• Title/Summary/Keyword: Effective Heat of Formation

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SIMULATION OF CORE MELT POOL FORMATION IN A REACTOR PRESSURE VESSEL LOWER HEAD USING AN EFFECTIVE CONVECTIVITY MODEL

  • Tran, Chi-Thanh;Dinh, Truc-Nam
    • Nuclear Engineering and Technology
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    • v.41 no.7
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    • pp.929-944
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    • 2009
  • The present study is concerned with the extension of the Effective Convectivity Model (ECM) to the phase-change problem to simulate the dynamics of the melt pool formation in a Light Water Reactor (LWR) lower plenum during hypothetical severe accident progression. The ECM uses heat transfer characteristic velocities to describe turbulent natural convection of a melt pool. The simple approach of the ECM method allows implementing different models of the characteristic velocity in a mushy zone for non-eutectic mixtures. The Phase-change ECM (PECM) was examined using three models of the characteristic velocities in a mushy zone and its performance was compared. The PECM was validated using a dual-tier approach, namely validations against existing experimental data (the SIMECO experiment) and validations against results obtained from Computational Fluid Dynamics (CFD) simulations. The results predicted by the PECM implementing the linear dependency of mushy-zone characteristic velocity on fluid fraction are well agreed with the experimental correlation and CFD simulation results. The PECM was applied to simulation of melt pool formation heat transfer in a Pressurized Water Reactor (PWR) and Boiling Water Reactor (BWR) lower plenum. The study suggests that the PECM is an adequate and effective tool to compute the dynamics of core melt pool formation.

Evaluation of Effective Thermal Conductivity and Thermal Resistance in Ground Heat Exchanger Boreholes (지중 열교환기 보어홀에서의 유효 열전도도 및 열저항 산정)

  • Sohn Byong Hu;Shin Hyun-Joon;Park Seong-Koo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.8
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    • pp.695-703
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    • 2005
  • The objective of this study is to determine the effective thermal conductivity and thermal resistance values in test boreholes with three different fill materials. To evaluate these heat transfer properties, in-situ tests on four vertical boreholes were conducted by adding a monitored amount of heat to water over various test lengths. Two parameter estimation models, line-source and numerical one-dimensional models, for evaluation of thermal response test data were compared when applied on the same four data sets. Results show that the average thermal conductivity deviation between measured data and these two models is in the range of $3.03\%$ to $4.45\%$. The effect of increasing grout thermal conductivity from 1.34 to 1.82 $W/m^{\circ}C$ resulted in overall increases in effective formation thermal conductivity by $11.1\%$ to $51.9\%$ and reductions in borehole thermal resistance by $11.6\%$ to $26.1\%$.

The effects of particle shape on the effective thermal conductivity enhancement of nanofluids (나노유체 입자상 모양의 유효 열전도도에의 영향)

  • Koo, June-Mo;Kang, Yong-Tae
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2106-2109
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    • 2008
  • Nanofluids have been studied as possible alternatives for heat transfer fluids to improve the efficiency of heat exchangers. There are deviations of measured effective thermal conductivities between research-groups, and the mechanisms of the effective thermal conductivity enhancement of nanofluids are not confirmed yet. In this study, the effects of particle shape on the effective thermal conductivity enhancement are discussed and presented as a possible explanation of the deviations. The particle motion effect is found to be negligible for nanofluids of high aspect ratio cylindrical particles, which is believed to be important for nanofluids of spherical particles, while the percolation network formation and contact resistance play dominant roles in determining the effective thermal conductivity.

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An Experimental Study on the Heat Transfer Characteristics to Enhance the Artificial Hydrate Formation Performance (전열특성을 이용한 가스하이드레이트 인공제조 성능향상에 대한 실험적 연구)

  • Shin, Chang-Hoon;Park, Seoung-Su;Kwon, Ok-Bae;Shin, Kwang-Sik;Choi, Yang-Mi;Lee, Jeong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.515-518
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    • 2007
  • Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Recently, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-sol id ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective mass production method of gas hydrate in solid form. In this study, some performance comparison among several cases classified by different volume sizes of solution were carried to identify the characteristics due to the volume increment. And it is found that one of the main reasons disturbing hydrate formation is related to the lack of cooling heat transfer due to the volume increase of the solution. So, three kinds of heat transfer plates which have different shapes and cross sectional areas were made and tested for the performance comparison following to the shape and area of each plate. Finally it is clarified that the heat transfer is one of the major factors effecting hydrate formation performance and the installation of heat transfer plate can enhance the formation performance especially not in terms of the quantity but the speed.

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Effect of Reverse Transformation Treatment on the Formation of Retained Austenite in 01.5%C-6%Mn Steels (0.15%C-6%Mn강의 잔류오스테나이트 생성에 미치는 역변태 열처리의 영향)

  • Hong, H.;Lee, O.Y.;Lee, K.B.
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.1
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    • pp.35-45
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    • 1998
  • The effects of alloying elements and the conditions of reverse transformation studied treatment on the formation of retained austenite in 0.15C-6%Mn-(Ti, Nb) steels has been studied. The addition of Ti and Nb to 0.15C-6%Mn steel shows no effect on the formation of retained austenite. In case of reverse transformation treatment at various temperatures, the shape of retained austenite was lath type, growing toward the longitudinal and thickness direction with increasing the heat treatment temperatures. The retained austenite formed by the reverse transformation treatment at higher temperature has a lot of stacking faults induced by the internal stress. The retained austenite was stabilized chemically by enrichment of C and Mn in the vicinity of a untransformed austenite and the chemical stability of retained austenite was decreased with increasing the heat treatment temperature and the holding time. It was effective to heat treat at $650^{\circ}C$ in order to obtain over 30vol.% of retained austenite, but more desirable to heat treat at $625^{\circ}C$ for a long time, considering the amount and quality of retained austenite.

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Silicide Formation by Solid State Diffusion in Mo/Si Multilayer Thin Films (Mo/Si 다층박막에서의 고상확산에 의한 실리사이드 생성에 관한 연구)

  • 지응준;곽준섭;심재엽;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.507-514
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    • 1993
  • The solid state reaction of Mo/Si multilayer thin films produced by RF magnetron sputtering technique was examine dusing differential scanning calorimetry (DSC) and x-ray diffraction, and explained in view of two concepts, effective drivig force and effective heat of formation. In constant scanning rate DSC, there were two exothermic peks which corresponded to the formation of h-MoSi2 and t-MoSi2 , respectively. The activation energyfor theformation of h-MoSi2 was 1.5eV , and that of t-MoSi2 was 7.8eV. Nucleation wa stherate controlling mechanism for each of the silicide formation. Amorphous phase was not formed , which was consistent withtheprediction by the concept of effective driving force. h-MoSi2 the first crystalline phase, was considered to have lower interfacial free energy than t-MoSi2 and by increasing temperature it was transformed into more stable t-MoSi2.

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Structural transition of Ti-Cr-V alloys with hydrogenation and dehydrogenation and the improvement of their hydrogen storage properties by heat treatment (Ti-Cr-V 합금의 수소화-탈수소화에 따른 상천이 및 열처리에 의한 수소저장특성의 향상)

  • You, Jeong-Hyun;Cho, Sung-Wook;Shim, Gun-Choo;Choi, Good-Sun;Park, Choong-Nyeon;Choi, Jeon
    • Journal of Hydrogen and New Energy
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    • v.17 no.2
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    • pp.125-132
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    • 2006
  • The alloys which compositions were represented by the formula, $Ti_{(0.22+X)}Cr_{(0.28+1.5X)}V_{(0.5-2.5X)}$ ($0{\leq}X{\leq}0.12$), had the total hydrogen storage capacity higher than 3 wt% and the effective hydrogen storage capacity higher than 1.4 wt%. Particularly, among all the tested alloys, the $Ti_{0.32}Cr_{0.43}V_{0.25}$ alloy exhibited the best effective hydrogen storage capacity of 1.65 wt%. Furthermore, the reversible bcc${\leftrightarrow}$fcc structural transition was observed with hydrogenation and dehydrogenation, which predicted the possibility of pressure cycling. EDS analysis revealed micro-segregation, which suggested the necessity of microstructure homogenization by heat treatment. The $Ti_{0.32}Cr_{0.43}V_{0.25}$ alloy was selected for heat treatment and for other related studies. The results showed that the total and the effective hydrogen storage capacity increased to 3.7 wt% and 2.3 wt%, respectively. The flatness of the plateau region was also greatly improved and heat of hydride formation was determined to be approximately -36 kJ/mol $H_2$.

The Effects of δ-ferrite on Weldment of 9-12% Cr Steels (9-12% Cr강의 용접부에 미치는 δ-ferrite의 영향)

  • Ahn, Sung-Yong;Kang, Namhyun
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.8-16
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    • 2013
  • As the energy consumption increases rapidly, power generation needs the high energy efficiency continuously. To achieve the high efficiency of power generation, the materials used have to endure the higher temperature and pressure. The 9-12%Cr steels possess good mechanical properties, corrosion resistance, and creep strength in high temperature due to high Cr contents. Therefore, the 9-12%Cr steels are widely used for the high-temperature components in power plants. Even though the steels usually have a fully martensitic microstructure, they are susceptible to the formation of ${\delta}$-ferrite specifically during the welding process. The formation of ${\delta}$-ferrite has several detrimental effects on creep, ductility and toughness. Therefore, it is necessary to avoid its formation. As the volume fraction of ${\delta}$-ferrite is less than 2% in microstructure, it has the isolated island morphology and causes no significant degradation on mechanical properties. For ${\delta}$-ferrite above 2%, it has a polygonal shape affecting the detrimental influence on the mechanical properties. The formation of ${\delta}$-ferrite is affected by two factors: a chemical composition and a welding heat input. The most effective ways to get a fully martensite microstructure are to reduce the chromium equivalent less than 13.5, to keep the difference between the chromium and nickel equivalent less than 8, and to reduce the welding heat input.

Mechanism of intragranular ferrite formation in heat-affected zone of titanium killed steel

  • Terasaki, Hidenori;Komizo, Yu-Ichi
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.197-201
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    • 2009
  • A lot of work is carried out concerning to acicular ferrite formation in the weld metal of high strength and low-alloy steel. Those results are suggesting that oxides that contain titanium elements provides nucleation site of intragranular ferrite, referred as acicular ferrite. Thus, when intragranular ferrite is expected to form in heat-affected zone, oxide containing titanium element should be formed in the steel. However, normal steel is deoxidized by using aluminum element (Al-killed steel) with little oxygen content. It means almost oxygen is deoxidized with aluminum elements. In the present work, in order to form the acicular ferrite in the heat affected zone, with the same concept in the case of weld metal, the steel deoxidized with titanium element (titanium killed-steel) is prepared and the acicular ferrite formation is observed in detail by using laser-conforcal microscopy technique. The confocal technique makes it possible that the morphological change along the phase transformation from austenite to ferrite is in-situ tracked. Thus, the inclusion that stimulated the ferrite nucleation could be directly selected from the observed images, in the HAZ of the Ti-killed steel. The chemical composition of the selected inclusion is analyzed and the nucleation potential is discussed by changing the nucleation site with boron element. The potency for the ferrite nucleation is summarized and the existence of effective and ineffective manganese sulfide for nucleation is made clear.

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The Effect of Environmental Parameters on Frost Formation on a Horizontal Cylinder (수평 실린더에서의 서리 생성에 대한 환경 변수들의 영향)

  • Lee, Yun-Bin;Ryu, In-Sang;No, Seung-Tak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.2
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    • pp.253-260
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    • 2002
  • It is known that frost formation on surfaces of the heat exchanger seriously affects the performance of the refrigeration system. Accordingly, defrosting should follow, and effective defrosting is possible only when both analytic tools and comprehensive experimental data on frost formation are assailable. An experimental investigation was undertaken to characterize the effect of environmental parameters on frost formation on a horizontal cylinder in cross uniform flow. Several experiments were carried out with various environmental parameters such as inlet air temperature, inlet air humidity, air velocity and cooling surface temperature. Frost thickness, mass, surface temperature and cylinder inner and outer temperature were measured at front and rear positions of the cylinder. Thickness, mass, density, and effective thermal conductivity of the frost layer were obtained from measured data and effects of environmental parameters on the frost formation were analyzed. Data from experiments were correlated using dimensionless variables.