• 한국물환경학회지
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• 제32권1호
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• pp.46-51
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• 2016

In this study, we synthesized a combination of graphene oxide (GO) and titanium dioxide (TiO₂) and confirm that GO can be used for CO₂ photoreduction. TiO₂ exhibited highly efficient combination with other conventional electric charges generated by these paration phenomenon for suppression of hole-electron recombination. This improved the efficiency of CO₂ photoreduction. The synthetic form of GO-TiO₂ used in this study was agraphene sheet surrounded by TiO₂ powder. Efficiency and stability were enhanced by combination of GO and TiO₂. In a CO₂ photoreduction experiment, the highest CO conversion rate was 0.652 μmol/g·h in GO10-TiO₂ (2.3-fold that of pure TiO₂) and the highest CH₄ production rate was 0.037 μmol/g·h in GO0.1-TiO₂ (2.4-fold that of pure TiO₂). GO enhances photocatalytic efficiency by functioning as a support and absorbent, and enabling charge separation. With increasing GO concentration, the CH₄ level decreases to~45% due to decreased transfer of electrons. In this study, TiO₂ together with GO yielded a different result than the normal doping effect and selective CO₂ photoreduction.

• 한국재료학회지
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• 제14권10호
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• pp.701-706
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• 2004

Bismuth layered structure ferroelectric thin films, La-substituted $Bi_{4}Ti_{3}O_{12}$ ($Bi_{1-x}La_{x}Ti_{3}O_{12}$, x=0.75, BLT) were prepared on the $Pt(111)/Ti/SiO_2/Si(100)$ substrates by a sol-gel spin coating process. The thin films were annealed in various conditions, i.e., oxygen, nitrogen and vacuum atmospheres for various annealing time. We investigated the annealing condition effects on the grain orientation and ferroelectric properties. The measured XRD patterns revealed that the BLT thin films showed only $Bi_{4}Ti_{3}O_{12}$-type phase with random orientation. $La^{3+}$ ion substitution for $Bi^{3+}$ ion in perovskite layers of $Bi_{4}Ti_{3}O_{12}$ decreased the degree of c-axis orientation and increased the remanent polarization ($2P_{r}$). The remanent polarization ($2P_{r}$) and the coercive field ($2E_{c}$) of the BLT thin film annealed at $650^{\circ}C$ for 5 min in oxygen atmosphere were $87{\mu}C/cm^2$ and 182 kV/cm, respectively, at an applied electric field of 240 kV/cm. For all of the BLT thin films annealed in various conditions, the fatigue resistance was shown. The improvement of ferroelectric properties with La substitution in $Bi_{4}Ti_{3}O_{12}$ could be attributed to the changes in space charge densities and grain orientation in the thin film.

• 전기화학회지
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• 제12권3호
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• pp.287-294
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• 2009

$TiO_2$가 첨가된 탄소복합전극을 제조 Capacitive deionization(CDI)에서의 제염효과에 대하여 고찰하였다. 본 연구에서는 탄소전극과 탄소복합전극을 제조하여 순환전류전압법과 충전-방전 평가를 하였으며 이때의 이온제거율에 대하여 고찰하였다. 순환전류전압법으로 1 mV/s의 전위주사속도에서 측정한 결과 탄소전극은 125 F/g, 탄소복합전극의 축전용량은 243 F/g으로 2배 증가됨을 확인하였다. 탄소복합전극의 $TiO_2$의 함량은 10 wt.%로 고정하였으며 $TiO_2$가 첨가됨에 따라 전기이중층 흡착량이 증가되어 이온제거율이 탄소전극보다 25% 증가되었다.

• 한국환경보건학회지
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• 제17권1호
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• pp.57-66
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• 1991

This study was carried out for 5 years between 1984 and 1986 and 1989 and 1990. This interviewers visited 292 households to evaluate the perception of the residents using .the. Simple Piped Water Supply (SPWS), and examined the pollution source surrounding 42 SPWS facilities and water quality by the chemical and microbiological method. The purpose of this study was to find out problems linked with SPWS and to investigate more efficient way of improvement in rural water supply. The results of the study are surmnarized as follows: 1) Approximately 55% of the sampled population have been served by simple piped water supply. 2) The drinking water was mostly taken from the springs in 16 sites and valley water in 26 sites. 3) Considering the type of distribution of the SPWS, there are 28 natural gravity systems and 14 pumping systems. 4) Out of the 180 SPWS in Chun Sung Area, 74% of the SPWS facilities were used more than ten years. In addition, 40% of residents expressed the need for repairs of old facilities. 5) 48% of the SPWS facilities are neighbored with pollution source. 6) 50% of the maintenance crews were not committed totheir job but instead, the facilities were operated by some residents or community leaders who were personally concerned about quality of the facilities. 7) About 85% of the residents answered that SPWS was convenient and helpful. 8) About 57% of the residents complaind that the amount of daily water supply is not adequate. 9) About 74% of the residents felt that the water quality is high for dringking water and therefore, 52% of the facilities were not properly chlorinated. But in contrast, the biochemical tests indicated that only 28% of the SPWS met the dringking water quality standards. 10) Maintenance cost per a household ranges form 500 to 2, 000Won (1 $ = 700 Won) a month. Most of the cost was to cover the power electric charge. For the effective maintenance and arrangement of the facilities, gorvermental financial support for the maintenance is strongly recommended.

• 대한기계학회논문집A
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• 제26권7호
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• pp.1241-1249
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• 2002

The extent of materials deterioration can be evaluated accurately by mechanical test such as impact test or creep test. But it is almost impossible to extract a large test specimen from in-service components. Thus material degradation evaluation by non-destructive method is earnestly required. In this paper, the material degradation for virgin and several aged materials of a Cr-Mo-V steel, which is an candidated as structural material of the turbine casing components for electric power plant, is nondestructively evaluated by reactivation polarization testing method. And, the results obtained from the test are compared with those in small punch(SP) tests recommended as a semi-nondestructive testing method using miniaturized specimen. In contrast to the aged materials up to 1,000hrs which exhibit the degradation behaviors with increased ${\Delta}[DBTT]_{SP}$, the improvement of mechanical property can be observed on the 2,000hrs and 3,000hrs aged materials. This is because of the softening of material due to the carbide precipitation, the increase of ferritic structures and the recovery of dislocation microstructure by long-time heat treatment. The reactivation rates($I_R/I_{Crit},\;Q_R/Q_{Crit}$) calculated by reactivation current densityt ($I_R$) and charge($Q_R$) in the polarization curves exhibit a good correlation with ${\Delta}[DBTT]_{SP}$ behaviors.

• 대한기계학회논문집B
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• 제31권6호
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• pp.531-538
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• 2007

In this study, an air conditioning system using carbon dioxide as a refrigerant was developed for automotive cabin cooling. Experiments have been carried out to examine the steady state and dynamic characteristics of this system. The system consists of a compressor, a gas cooler, an evaporator, an expansion device, an internal heat exchanger and an accumulator. The compressor is a variable displacement type, driven by the electric motor, and the gas cooler and the evaporator are aluminum extruded heat exchangers of micro channel type. The $CO_2-refrigerant$ charge, the compressor speed, the air inlet temperature of the gas cooler, the air inlet temperature and the air flow rate of the evaporator and the cooling load are varied and the performance of the system is experimentally investigated. As the compressor speed increased, cooling capacity increased, but the coefficient of performance was deteriorated. As the cabin air temperature or the air flow rate to the cabin was set high, both the cooling capacity and the COP increased. In the cool down experiment with 1.0 or 2.0 kW of heat load, the dynamic characteristics of the air-conditioning system were investigated. For a given capacity of compressor, cool down speed was monitored, and the temperature change was acceptable fur low heat load condition.

• Composites Research
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• 제32권6호
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• pp.307-313
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• 2019

Triboelectric nanogenerators (TENGs)는 정전기 기반의 마찰 전기 발전기로써 간단한 구조로 저비용, 대면적으로 손쉽게 활용할 수 있는 기술이다. 본 연구에선 생활 용품을 활용하여 화학적 결합 및 SEM image로써 분석을 하고 C-C/C-H/C-O/C=O bonding에 따라 bonding 조성비에 따라 C-C bonding의 비율이 클수록 음전하, C-H bonding 비율이 클수록 양전하 대전체가 되는 것을 확인하였다. 그러한 특성을 가지고 최적 생활용품을 활용하여 정전 출력 실험을 했을 때 최대 210 V, 14.6 ㎂, 9.83 mW의 출력을 얻었다. 최종적으로, 랩과 마그네틱 노트를 이용해 97개의 Light Emitting Diodes (LEDs)를 점등할 수 있었다.

• Journal of Mechanical Science and Technology
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• 제19권4호
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• pp.1044-1051
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• 2005

The isothermal characteristics of a rectangular parallelepiped sodium heat pipe were inves­tigated for high-temperature applications. The heat pipes was made of stainless steel of which the dimension was $140\;m\;(L)\;{\times}\;95m\;(W)\;{\times}\;46 m\;(H)$ and the thickness of the container was 5 mm. Both inner surfaces of evaporator and condenser were covered with screen meshes to help spread the liquid state working fluid. To provide additional path for the working fluid, a lattice structure covered with screen mesh wick was inserted in the heat pipe. The bottom surface of the heat pipe was heated by an electric heater and the top surface was cooled by circulating coolant. The concern in this study was to enhance the temperature uniformity at the bottom surface of the heat pipe while an uneven heat source up to 900 W was in contact. The temperature distribution over the bottom surface was monitored at more than twenty six locations. It was found that the operating performance of the sodium heat pipe was critically affected by the inner wall temperature of the condenser region where the working fluid may be changed to a solid phase unless the temperature was higher than its melting point. The maximum temperature difference across the bottom surface was observed to be $114^{\circ}C$ for 850 W thermal load and $100^{\circ}C$ coolant inlet temperature. The effects of fill charge ratio, coolant inlet temperature and operating temperature on thermal performance of heat pipe were analyzed and discussed.

• 대한전자공학회논문지SD
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• 제48권7호
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• pp.1-9
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• 2011

멤리스터(Memristor)는 메모리 레지스터의 합성어로 흐른 전하량에 따라 저항이 스스로 변하고 전원이 끊긴 상태에서도 저항 상태가 기억되는 특수한 메모리 소자이다. 본 논문에서는 차세대 메모리소자로 주목받고 있는 멤리스터를 모델링하고 SPICE 시뮬레이션을 위한 behavior모델을 제시한다. 그리고 제안된 모델을 바탕으로 멤리스터 기반의 M_CAM(Memristor MOS content addressable memory)을 설계하였다. 제안된 M_CAM은 기존의 CAM에 비해서 단위 셀 면적과 평균 전력소모가 각각 40%, 96% 감소하였다. 칩은 0.13${\mu}m$ CMOS 공정에서 공급전압이 1.2V를 갖도록 설계되었다.

• 전기전자학회논문지
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• 제18권4호
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• pp.447-455
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• 2014

본 연구에서는 4H-SiC MOSFET의 주요 문제점인 $SiC/SiO_2$ 계면의 특성을 향상시키기 위해 PECVD (plasma enhanced chemical vapor deposition) 공정을 이용하여 n-based 4H-SiC MOS Capacitor를 제작하였다. 건식 산화 공정의 낮은 성장속도, 높은 계면포획 밀도와 $SiO_2$의 낮은 항복전계 등의 문제를 극복하기 위하여 PECVD와 NO어닐링 공정을 사용하여 MOS Capacitor를 제작하였다. 제작이 끝난 후, MOS Capacitor의 계면특성을 hi-lo C-V 측정, I-V 측정 및 SIMS를 이용해 측정하고 평가하였다. 계면의 특성을 건식 산화의 경우와 비교한 결과 20% 감소한 평탄대 전압 변화, 25% 감소한 $SiO_2$ 유효 전하 밀도, 8MV/cm의 증가한 $SiO_2$ 항복전계 및 1.57eV의 유효 에너지 장벽 높이, 전도대 아래로 0.375~0.495eV만큼 떨어져 있는 에너지 영역에서 69.05% 감소한 계면 포획 농도를 확인함으로써 향상된 계면 및 산화막 특성을 얻을 수 있었다.