• Title/Summary/Keyword: Electric double-layer capacitor

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Evaluation of Electrochemical Stability of Graphite Current Collector for Electric Double Layer Capacitor Based on Acid Electrolyte (산성 전해질 기반의 전기 이중층 커패시터용 흑연 집전체의 전기화학적 안정성 평가)

  • Park, Sijin;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.272-277
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    • 2021
  • Owing to its low cost, easy fabrication process, and good ionic properties, aqueous supercapacitors are under strong consideration as next-generation energy storage devices. However, the limitation of the current collector is its poor electrochemical stability, leading to low energy storage performance. Therefore, a reasonable design of the current collector and the acidic electrolyte is a necessary, as well as interfacial engineering to enhance the electrochemical performance. In the present study, graphite foil, with excellent electrochemical stability and good electrical properties, is suggested as a current collector of aqueous supercapacitors. This strategy results in excellent electrochemical performance, including a high specific capacitance of 215 F g-1 at a current density of 0.1 A g-1, a superior high-rate performance (104 F g-1 at a current density of 20.0 A g-1), and a remarkable cycling stability of 98 % at a current density of 10.0 A g-1 after 9,000 cycles. The superior energy storage performance is mainly ascribed to the improved ionic diffusion ability during cycling.

PEDOT:PSS/Single Wall Carbon Nanotube Composite Nanoparticles as an Additive for Electric-double Layer Capacitor

  • Park, Jong Hyeok;Lee, Sang Young;Kim, Jong Hun;Ahn, Sunho
    • Journal of Electrochemical Science and Technology
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    • v.3 no.3
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    • pp.143-148
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    • 2012
  • The unique effects of highly conductive conducting polymer/SWNT (single walled carbon nanotube) composite nanoparticles in electric double layer capacitors are studied for the enhancement of the adhesive properties, specific capacitance and power characteristics of the electrode. Because the conducting polymer/SWNT composite material, which is believed to act as a polymer binder, an active material for charge storage and a conducting agent, is well distributed on the activated carbon, greatly enhanced adhesion properties, cell capacitance and power characteristics were obtained.

Vehicle Voltage Stabilizing Module Using Supercapacitors (슈퍼캐패시터를 이용한 자동차 전압 안정화 모듈)

  • Park, Sukhee;Jeong, Kyuwon
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.1
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    • pp.124-129
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    • 2015
  • The performance of a passenger vehicle has been greatly improved recently owing to the intensive use of electronic controllers. Many components of a vehicle, including the engine, are controlled by electronic systems installed in the vehicle. Therefore, the electrical power required for such electronics has increased significantly. However, the electrical power generated by the vehicle's alternator, operated by the engine, is limited, and when the vehicle is started, a large instantaneous current is required. The voltage of the vehicle electrical system fluctuates to a very low level, then, it is gradually recovered. This case is very severe and can even cause damage to electronic systems. In this study, a voltage-stabilizing module comprising electric double layer supercapacitors, which could alleviate the voltage variation, was developed and tested.

Electrochemical Characteristics of Highly Porous Carbon Prepared by Chemical Activation Method for EDLC (화학적 활성법으로 제조된 EDLC용 고다공성 탄소전극의 전기화학 특성)

  • Eo, Soo-Mi;Kim, Han-Joo;Oh, Seung-Mo;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2010-2012
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    • 2005
  • Activated carbon was activated with chemical treatment to attain high surface area with porous structure. We have been considered activated carbon is the ideal material for high voltage electric double layer capacitor due to their high specific surface area, good conductivity and chemical stability. In this study we found that increase in electrochemical capacitance due to activated carbon. Also chemically activated carbon and water treatment have resulted larger capacitance and also exhibits better electrochemical behavior, and is about 15% more than in untreated state. The structural change in activated carbon through chemical treatment activation was investigated by using SEM and XRD. In this study, the dependence of the activation behavior with KOH in the micro structure of host materials will be discussed. Furthermore, the relation to the electric double layer capacitance, especially the specific capacitance per unit area, is also discussed.

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A Study on the dynamic voltage restorer using hybrid capacitor (하이브리드 커패시터를 적용한 순간전압강하 보상장치에 관한 연구)

  • Seo, Ansik;Maeng, Jucheol;Yoon, Jungrag
    • Proceedings of the KIPE Conference
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    • 2013.11a
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    • pp.75-76
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    • 2013
  • 최근 산업 및 경제의 급속한 발전으로 컴퓨터를 비롯한 전기 및 전자 장비, 통신기기, 반도체 장비 등 전기적 외란에 민감한 부하 설비의 사용이 급증하면서 전력 품질에 대한 관심이 고조되고 있다. 그 이유는 정밀 부하 장비들이 전압의 순간적 변동에 대하여 민감하여 이 문제로 인하여 파생되는 경제적 피해가 매우 크기 때문에 지속적인 관리가 필요하다. 이러한 문제 중에서 가장 빈번하게 발생하는 순간 전압 강하를 보상하기 위한 장치로 전기 이중 층 커패시터 (EDLC: Electric Double Layer Capacitor)를 에너지 저장장치로 사용한 순간전압강하 보상장치 (DVR: Dynamic Voltage Restorer) 시스템이 개발 되어 적용되고 있다. 본 논문에서는 현재 순간전압강하 보상장치에 사용되는 DVR 시스템에서 주로 사용되는 에너지 저장장치인 EDLC 보다 동일 사이즈 대비 에너지 밀도가 높은 하이브리드 커패시터를 적용하는 연구를 하고자 한다.

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Development of Dynamic Voltage Restorer System Considering Characteristics of EDLC (EDLC의 특성을 고려한 동적전압보상시스템의 개발)

  • Lee, Sang-Cheol;Seo, Il-Dong
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.59 no.3
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    • pp.288-292
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    • 2010
  • Recently, in energy storage system, the EDLC is paid attention as a new environmentally friendly energy storage element. This capacitor has higher energy density than the electrolytic capacitor. Also, this capacitor has a lot of advantage such as no maintenance, longer life cycle and faster charge-discharge time than the battery system. But the EDLC must have a each charge-discharge controller to effectively control, an energy design method circuit to use effectively energy, and several compensation techniques to control a optimal operating. In this respect, this study suggests major parameters to effectively represent the characteristics of EDLC, the measurement methods of those parameters have been investigated with experiments, and the interpretation about the buck/boost DC/DC converter for the operation of EDLC.

Electrochemical Properties of Electric Double Layer Capacitor with PolyanilineComposite (Polyaniline Composite 전극을 사용한 전기 이중층 캐패시터의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.370-373
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    • 1999
  • The purpose of this study is to research and develop PAn composite electrode for EDLC. EDLC cell of PAn composite electrode with 1M LiClO$_4$/PC brings out good capacitor performance below 4.0V. The radius of semicircle of PAn composite electrode adding 15wt% SP270 was absolutely small. The total resistance of EDLC cell mainly depended on internal resistance of the electrode. The discharge capacitance of PAn composite with 15wt% SP270 in 1st and 200th cycles was 42 and 42 F/g at current density of 1mA/cm$^2$. The capacitance of PAn composite with 15wt%. SP270 capacitor was larger than that of PAn capacitor without SP270. The coulombic efficiency of EDLC at discharge process of 1 and 200 cycles were 94 and 100% respectively. PAn composite EDLC with 15wt% SP270 content showed good capacitance and stability with cycling.

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Parameter Measurement Method for Super Capacitor Failure Diagnosis and Application of Voltage Sag Compensation System Using Super Capacitor (수퍼 커패시터의 고장진단을 위한 파라미터의 측정기법과 순시전압강하 보상장치에의 응용사례)

  • Shon, Jin-Geun
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.8 no.6
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    • pp.173-179
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    • 2009
  • Recently, the super capacitor(EDLC) which has drawn attention as a new energy storage element has a lot of advantage such as no maintenance, long lifetime and quick charge/discharge characteristics with large current. The objective of this paper is propose a parameter measurement method to detect the changes in equivalent series resistor (ESR) and the capacitance value of a super capacitor in order to analysis the internal characteristic and worn-out state of a super capacitor. For proposed method, only the capacitor voltage measurement using simple analog switch is required. In addition, experimental results of voltage sag compensation system in order to compensate the input voltage drop during short-term power interruption adopted super capacitor are presented.

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Electrochemical Characteristics of EDLCs with Selectivity Factors for the Organic Electrolyte (유기용매전해질에 따른 전기이중층캐패시터의 전기화학적 특성)

  • Lee, Sun-young;Ju, Jeh-Beak;Sohn, Tae-Won;Cho, Won-Il;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.1-5
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    • 2005
  • Electric double layer capacitors(EDLCS) based on the charge stored at the interface between a hi팀 surface area carbon electrode and an organic electrolyte solution are widely used as a maintenance-free power source for IC memories and microcomputers. The achievement of the excellent performance of the capacitor requires an electrolyte solution which provides high conductivities over a wide temperature range and good electrochemical stabilities to allow the capacitor to be operated at high voltage. The electrochemical capacitor using a carbon material as electrodes and using an organic electrolyte with $1M-LiPF_6$ in PC-GBL-DEC(volume ratio 1:1:2) has specific capacitance of 64F/g.

Electrochemical Properties of Activated Carbon Capacitor Adopting a Proton-conducting Hydrogel Polymer Electrolyte (수소이온전도성 고분자 겔전해질을 적용한 활성탄소계 전기이중층 캐패시터의 전기화학적 특성)

  • Latifatu, Mohammed;Kim, Kwang Man;Kim, Yong Joo;Ko, Jang Myoun
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.292-296
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    • 2012
  • An electric double-layer capacitor (ELDC) of activated carbon electrode is prepared using a proton-conducting hydrogel polymer electrolyte, which is composed of poly(vinyl alcohol), silicotungstic acid, $H_3PO_4$, and deionized water. A solid film by evaporating the hydrogel polymer electrolyte is also prepared for comparison. The hydrogel polymer electrolyte also acts as a separator with the thickness of about $80{\mu}m$ and the room-temperature ionic conductivity of $10^{-2}S\;cm^{-1}$. The EDLC containing the symmetric electrodes of activated carbon shows the specific capacitance of $58F\;g^{-1}$ at $100mV\;s^{-1}$ with a good cycle life, implying that the hydrogel polymer electrolyte is very promising for use in EDLCs.