• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.321-328
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• 2024

The performance of carbon fluoride-based lithium primary batteries (Li/CF_X) is limited due to poor rate capability resulting from the low conductivity of carbon fluoride, which is used as the active material. Therefore, in this study, we applied a carbon coating using pyrolysis fuel oil on carbon fluoride to overcome this limitation and considered its electrochemical performance. An amorphous carbon layer was formed on the surface of the carbon fluoride through carbon coating, and the surface physicochemical properties of the carbon fluoride were meticulously considered based on the heat treatment temperature. The advanced research chemical 1000 heat treated at 450 ℃ (ARC@C450) sample, which was commercial carbon fluoride heat-treated at 450 ℃, showed the largest increase in the concentration of sp² carbon bonds (62%) and the highest formation of semi-ionic C-F bonds. Also, the primary battery using the ARC@C450 sample as a cathode active material exhibited stable discharge capability at the highest rate of 5 C (392 mAh/g), and the R_ct value was reduced by 53% compared to the untreated sample. Therefore, we proposed pyrolysis fuel oil-based carbon coating as a method to overcome the low conductivity of carbon fluoride, and the carbon-coated carbon fluoride showed excellent rate performance, suggesting its potential application in high-power primary batteries.

• Proceedings of the KIEE Conference
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• 2000.07c
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• pp.2038-2040
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• 2000

The main objective of this paper is to design and test a new type of polymer ZnO surge arrester for AC power system of railroad vehicles. Metal oxide surge arrester for most electric power system applications, electric train and subway are now being used extensively to protect overvoltage due to lightning. Surge arresters with porcelain housing must not have explosive breakage of the housing to minimize damage to other equipment when subjected to internal high short circuit current. When breakdown of ZnO elements in a surge arrester occurs due to flashover, fault short current flows through the arrestor and internal pressure of the arrester rises. The pressure rise can usually be limited by fitting a pressure relief diaphragm and transferring the arc from the inside to the outside of the housing. However, there is possibility of porcelain fragmentation caused by the thermal shock, pressure rise. etc. Non-fragmenting of the housing is the most desired way to prevent damage to other equipment. The pressure change which is occurred by flashover become discharge energy. This discharge energy raises to damage arrester housing and arrester housing is dispersed as small fragment. Therefore, the pressure relief design is requested to obstruct housing dispersion. The main research works are focused on the structure design by finite element method, pressure relief of module, and studies of performance of surge arrester for electric railway vehicle.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1774-1777
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• 1996

In this paper, applicability of SI-PD(switching impulse - partial discharge) testing method was put on an attempt as a newly proposed diagnostic method for the underground distribution power cable system in Korea. For this purpose, SI-PD testing equipment was designed, and tests were performed using artificial needle-type defects integrated into the 22.9 kV CN/CV cables in drder to prove its reliability. As a result, arc noises, generated from spark gap, were considerably decreased by use of a pneumatic switch immersed into oil, and artificial needle-type defects were well detected with impulse voltage level under $2U_0$. These results imply that it is likely possible to apply SI-PD measurement method as a the nondistructive test for the 22.9 kV CN/CV cable system in Korea.

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1574-1576
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• 1994

$SF_6$ gas has become an important insulation medium in modern electric power apparatus, because of its high insulation withstand levels and good arc quenching capability. For the application of $SF_6$ gas in GIS the estimation of insulation properties is a fundamental point. Moreover the reduction of withstand levels in case of inhomogeneous fields caused by particles or fixed protrusions is of special interest. It is known that the presence of free conducting particles in GIS can significantly lower the insulating level of $SF_6$ gas at elevated pressure and also it has been recently shown that dielectric strength is greatly reduced by fast transients such as disconnector surges where metallic particles are involved. In this paper, we have disigned the particle test chamber rated 362kV for the purpose of investigating the discharge characteristics in SF6 gas where inhomogenius fields are caused by metallic particles.

• Proceedings of the KIEE Conference
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• 2006.07e
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• pp.19-22
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• 2006

The CMD(Condition Monitoring & Diagnosis) System is used to monitor and analyze the PD(Partial Discharge), Arc, Temperature, Pressure, Gas in Oil and so on for reliability and availability of the substation. Although this system comes into the spotlight as the forecast and management of the failure and fault, there are some problems. For example, the unified standard was not defined, and the effective management of the layed communication network does not performed, limitation of physical space, etc. To resolve above problems, this paper suggests the IEC61850 compatible eCMD system architecture for monitoring and analyzing the CMD factor in substations. The suggested eCMD system consists of CMD-LU(Condition Monitoring & Diagnosis-Local Unit), IED(Intelligent Electronic Device), and engineering centers. The IEC61850 is the international standard that defines communication networks and system in substation.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.111.1-111.1
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• 2012

Interest in flexible transparent conducting films (TCFs) has been growing recently mainly due to the demand for electrodes incorporated in flexible or wearable displays in the future. Indium tin oxide (ITO) thin films, which have been traditionally used as the TCFs, have a serious obstacle in TCFs applications. SWNTs are the most appropriate materials for conductive films for displays due to their excellent high mechanical strength and electrical conductivity. In this work, the fabrication by the spraying process of transparent SWNT films and reduction of its sheet resistance on PET substrates is researched Arc-discharge SWNTs were dispersed in deionized water by adding sodium dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWNT was spray-coated on PET substrate and dried on a hotplate. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then was doped with Au-ionic doping treatment, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. This was confirmed and discussed on the XPS and UPS studies. We show that 87 ${\Omega}/{\Box}$ sheet resistances with 81% transmittance at the wavelength of 550nm. The changes in electrical and optical conductivity of SWNT film before and after Au-ionic doping treatments were discussed. The effect of Au-ion treatment on the electronic structure change of SWNT films was investigated by Raman and XPS.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.412-412
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• 2009

Carbon-based nano materials have a significant effect on various fields such as physics, chemistry and material science. Therefore carbon nano materials have been investigated by many scientists and engineers. Especially, since graphene, 2-dimemsonal carbon nanostructure, was experimentally discovered graphene has been tremendously attracted by both theoretical and experimental groups due to their extraordinary electrical, chemical and mechanical properties. Electrical conductivity of graphene is about ten times to that of silicon-based material and independent of temperature. At the same time silicon-based semiconductors encountered to limitation in size reduction, graphene is a strong candidate substituting for silicon-based semiconductor. But there are many limitations on fabricating large-scale graphene sheets (GS) without any defect and controlling chirality of edges. Many scientists applied micromechanical cleavage method from graphite and a SiC decomposition method to the fabrication of GS. However these methods are on the basic stage and have many drawbacks. Thereupon, our group fabricated GS through Thermo-electrical Pulse Induced Evaporation (TPIE) motivated by arc-discharge and field ion microscopy. This method is based on interaction of electrical pulse evaporation and thermal evaporation and is useful to produce not only graphene but also various carbon-based nanostructures with feeble pulse and at low temperature. On fabricating GS procedure, we could recognize distinguishable conditions (electrical pulse, temperature, etc.) to form a variety of carbon nanostructures. In this presentation, we will show the structural properties of OS by synthesized TPIE. Transmission Electron Microscopy (TEM) and Optical Microscopy (OM) observations were performed to view structural characteristics such as crystallinity. Moreover, we confirmed number of layers of GS by Atomic Force Microscopy (AFM) and Raman spectroscopy. Also, we used a probe station, in order to measure the electrical properties such as sheet resistance, resistivity, mobility of OS. We believe our method (TPIE) is a powerful bottom-up approach to synthesize and modify carbon-based nanostructures.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.434-434
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• 2012

Despite recent efforts for fabricating flexible transparent conducting films (TCFs) with low resistance and high transmittance, several obstacles to meet the requirement of flexible displays still remain. Indium tin oxide (ITO) thin films, which have been traditionally used as the TCFs, have a serious obstacle in TCFs applications. SWNTs are the most appropriate materials for conductive films for displays due to their excellent high mechanical strength and electrical conductivity. Recently, it has been demonstrated that acid treatment is an efficient method for surfactant removal. However, the treatment has been reported to destroy most SWNT. In this work, the fabrication by the spraying process of transparent SWNT films and reduction of its sheet resistance by Au-ionic doping treatment on PET substrates is researched. Arc-discharge SWNTs were dispersed in deionized water by adding sodium dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWNT was spray-coated on PET substrate and dried on a hotplate. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then was doped with Au-ionic doping treatment, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. This was confirmed and discussed on the XPS and UPS studies. We show that 87 ${\Omega}/{\Box}$ sheet resistances with 81% transmittance at the wavelength of 550 nm. The changes in electrical and optical conductivity of SWNT film before and after Au-ionic doping treatments were discussed. The effects of hole transport interface layer using Au-ionic doping SWNT on the performance of organic solar cells were investigated.

• Applied Microscopy
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• v.45 no.4
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• pp.236-241
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• 2015

Carbon-coated Ni, Cu and Sn nanocapsules were investigated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM) and a four-point probe device. All of these nanocapsules were prepared by an arc-discharge method, in which the bulk metals were evaporated under methane ($CH_4$) atmosphere. Three pure metals (Ni, Cu, Sn) were typically diverse in formation of the carbon encapsulated nanoparticles and their different mechanisms were investigated. It was indicated that a thick carbon layers formed on the surface of Ni(C) nanocapsules, whereas a thin shell of carbon with 1~2 layers covered on Cu(C) nanocapsules, and the Sn(C) nanocapsules was, in fact, a longger multi-walled carbon nanotubes partially-filled with metal Sn. As one typical magnetic/dielectric nanocomposite particles, Ni(C) nanocapsules and its counterpart of oxide-coated Ni(O) nanocapsules were compared in the electrically conductive behaviors for further applications as the electromagnetic materials.

• Proceedings of the KOSOMBE Conference
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• v.1998 no.11
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• pp.295-296
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• 1998

With xeroradiography appearance, DR (Digital Radiography) system have been studying for X-ray detection using photoreceptor. Also detection method for receptor charge change have been developing variably. We use photoreceptor material of a-Se(Amorphous Selenium) with high DQE, high SNR(Signal to Noise Ratio) and high transformation efficiency of X-ray signals into electrical signals. After a-Se receptor is uniformly charged by using Arc discharge, X-ray is exposed. Then a-Se receptor produce subtle charge variation and MOSFET detect charge variations. The detected signal pass A/D converter and signal processing by PC. As results, the initial voltage is 8V. It has wide dynamic range needed digital radiography system. In this study, we obtained data with changing kVp(tube potential voltage) and fixed 8mAs(tube current by exposure time) in X-ray system. However MOSFET detector for X-ray signal is not tested X-ray mAs variations. But if MOSFET detector is tested X-ray mAs variation and exactly calibrated multichannel is made and noise-reduction is done, suitable DR system readout method will be done.