• Title/Summary/Keyword: Electric Double Layer

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Electrochemical Characteristics of DAAQ/CNFs electrode for Supercapacitor (슈퍼커패시터용 DAAQ/CNFs 전극의 전기화학적 특성)

  • Kim, Hong-Il;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1184-1187
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    • 2003
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M $H_2SO_4$. We established Process Parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured CNFs electrodes using controlled solution chemistry. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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Charging-Discharging Behavior and Performance of AGM Lead Acid Battery/EDLC Module for x-HEV (x-HEV용 AGM 연축전지/EDLC 통합모듈의 성능 및 충방전 거동)

  • Kim, Sung Joon;Seo, Sung Won;An, Sin Young;Kim, Bong-Gu;Son, Jeong Hun;Jung, Yeon Gil
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.84-91
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    • 2021
  • To cope with automobile exhaust gas regulations, ISG and charging control systems are applied to HEV vehicles for the purpose of improving fuel economy. These systems require quick charge-discharge performance of high current. Therefore, a Module of the AGM battery with high energy density and EDLC(Electric Double Layer Capacitor) with high power density are constructed to study the charging and discharging behavior. In CCA, which evaluates the starting performance at -18 ℃ & 30 ℃ with high current, EDLC contributed for about 8 sec at the beginning. At 0 ℃ CA (Charge Acceptance), the initial Charging current of the AGM/EDLC Module, is twice that of the AGM lead acid battery. To play the role of EDLC during high-current rapid charging and discharging, the condition of the AGM lead-acid battery is optimally maintained. As a result of a Standard of Battery Association of Japan (SBA) S0101 test, the service life of the Module of the AGM Lead Acid Battery/EDLC is found to improve by 2 times compared to that of the AGM Lead Acid Battery.

Channel Capacity Analysis of DNA-based Molecular Communication with Length Encoding Mechanism

  • Xie, Jialin;Liu, Qiang;Yang, Kun;Lin, Lin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.8
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    • pp.2923-2943
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    • 2021
  • The double helix structure of DNA makes it diverse, stable and can store information with high density, and these characteristics are consistent with the requirements of molecular communication for transport carriers. In this paper, a specific structure of molecular communication system based on DNA length coding is proposed. Transmitter (Tx) adopts the multi-layer golden foil design to control the release of DNA molecules of different lengths accurately, and receiver (Rx) adopts an effective and sensitive design of nanopore, and the biological information can be converted to the electric signal at Rx. The effect of some key factors, e.g., the length of time slot, transmission distance, the number of releasing molecules, the priori probability, on channel capacity is demonstrated exhaustively. Moreover, we also compare the transmission capacity of DNA-based molecular communication (DNA-MC) system and concentration-based molecular communication (MC) system under the same parameter setting, and the peak value of capacity of DNA-MC system can achieve 0.08 bps, while the capacity of MC system remains 0.025 bps. The simulation results show that DNA-MC system has obvious advantages over MC system in saving molecular resources and improving transmission stability.

Experimental Study on Electrokinetic Streaming Potential in Micropore Channels of Hollw-Fiber Based on General Helmholtz-Smoluchowski's Principle (일반적 Helmholtz-Smoluchowski 원리에 따른 중공사 미세기공 채널에서의 계면동전기 흐름전위에 관한 실험연구)

  • 전명석;조홍일
    • Membrane Journal
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    • v.12 no.1
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    • pp.41-50
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    • 2002
  • The streaming potential generated by the electrokinetic flow within electric double layer of charged microchannel is applied to determine the zeta potential of hollow-fiber membrane pore by using the general Helmholtz-Smoluchowski equation. The streaming potential is know to provide a useful real-time information on the surface property and the interaction between pore and particles in actual situations and physicochemical conditions. The influence of physicochemical parameters upon the filtration with hollow-fibers has been examined with an in-situ and simultaneously monitoring the streaming potential as well as permeate flux. In particular, the present study examined an experimental method to identify the effect of cake layer which can vary according to the axial position of a hollow-fiber and the progress of membrane fouling by measuring the position-dependent streaming potential. As the latex concentration increases, the permeate flux decreased but the streaming potential increased. The growth of cake layer has been mire developed with increasing latex concentration, however, the effect of surface charges of latexes deposited on the membrane surface leads to increase the streaming potential. With increasing ionic concentration of KCI, both the permeate flux and the streaming potential decrease. The increase of ionic concentration provides a compact cake layer due to the shrinkage of Debye length and the decreased streaming potential results from the weakened ionic flows owing to a thin diffusive double layer.

A Study on the dynamic voltage restorer using hybrid capacitor (하이브리드 커패시터를 적용한 순간전압강하 보상장치에 관한 연구)

  • Seo, Ansik;Maeng, Jucheol;Yoon, Jungrag
    • Proceedings of the KIPE Conference
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    • 2013.11a
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    • pp.75-76
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    • 2013
  • 최근 산업 및 경제의 급속한 발전으로 컴퓨터를 비롯한 전기 및 전자 장비, 통신기기, 반도체 장비 등 전기적 외란에 민감한 부하 설비의 사용이 급증하면서 전력 품질에 대한 관심이 고조되고 있다. 그 이유는 정밀 부하 장비들이 전압의 순간적 변동에 대하여 민감하여 이 문제로 인하여 파생되는 경제적 피해가 매우 크기 때문에 지속적인 관리가 필요하다. 이러한 문제 중에서 가장 빈번하게 발생하는 순간 전압 강하를 보상하기 위한 장치로 전기 이중 층 커패시터 (EDLC: Electric Double Layer Capacitor)를 에너지 저장장치로 사용한 순간전압강하 보상장치 (DVR: Dynamic Voltage Restorer) 시스템이 개발 되어 적용되고 있다. 본 논문에서는 현재 순간전압강하 보상장치에 사용되는 DVR 시스템에서 주로 사용되는 에너지 저장장치인 EDLC 보다 동일 사이즈 대비 에너지 밀도가 높은 하이브리드 커패시터를 적용하는 연구를 하고자 한다.

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Stand-alone Wind-Photovoltaic Streetlight system using Electric Double Layer Capacitor (슈퍼캐패시터를 적용한 독립형 태양광-풍력 가로등시스템)

  • Kim, D.S.;Min, B.G.;Park, J.M.;Kim, Y.J.;Cho, G.B.;Back, H.L.;Jeong, B.H.
    • Proceedings of the KIEE Conference
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    • 2008.04c
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    • pp.227-229
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    • 2008
  • 태양광/풍력 복합발전시스템은 친환경적인 에너지원의 대표적인 복합발전시스템이다. 본 논문에서는 독립형 태양광/풍력 발전시스템을 이용한 가로등 시스템을 구성하여 출력특성을 고찰하였다. 풍력에서 발전된 교류전력을 DC로 변환하여 태양광발전에서 출력된 DC 전력과 공통 DC버스로 전달되도록 하였으며, 공통 직류단 병렬운전을 위해 출력전압을 일치시켰다. 또한 슈퍼캐패시터를 적용하여 발전된 전력의 배터리 충전매체로 활용하여 시스템의 안정성을 높이고 충방전 효율을 증가시키고자 하였다.

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Polymeric Gel Electrolytes for Electric Double Layer Capacitors (전기이중층 캐패시터에 관한 폴리머 겔 전해액)

  • Morita, Masayuki;Qiao, Jin-Li
    • Journal of the Korean Electrochemical Society
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    • v.6 no.2
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    • pp.141-144
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    • 2003
  • Proton conducting polymeric gels as the electrolytes of electrochemical capacitors have been prepared by two different methods: 1) swelling a polymethacrylate-based polymer matrix in aqueous solutions of inorganic and organic acids, and 2) polymerizing complexes of anhydrous acids and prepolymers with organic plasticizer. The FT-IR spectra strongly suggest that the carbonyl groups in the polymer matrix interact with protons from the doped acids. High ionic (proton) conductivity in the range of $6\times10^{-4}-4\times10^{-2}\;S\;cm^{-1}$ was obtained at room temperature for the aqueous gels. The non-aqueous polymer complexes showed rather low ionic conductivity, but it was about $10^{-3}\;S\;cm^{-1}\;at\;70^{\circ}C$ for the $H_3PO_4$ doped polymer electrolyte. The mechanisms of ion (proton) conduction in the polymeric systems are discussed.

A novel EDLC application scheme for PMSG type wind power generation system (영구자석형 동기발전기를 갖는 풍력발전시스템을 위한 EDLC의 새로운 응용 방법)

  • Kim, Gyeong-Hun;Park, Min-Won;Yu, In-Keun;Jeon, Jin-Hong;Ahn, Jong-Bo
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1292-1293
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    • 2011
  • Electric double layer capacitor (EDLC) is used to overcome power quality problem caused by output power oscillation of wind turbines. A novel EDLC application for permanent magnet synchronous generator type wind power generation system is proposed in this paper. The structure of the proposed system is cost-effective and efficient. The proposed system including an EDLC is modeled and analyzed by PSCAD/EMTDC. The simulation results show the effectiveness and major features of the proposed system.

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Effect of crystallinity on the electrochemical properties of carbon black electrodes

  • Yoo, Hye-Min;Heo, Gun-Young;Park, Soo-Jin
    • Carbon letters
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    • v.12 no.4
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    • pp.252-255
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    • 2011
  • Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from $650^{\circ}C$ to $1100^{\circ}C$ were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 $F{\cdot}g-1$ for the CB sample treated at $1000^{\circ}C$.

Preparation of mesoporous carbon using ion exchange (이온 교환을 이용한 메조기공 활성탄의 제조)

  • Lee, Jong-Dae;Kang, Chae-Yoen;Kang, Min-Goo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.328-334
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    • 2009
  • Recently, much interest on mesoporous carbon has been shown in their use for both hydrogen and methane storage and as an electrode material for electric double layer capacitors. The mesoporous active carbons by ion exchange were prepared and physical properties such as specific surface area and pore structure of active carbon were investigated using BET. In this study, active carbons with mesopore fraction of $60{\sim}90%$ were obtained. The Fe/Ca-exchanged active carbons showed a greater mesoporosity compared with Fe-exchanged carbons. The mean mesopore size in active carbons using Ca- and Fe-exchange was about $5.5{\sim}6.0nm$ and was approximately 1nm higher than that of the Fe-exchanged active carbon.