• Title/Summary/Keyword: Effects of Mo

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Effects of Plasma Nitriding on the Surface Charcteristice Of Stainless Steels (스테인스강의 표면특성에 미치는 플라즈마질화의 영향)

  • 최한철;김관휴
    • Journal of the Korean institute of surface engineering
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    • v.30 no.2
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    • pp.144-154
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    • 1997
  • Effects of plasma nitriding on the surface charcteristice of stainless steel(SS) were investjgated by utilizing wear tester, micro-hardness tester and potentiostat. The surface and corrosion morphology of plasma nitrided SS were analyzed by utilizing optical microscopy, SEM, XRD and WDX. It was found that plasma nitriding at $550^{\circ}C$, compared with $380^{\circ}C$, prodiced a good wear resistance and hardness as nitriding time increased, whereas Mo addition showd that were resistance and hardness decreased. Intergranular corrosion(IGC) resistance improved significantly in the case of plasma nirtrided SS containing 4.05wt% Mo at $380^{\circ}C$ because that nitrogen and Mo ast syner gidically to form a protective layer on surface which is responsible for the aggresive SCN-ion. Plasma nitrided at $550^{\circ}C$ decreased IGC as Mo content increased. Pitting improved in the plasma nitirided SS at Mo content incresased owing to retard a nucleation and growth of chromium carbide or nitirde in grain boundary.

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Effects of Long-term Heat treatment on Mechanical Softening of Mn-Mo-Ni Low-Alloy Steel (Mn-Mo-Ni 저합금강의 기계적 연화에 미치는 장시간 열처리 영향)

  • Kim, Minsuk;Kim, Chungseok
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.6
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    • pp.294-301
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    • 2021
  • In the present study, we investigate the effects of long-term heat treatment at elevated temperatures on the mechanical softening of the Mn-Mo-Ni low-alloy steel. The influence of long-term heat treatment on microstructure and mechanical strength was evaluated. To simulate the long-term material degradation, heat treatment test was interrupted at several stages up to 10,000 hours in an electric furnace. The Mn-Mo-Ni low-alloy steel shows a typical bainitic phase, which consists of a well-developed lath substructure with fine precipitates along the lath boundaries. However, these fine precipitates were redissolved into the matrix with long-term heat treatment, and then the lath substructures were recovered. Consequently, ultimate tensile strength and yield strength decreased during long-term heat treatment showing a mechanical softening phenomenon.

Effects of Fattening Period on Growth Performance, Carcass Characteristics and Lipogenic Gene Expression in Hanwoo Steers

  • Kwon, Eung Gi;Park, Byung Ki;Kim, Hyeong Cheol;Cho, Young Moo;Kim, Tae Il;Chang, Sun Sik;Oh, Young Kyoon;Kim, Nam Kuk;Kim, Jun Ho;Kim, Young Jun;Kim, Eun-Jib;Im, Seok Ki;Choi, Nag-Jin
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.12
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    • pp.1654-1660
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    • 2009
  • This study was conducted to investigate the effects of different fattening periods i.e. 25, 27 and 29 months of age (25 mo, 27 mo and 29 mo), on feed consumption, body weight gain, carcass parameters, and lipogenic gene expression in 45 Korean native steers (Hanwoo). Daily DM intake was higher in steers on 29 mo compared with those on 25 mo or 27 mo. Daily body weight gain was higher in steers on 25 mo compared with those on 27 mo or 29 mo during fattening and overall experimental periods. Therefore, feed conversion ratio was lower in 25 mo compared with 27 mo or 29 mo during the fattening and whole experimental periods. As expected, slaughter and carcass weights were higher in the order of 29 mo>27 mo>25 mo. Carcass yield grade was relatively lower in 29 mo reflecting higher back fat thickness compared with other treatments, while carcass quality grade was not largely influenced by the treatments. By investigation with an ultra-sound scanning technique, the marbling score was significantly and numerically higher in 25 mo compared with 27 mo or 29 mo. The mRNA levels of stearoyl-CoA desaturase (SCD) gene were gradually increased in the late fattening stages (p<0.01) and mRNA of acetyl-CoA carboxylase (ACC), ATP citrate lyase (ACL) and glucose transporter 4 (GLUT4) gene were highly expressed in 29 mo compared with 25 mo and 27 mo (p<0.05). However, gene expressions of adipocyte fatty acid binding protein 4 (FABP4) and lipoprotein lipase (LPL) were not significantly different among the treatments. Thus the present results indicated that different fattening period has no major effect on carcass characteristics, although 25 mo had a lower carcass weight compared with 27 mo or 29 mo.

Sintering Effects on Fe/Mo Ordering and Magnetoresistance in Double Perovskite Sr2FeMoO6

  • Kim, J;Park, B.J;Lee, B.W
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.9-12
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    • 2004
  • We have investigated sintering effects on Fe/Mo ordering and magnetoresistance (MR) in double perovskite-reflection lines due to $Sr_2FeMoO_6$ (SFMO). Polycrystalline samples have been prepared by the conventional solid-state reaction by sintering in a stream of 5% $H_2/Ar$ gas. All samples are single phase and exhibit a series of superstructurecation ordering at Fe and Mo sites. As sintering temperature increases from 900 to $1300^{\circ}C$, the degree of Fe/Mo ordering increases from 82 to 92%, magnetization (15 K, 7 kOe) increases from 1.6 to 2.7 ${\mu}_B/f.u.,$ and Curie temperature increases at a rate of 4.3 K/% with the increase of Fe/Mo ordering ratio. The magnitude of MR measured at 5 K is 19% for sample prepared at $1000^{\circ}C$ with magnetic fields of 7 kOe. The observed MR is proportional to the square of magnetization indicating that the MR feature in SFMO is explained by the spin-polarized tunneling at grain boundaries.

Effects of sodium molybdate on myo-inositol phospholipid metabolism-related enzymes in peripheral nerves of lead-intoxicated rats. (Sodium molybdate가 납중독 랫드의 말초신경내 myo-inositol 인지질 대사 관련 효소에 미치는 영향)

  • 박성환;정명규;조해용;최창하;김명녀
    • Journal of environmental and Sanitary engineering
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    • v.16 no.4
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    • pp.1-8
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    • 2001
  • We have previously demonstrated that sodium molybdate(Mo) improved lead-intoxicated status by enhancing the metabolism of mao-inositol-related phospholipids in sciatic nerves isolated from rats. In this study, in order to address the reduction mechanism of Mo for lead toxicity, effects of Mo on cystidine-diglyceride transferase, phosphatidylinositol kinase, and phosphatidyl inositol-4-phosphate kinase, involved in mao-inositol metabolism of nerve, were investigated in vivo and in vitro. Mo significantly increased the activities of cystidine- diglyceride transferase and phosphatidylinositol kinase in lead-intoxicated rat, and the pattern of increase was dose-dependent manner. However, Mo did not affect the activity of phosp- hatidylinositiol-4-phosphate kinase in normal and lead-intoxicated rats. We also found that Mo affected the activities of phopholipid metabolism-related enzymes not by the indirect manner such as activation of another metabolic pathway but by the direct manner. These results suggest that the improvement mechanism of Mo for lead-intoxicated status might be a normalization of the activities of phospholipid metabolism-related enzymes in sciatic nerve.

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Effects of Mo on the Passive Films Formed on Ni-(15, 30)Cr-5Mo Alloys in pH 8.5 Buffer Solution

  • Jang, Hee-Jin;Kwon, Hyuk-Sang
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.258-262
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    • 2009
  • The composition and semiconducting properties of the passive films formed on Ni- (15, 30)Cr-5Mo alloys in pH 8.5 buffer solution were examined. The depth concentration profile of passive films formed on Ni-(15, 30)Cr-5Mo in pH 8.5 buffer solution showed that Mo enhances the enrichment of Cr. The Mott-Schottky plot for the passive film on Ni-(15, 30)Cr- 5Mo closely resembled that for the film on Cr, whereas those for the less Cr-enriched film on Mo-free alloys showed similar behavior to that for the film on Ni. The acceptor density was reduced by increasing Cr content in Ni-(15, 30)Cr-(0, 5)Mo alloys, but addition of Mo considerably increased the acceptor density.

Effects of Additives on the Phase Sepration and the Chemical Durability of Sodium Borosilicate Glasses (붕규산 소다 유리의 분상 및 화학적 내구성에 대한 첨가제의 영향)

  • 현상훈;천광수;송원선
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.173-183
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    • 1988
  • Effects of oxide additives such as MoO3, MnO2 ZrO2 and Fe2O3 on the phase separation and the chemical durability of sodium borosilicate glasses which are the host of waste glasses have been investigated as the basic study on the nuclear-waste immobilization through vitrification. MoO3 and MnO2 were found to be phase separation promotors which increased the temperature as well as catalyzed nucleation and growth for the phase separation of the 10Na2-O-3OB2O3-6OSiO2 (wt%) parent glass within the immiscibility region. The glasses had the interconnected phase-separated structure as the amount of addition increased. On the other hand, ZrO2 and Fe2O3 were inhibitors which showed the reverse effects to the above promotors. It was also found that addition of MoO3 could cause the phase separaton of the 20Na2O-10B2O3-70SiO2(wt%) glass even within the miscibility region. Addition of ZrO2 and Fe2O3 increased the chemical durability of the parent glass within the immiscibility region. Within the miscibility region, however, the addition of 1.96 wt % of MoO3 increased the chemical durability considerably, while MnO2 had little effects.

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Complex heat-treatment effects on as-built CoCrMo alloy (적층공정법으로 제작된 CoCrMo 합금의 복합열처리 효과)

  • Lee, Jung-Il;Kim, Hung Giun;Jung, Kyung-Hwan;Kim, Kang Min;Son, Yong;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.250-255
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    • 2018
  • The CoCrMo as-built alloys prepared by 3D-printing process are studied on tensile strength, wear resistance, crystal structure and microstructure after complex heat-treatment including HIP. In this study, HIP treatment for removing micropores, ambient heat-treatment for formation of metal carbides, and solution heat-treatment for homogenization of the created metal carbides were tried and characterized for applying to artificial joint. The complex heat-treatment effects of the CoCrMo as-built alloys prepared by 3D-printing process were owing to the densification during HIP, formation of metal carbides and homogenization of the created metal carbides. The effects of the complex heat-treatment were confirmed by XRD, FE-SEM and EDS.