of organics. Hydrogen peroxide is now employed for the bleaching as well as mechanical and chemical treatment in the pulp and paper industries. It addition, it is considered as an agent to displace the traditional alkaline treatments with chlorine-based chemicals. This paper reports a comparative study of $H_2O_2$ electogeneration on gas-diffusion electrode in divided cell with several $Nafion^{(R)}$ proton-exchange membranes, Russian cation-exchange membrane MK-40 and SPEEK membrane. The influence of different PEMs on electro-chemical cell voltage, current efficiency and energy consumption of hydrogen peroxide generation has been studied.