• 제목/요약/키워드: Effect of Cu addition

검색결과 506건 처리시간 0.026초

이동 통신용 $BiNbO_4$ 세라믹스의 CuO 및 CdO 첨가량에 따른 고주파 유전 특성 (Effect of CuO and CdO Additions on the Microwave Dielectric Properties of $BiNbO_4$ Ceramics using Mobile Communication)

  • 윤중락;이헌용;김경용
    • 한국재료학회지
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    • 제8권11호
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    • pp.1043-1047
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    • 1998
  • CuO 및 C얘의 첨가가 $BiNbO_4$ 세라믹스의 고주파 유전특성에 미치는 영향을 조사하였다. CdO 첨가량이 증가함에 따라 소결밀도 및 품질계수는 감소하였고 소결온도가 증가하면 유전상수 및 품질계수는 증가하였다. $BiNbO_4$에 CuO 및 CdO를 각각 0.03wt% 첨가한 시편을 $960^{\circ}C$에서 소결시 유전율 41.2, 품질계수($Q{\times}f_0$) 6,500(at 5.6GHz), 공진주파수 온도계수 $3ppm^{\circ}C$의 우수한 고주파 유전특성을 얻을 수 있었다.

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구리 CMP시 확산방지막의 부식특성 (Corrosion Characteristics of Diffusion Barrier in Copper CMP)

  • 이도원;김남훈;임종혼;김상용;이철인;장의구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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    • pp.162-165
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    • 2003
  • The corrosion characteristics of diffusion barrier in Copper CMP has been investigated. Key experimental variables that has been investigated are the corrosion rate by different agents containing slurry of Cu CMP. Whenever Cu and Ta films were corroded adding each oxidizer, the corrosion rate of Ta was much lower than that of Cu. That is, the difference in the corrosion rates of Ta by oxidizer was not larger as compared with Cu. As corroded by complexing agents, the corrosion rate of Ta was close to O. The corrosion rate of Ta increased as added $HNO_3$ and $CH_3COOH$ compared with the reference slurry; on the other hand, it decreased with addition of HF. In addition, resulting corrosion rate went up with lower pH of agent. The corrosion rates by agents were however significant small; hence, it doesn't affect on the removal rate of Cu CMP practically. Consequently, this can be explained by assuming that the mechanical effect dominates than the chemical effect on the polishing rate of Ta(TaN).

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무전해 Ni-Cu-P 도금층의 자성에 미치는 도금조건과 도금속도의 영향 (Effect of Plating Condition and Plating Rate on the Magnetic Properties of Electroless Ni-Cu-P Deposits)

  • 오이식;이태희
    • 동력기계공학회지
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    • 제10권3호
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    • pp.58-66
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    • 2006
  • The effect of bath composition, plating condition and plating rate on the magnetic properties of electroless Ni-Cu-P deposits were investigated. With increasing $CuSO_4$ concentration in the bath, plating rate increased, while the Br value of deposits decreased Sharply. Plating rate increased up to 34% with the addition of 200ppm of NaF and 0.8ppm of Thiourea to the bath. Plating reaction had been ceased by the increase of pH above 11.3, bath temperature higher than $90^{\circ}C$ and under $70^{\circ}C$. The Br value of deposit was uniform with various concentration of complexing agent (Sodium citrate, Ethylenediamine) in the bath. The Br value of deposit was almost equal to that found by the addition of stabilizer(Thiourea) and accelerator(NaF). The Br value of deposit was uniform in plating time(120 min) and heat treatment temperature(below $200^{\circ}C$), and were confirmed to have adequate bath stability for practical use.

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Al-Cu-Mn 주조합금의 피로성질에 미치는 Cd 첨가의 영향 (Effect of Cd addition on the Fatigue Properties of Al-Cu-Mn cast alloy)

  • 김경현;이병훈;김인배
    • 한국재료학회지
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    • 제11권4호
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    • pp.300-304
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    • 2001
  • Al-Cu-Mn 주조합금의 피로성질에 미치는 Cd 첨가의 영향을 저주기 및 고주기 피로시험을 통하여 조사하였다. Cd 첨가량이 증가함에 따라 피로수명이 증가하였으며, 인장강도도 증가하였다. 고주기 피로시험결과 피로강도는 115MPa이었으며 피로비는 0.31이었다. 피로시험 결과 균열이 표면에서 발생하여 입계를 따라 전파되었는데 이러한 입계파괴는 입계를 따라 존재하는 무석출대의 영향으로 생각된다. 인장강도값은 Cd이 첨가되지 않았을 경우 330MPa이었으나 0.15%의 Cd이 첨가됨으로써 401MPa 까지 증가되었다.

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CuO 및 MgO 첨가가 Mg-Zn Ferrite의 자기적 특성에 미치는 효과 (Effect of the Addition of CuO and MgO on the magnetic characteristics of Mg-ZnFerrite)

  • 이준모;최규만;권혁상;이윤식;이호진;이상훈
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2008년도 하계종합학술대회
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    • pp.495-496
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    • 2008
  • The magnetic characteristics of Mg-Zn ferrite that was fired at $1150^{\circ}C$ for 1hour and sintered at $1250^{\circ}C$ for 3hours was examined. The composition ratio of the ferrite was changed after sintering. In that case the composition ratio of ${Fe_2}{O_3}$ was increased but that of CuO was decreased. When the addition quantity of CuO was 3.8 mole%, it's shrinkage rate had maximum value. Magnetic permeability was decreased as the addition rate of CuO was increased and MgO was decreased. When the composition rate of CuO was 2.3 mol% and MgO was 10.9 mol%, the firing density had maximum value. In case that CuO was 2.8mol% and MgO was 10.4mol%, PL had minimum value.

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TFT-LCDs에 적용 가능한 Cu-Ag 박막에 대한 Mo 기판 위에서의 특성조사 (Characteristic of Cu-Ag Added Thin Film on Molybdenum Substrate for an Advanced Metallization Process)

  • 이현민;이재갑
    • 한국재료학회지
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    • 제16권4호
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    • pp.257-263
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    • 2006
  • We have investigated the effect of silver added to Cu films on the microstructure evolution, resistivity, surface morphology, stress relaxation temperature, and adhesion properties of Cu(Ag) alloy thin films deposited on Mo glue layer upon annealing. In addition, pure Cu films deposited on Mo has been annealed and compared. The results show that the silver in Cu(Ag) thin films control the grain growth through the coarsening of its precipitates upon annealing at $300^{\circ}C{\sim}600^{\circ}C$ and the grain growth of Cu reveals the activation energy of 0.22 eV, approximately one third of activation energy for diffusion of Ag dopant along the grain boundaries in Cu matrix (0.75 eV). This indicates that the grain growth can be controlled by Ag diffusion along the grain boundaries. In addition, the grain growth can be a major contributor to the decreased resistivity of Cu(Ag) alloy thin films at the temperature of $300^{\circ}C{\sim}500^{\circ}C$, and decreases the resistivity of Cu(Ag) thin films to $1.96{\mu}{\Omega}-cm$ after annealing at $600^{\circ}C$. Furthermore, the addition of Ag increases the stress relaxation temperature of Cu(Ag) thin films, and thus leading to the enhanced resistance to the void formation, which starts at $300^{\circ}C$ in the pure Cu thin films. Moreover, Cu(Ag) thin films shows the increased adhesion properties, possibly resulting from the Ag segregating to the interface. Consequently, the Cu(Ag) thin films can be used as a metallization of advanced TFT-LCDs.

Cu 첨가에 따른 Nd-Fe-B strip cast의 미세조직과 자기적 특성의 상관관계 (Effect of Cu Content on Microstructural and Magnetic Properties of a Nd-Fe-B Strip Cast)

  • 박송이;김태훈;이성래;김동환;남궁석;장태석
    • 한국분말재료학회지
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    • 제18권1호
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    • pp.24-28
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    • 2011
  • Effect of Cu content on microstructural and magnetic properties of a $(Nd_{26.06},Dy_{6.51})Fe_{bal.}$ $Cu_xB_{0.97}$(wt.%), (x = 0.2, 0.3, 0.4, 0.5) strip-cast was studied. The average inter-lamellar spacing in the free surface and wheel side of the strip cast increased as the Cu content increases. The grain uniformity, the grain alignment, and (00L) texture of the strip cast increased with Cu contents up to 0.4 wt.%. These microstructural changes were attributed to the decrease of the effective cooling rate of the melted alloy caused by the decrease of the melting temperature of resulting from Cu addition. Coercivity and remanence were increased because of the grain alignment and (00L) texture improvement with Cu contents up to 0.4 wt.%.

Effect of La0.7Sr0.3MnO3 addition on superconducting properties and local structure of (Bi, Pb)-2223 superconductor

  • M. A. Anugrah;R. P. Putra;J. Y. Oh;B. Kang
    • 한국초전도ㆍ저온공학회논문지
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    • 제25권2호
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    • pp.5-9
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    • 2023
  • The effect of La0.7Sr0.3MnO3 (LSMO) addition on the superconducting property of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ((Bi, Pb)-2223) polycrystalline samples was studied. LSMO (0.3 wt.% to 2.0 wt.%) added (Bi, Pb)-2223 samples were prepared by using a solid-state reaction method. The XRD analyses show that as the LSMO addition increases, the volume fraction of the Bi-2223 phase is gradually decreased. The critical temperature (Tc) exhibits a gradual decrease with a single transition as the LSMO amount increases up to 1.0 wt.%, but a further addition of LSMO induces an abrupt decrease of Tc with a dual transition. The analyses on the local structure of the CuO2 plane from the X-ray absorption fine structure (EXAFS) measurements showed that for the samples with low concentration of LSMO up to 1.0 wt.%, the Cu-O bond length and the CuO2 plane ordering do not degrade from the values of pure (Bi, Pb)-2223, while they get worsen with a further increase of LSMO addition. These results open up the possibility of LSMO as artificial pinning centers of the (Bi, Pb)-2223 system for power application.

Al-10.5wt%Si-2wt%Cu 다이 캐스팅용 2차 지금의 미세조직에 미치는 Sr의 양과 유지시간의 영향 I (The Effect of Sr Addition and Holding Time on Microstructure of Al-10.5%Si-2%Cu Secondary Die-casting Alloys)

  • 신상수;김명용;염길용
    • 한국주조공학회지
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    • 제30권5호
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    • pp.161-166
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    • 2010
  • In this examination, the effect of Sr addition and holding time on microstructure of Al-10.5wt%Si-2wt%Cu secondary die-casting alloy was investigated. Degree of undercooling was improved with increasing the Sr content in this alloy. Up to 0.02wt%Sr addition, acicular and lamellar eutectic structure was observed in the microstructure. Meanwhile, the eutectic Si was modified toward the fine fibrous form by increasing Sr content with more than 0.03wt% and holding time of the melt. The well- modified alloys showed decreased eutectic silicon size from 3.25 ${\mu}m$ to less than 0.8 ${\mu}m$. From these results, the optimal strontium content and holding time were identified on the Al-10.5wt%Si-2wt%Cu secondary die-casting alloy.

Cu와 Si 첨가에 의한 Al-Sn 합금의 미세조직 제어 (Microstructural Control of Al-Sn Alloy with Addition of Cu and Si)

  • 손광석;박태은;김진수;강성민;김태환;김동규
    • 대한금속재료학회지
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    • 제48권3호
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    • pp.248-255
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    • 2010
  • The effect of various alloying elements and melt treatment on the microstructural control of Al-Sn metallic bearing alloy was investigated. The thickness of tin film crystallized around primary aluminum decreased with the addition of 5% Cu in Al-Sn alloy, with tin particles being reduced in size by intervening the Ostwald ripening. With the addition of Si in Al-10%Sn alloy, the tin particles were crystallized with eutectic silicon, resulting in uniform distribution of tin particles. With the addition of Cu and Si in Al-Sn alloy, both the tensile strength and yield strength increased, with the increasing rate of yield strength being less than that of tensile strength. Although the Al-10%Sn-7%Si alloy has similar tensile strength compared with Al-10%Sn-5%Cu, the former showed superior abrasion resistance, resulting from preventing the tin particles from movement to the abrasion surface.