• Title/Summary/Keyword: Effect Modifier

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A study on the Water Retention of Coating Colors(V)-Application of Alkali Sensitive Water Retention and Rheology Modifiers- (도공액의 보수성에 관한 연구(제5보)-알칼리 반응형 보수.유동성 개량제의 적용-)

  • 이용규;엄기용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.28-35
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    • 1997
  • Sole-binder formulation has been recently introduced to solve the problems of coating process and printability caused by use of natural polymer However, the decrease of natural polymer application causes another problem in paper coating. Therefore, synthetic thickener is used to get similar effect to natural polymer usage. In this study. low shear viscosity, dewatering of coating colors were measured to evaluate the performance of the alkali sensitive water retention and rheology modifiers. The effects of alkali sensitive thickener on the physical properties of coated paper and printability were also investigated. The gloss and printability of coated paper containing the synthetic flow modifier were similar or superior to those of CMC containing coated paper. This modifier was also effective to improve the problems caused by the use of starch. The results indicated that the flow modifier synthesized with alkali sensitive thickener can reduce the problems of natural polymer and could be a good substitute f3r a natural polymer.

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Studies on Relations between High Solid Coating and Quality Changes(II) - Effect of high solid coating on coated paper properties - (고농도 도공과 품질변화의 상관성 연구(2보) -도공지의 품질과 고농도 도공의 효과-)

  • Lee, Yong-Kyu;Yoo, Sung-Jong;Cho, Byoung-Uk;Kim, Yong-Sik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.3
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    • pp.52-59
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    • 2007
  • This paper confirms that high solid coating can increase coating speed and reduce drying cost. Low solid coating color with the synthetic thickener and high solid coating color with the rheology modifier and with higher ratio of GCC were prepared. Coated paper was then produced with an industrial coater, varying coating speed and dryer temperature in order to keep the moisture content of the coated paper constant. Coating color concentration was able to be increased from 66% to 69% and from 68% to 71% without an adverse effect on coating color rheology. With a help of the rheology modifier, the increased ratio of GCC in high solid coating did not show harmful effects on the coated paper quality.

Performance of Geogrids for Retarding Reflection Crack of Asphalt Overlay Pavement (아스팔트 덧씌우기의 반사균열 지연을 위한 지오그리드의 적용성 연구)

  • Kim, Kwang-Woo;Doh, Young-Soo;Kim, Bun-Chang;Lee, Moon-Sup
    • International Journal of Highway Engineering
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    • v.7 no.2 s.24
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    • pp.1-12
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    • 2005
  • This study was conducted to evaluate effect of geogrid and fabric, which are used underneath the overlaid asphalt pavement for retarding reflection cracking by simulated laboratory test. In this study, an interlayer at the interface between old concrete pavement surface and overlaid asphalt mixture, and polymer-modifier were used as an effort of retarding reflection crack initiation and for strengthening mixture. Five products were used in preparation of asphalt concrete beam specimen which was tack coated on top of jointed concrete block. Simulated Mode I and II fracture test were conducted under wheel loading and results were compared among those products. From the test results, several material and reinforcement combinations were observed to have a significant retardation effect against reflection cracking. The most effectively strengthened pavement against reflection cracking was found to be the LDPE-modifier asphalt mixture with a grid reinforcement at the bottom.

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Study on miscibility, morphology, thermal and mechanical properties of elastomeric impact modifier reinforced Poly(lactide)/Cellulose ester blends (충격보강제로 강인화된 PLA와 cellulose ester 블렌드의 상용성 및 모폴로지, 열적, 기계적 특성에 관한 연구)

  • Park, Jun-Seo;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4081-4086
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    • 2014
  • Cellulose acetate butyrate (CAB) is a biodegradable resin with excellent optical properties, but it is difficult to apply film process. In this study, an attempt was made to improve the processability of CAB using polyactic acid and the mechanical properties using an impact modifier. Polylacitc acid (PLA)/Cellulose acetate butyrate (CAB) blends with an impact modifier were prepared using a twin screw extruder. The temperature range was $140^{\circ}C$ to $200^{\circ}C$, and the screw speed was fixed to 200 rpm. To evaluate the miscibility of impact modified CAB/PLA, the glass transition behavior and morphology were observed by DSC and FE-SEM. The mechanical properties were investigated by dynamic mechanical analysis (DMA) and a Universal Testing Machine (UTM). In addition, the effect of an impact modifier in the polymer matrix was determined using a notched Izod impact strength tester. Finally, the PLA/CAB/impact modifier 75/25/10 ratio was found to be a compatible system. In the 10wt.% impact modifier, the sample had a 4 times higher izod impact strength than the non-toughening composition.

A Comparative Analysis of Whole Blood Cadmium by Atomic Absorption Spectrophotometry with a Graphite Furnace (흑연로 원자흡수분광법에 의한 혈액중 카드뮴 정량분석)

  • Park, Jong An;Oh, Hye Jeong;Lee, Jong Hwa
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.301-312
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    • 1996
  • This study was performed to search a optimal analyzing method of cadmium in whole-blood. Cadmium was determined by graphite furnace atomic absorption spectrometry(GFAAS). We investigated the effect of ashing temperature on the absorbance of cadmium in a simple dilution(ten-fold) method with triton X-100 and matrix modifier methods treated with $NH_4H_2PO_4$(1 and 3%) and $Pd(NO_3)_2$(0.00l and 0.005%) as matrix modifier. We also compared the reported reference values of standard blood with values resulted from optimal analyzing conditions of this study. In case of a simple dilution method, when ashing temperature was set at $450^{\circ}C$, the absorbance of sample and background were $0.334{\pm}0.012$ and $1.382{\pm}0.245$, respectively. Background level was higher than the value(0.8) that can be corrected by $D_2$ background correction method. As ashing temperature was rised to $500^{\circ}C$, the absorbance of sample and background were $0.178{\pm}0.008$ and $0.711{\pm}0.223$ respectively. The higher ashing temperature($450^{\circ}C-650^{\circ}C$) was, the lower the absorbance of sample was. In case of a matrix modifier method with $NH_4H_2PO_4$(1 and 3%), when ashing temperature was rised from $500^{\circ}C$ to $650^{\circ}C$, the absorbance of sample slightly changed. The absorbances of sample at $600^{\circ}C$ were $0.230{\pm}0.017$ and $0.137{\pm}0.012$, respectively. These values were larger than that of simple dilution method. But the absorbance of background was higher than the level that can be corrected by $D_2$ method. In case of a matrix modifier method with $Pd(NO_3)_2$(0.001 and 0.005%), the absorbance of sample and background were higher than those of other methods and were stable and reproducible. When ashing temperature was over $550^{\circ}C$, the absorbance of sample was significantly decreased. In case of 0.005% $Pd(NO_3)_2$ carbon residue remained in graphite tube affected the absorbance of sample and background. From these results, We propose that in case of a simple dilution(ten-fold) method with triton X-100 ashing temperature must be maintained below $400^{\circ}C$. In order to diminish the absorbance of background, the alternative method is attenuation of injection volume or multiplication of dilution ratio. We recommend $Pd(NO_3)_2$ than $NH_4H_2PO_4$ as a matrix modifier. In case of a matrix modifier method with $Pd(NO_3)_2$ ashing temperature might be maintained below $550^{\circ}C$.

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Automotive Engine Oil and Vehicle Fuel Economy (자동차 엔진오일과 연비)

  • 이영재;김강출;표영덕
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.155-161
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    • 2000
  • To improve the vehicle fuel economy, various technologies such as improvement of power train efficiency, use of light weight material, improvement of aerodynamic design, have been studied. One of the possible way to improve the vehicle fuel economy is to reduce the engine friction loss by improving the engine oil characteristics. In the present paper, it was examined the effect of the engine oil viscosity and the addition of friction modifier to engine oil on vehicle fuel economy improvements. Moreover, the effect of engine oil degradation on vehicle fuel economy was examined with two gasoline vehicles and one diesel vehicle by using the fuel economy test facility.

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A Proposal of Wheel/Rail Contact Model for Friction Control

  • Matsumoto Kosuke;Suda Yoshihiro;Komine Hisanao;Nakai Takuji;Tomeoka Masao;Shimizu Kunihito;Tanimoto Masuhisa;Kishimoto Yasushi;Fujii Takashi
    • Journal of Mechanical Science and Technology
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    • v.19 no.spc1
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    • pp.437-443
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    • 2005
  • Controlling the friction between wheel and rail is direct and very effective measures to improve the curving performances of railway trucks, because the curving performances depend much on friction characteristics. Authors have proposed a method, 'friction control', which utilizes friction modifier ($KELTRACK^{TM}$ HPF) with onboard spraying system. With the method, not only friction coefficient, but also friction characteristics can be controlled as expected. In this study, MBD simulation is very valuable tool to foresee the effect of the control in advance of experiment with real car. And the creep characteristics of wheel/rail contact with the friction modifier takes very important role in the simulation. In this paper, authors propose a theoretical model of wheel/rail contact condition considering the creep characteristics of friction modifier, which is derived the application of principle tribological theories.

Studies on Rheological Properties of High Solid Coating Colors(Part 2) - Effect of Rheology Modifiers on High-Shear Viscosity and Dynamic Penetration Behavior - (고농도 도공액의 유동특성에 관한 연구(제2보) - 유동성 조절제가 고전단 점도 및 동적 침투특성에 미치는 영향 -)

  • Yoo, Sung-Jong;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.121-127
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    • 2011
  • This study used two types of rheology modifiers including an alkali-swellable emulsion (ASE) and an surface-adhesion emulsion (SAE) to elucidate their effects on high shear viscosity and dynamic penetration behavior among the flow properties of high solids coating. Since rheology under high shear and dynamic penetration behavior significantly affect the quality of coated paper in case of high solids coating, it is very important to examine the variations in rheology of high solids coating color by rheology modifier. It was found that the high solids coating color prepared with the SAE type showed superior dynamic penetration behavior and high shear viscosity than that with the ASE type rheology modifier.

Effects of Modifiers on the Supercritical $CO_2$ Extraction of Licorice (Glycyrrhiza glabra) and the Morphology of Licorice Tissue

  • Kim, Hyun-Seok;Lim, Gio-Bin;Kim, Byung-Yong
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.6-10
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    • 2005
  • Optimal extraction conditions such as pressures, temperatures, and modifiers on glycyrrhizin extraction from licorice were investigated using supercritical $CO_2\;(SC-CO_2)$ at 3 mL/min flow rate. Morphology of licorice tissue, after glycyrrhizin extraction, was examined by SEM, and absolute density ($g/cm^3$) measurement and glycyrrhizin content were determined by HPLC. Pure $SC-CO_2$ had no effect on glycyrrhizin extraction, but recovery of glycyrrhizin ($32.66{\pm}0.77%$) was enhanced when water was used as modifier. The highest recovery was $97.22{\pm}2.17%$ when 70% (v/v) aqueous methanol was added to 15% (v/v) $SC-CO_2$ at 50 MPa and $60^{\circ}C$. Under optimal extraction conditions, 30 MPa pressure and $60^{\circ}C$ heating temperature, glycyrrhizin recovery reached maximum ($102.67{\pm}1.13%$) within 60 min. Licorice tissue was severely damaged by excessive swelling, and absolute density of licorice residues was highest when aqueous methanol was used as a modifier.

Effect of Concentration of Ionic Liquids on Resolution of Nucleotides in Reversed-phase Liquid Chromatography

  • Hua, Jin Chun;Polyakova, Yulia;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.601-606
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    • 2007
  • The chromatographic behaviors of nucleotides (inosine 5'-monophosphate, uridine 5'-monophosphate, guanosine 5'-monophosphate, and thymine monophosphate disodium salts) on a C18 column were studied with different types of ionic liquids (ILs) as additives for the mobile phase in reversed-phase liquid chromatography (RPLC). Three ILs, 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]), 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm][BF4]), and 1-ethyl-3-methylimidazolium methylsulfate ([EMIm][MS]), were used. Eluents were composed of water and methanol (90/10%, vol) with the addition of 0.5-13.0 mM of ILs. The effects of the concentration of ILs on retention and separation were investigated and discussed. The results showed that the addition of ILs affects the retention and resolution of the tested compounds. Use of 13.0 mM of [BMIm][BF4] as the eluent modifier resulted in a baseline separation of nucleotides without requiring gradient elution. This study demonstrates that ILs can be potentially applied as a mobile phase modifier in RPLC.