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A Study on Property Change with Mixing Ratio in NBR/PVC Composites

  • Li, Xiang Xu;Jeong, Hyung Seok;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.48-51
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    • 2018
  • 10, 20, 30, and 40% of polyvinyl chloride (PVC) were added to nitrile butadiene rubber (NBR) to modify the latter. The NBR/PVC composites containing pure NBR were synthesized to investigate properties, such as crosslinking density, hardness, tensile strength, abrasion resistance, heat resistance, solvent resistance, and filler dispersion. The experimental result revealed a decrease in crosslinking density and heat resistance with increase in the PVC content. In contrast, addition of PVC to NBR resulted in enhancement of hardness, tensile strength, solvent resistance, and filler dispersion.

Estimation of Cooling Rate in Bulk Amorphous Alloys by Separate Cooling Process

  • Kang, Bok-Hyun;Choi, Seong-Pil;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.30 no.5
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    • pp.167-173
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    • 2010
  • 벌크 비정질 합금의 특성상 점도가 높고, 냉각속도가 빨라 냉각되는 합금의 온도를 직접 측정하는 것은 곤란하므로, 측정에 의하여 냉각속도를 구하는 것은 매우 어렵다. 본 연구에서는 합금의 온도를 직접 측정하는 대신 금형의 온도를 측정하고, 측정된 금형의 온도를 상용 열해석 프로그램을 이용한3차원 계산 결과와 비교, 보정하는 역문제 기법을 사용하여 Cu계와 Zr계 벌크 비정질합금의 냉각속도를 예측하였다. 예측된 냉각속도는 금형온도와 시편의 두께에 따라Cu계의 경우는 284~300 K/s, Zr계는 279~289 K/s로, 초기 금형온도의 영향은 크지 않은 것으로 나타났다. 전산모사 결과와 달리 금형을 수냉한 쪽보다 가열한 쪽의 응고중 냉각속도가 빨라 조직이 더 미세한 것으로 나타났는데, 이는 응고중 금형과 주물간에 에어갭의 형성으로 열전달을 방해 받은 영향으로 사료된다.

Study on Property Modification with Fire Retardant Content in the Manufacture of Compounds for Cable Sheath (전선피복용 컴파운드의 제조에서 난연제의 첨가량에 따른 물성 변화 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.47-51
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    • 2019
  • The three different polymer compounds were manufactured with the three different fire retardant (silane coated magnesium dihydroxide) contents, 180, 200, 220 phr, for making cable sheath for ship industry. In the research, ethylene-vinylacetate, polyethylene as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, plasticizer, and other additives. In the evaluation. ΔT, Mooney viscosity, and tensile strength increased with the content of fire retardant. But it was found that too much fire retardant damaged aging resistance and cold resistance of the polymer compound.

Axisymmetric bending of a circular plate with stiff edge on a soft FGM layer

  • Volkov, Sergey S.;Litvinenko, Alexander N.;Aizikovich, Sergey M.;Wang, Yun-Che;Vasiliev, Andrey S.
    • Structural Engineering and Mechanics
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    • v.59 no.2
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    • pp.227-241
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    • 2016
  • A circular plate with constant thickness, finite radius and stiff edge lying on an elastic halfspace is considered. The half-space consists of a soft functionally graded (FGM) layer with arbitrary varying elastic properties and a homogeneous elastic substrate. The plate bends under the action of arbitrary axisymmetric distributed load and response from the elastic half-space. A semi-analytical solution for the problem effective in whole range of geometric (relative layer thickness) and mechanical (elastic properties of coating and substrate, stiffness of the plate) properties is constructed using the bilateral asymptotic method (Aizikovich et al. 2009). Approximated analytical expressions for the contact stresses and deflections of the plate are provided. Numerical results showing the qualitative dependence of the solution from the initial parameters of the problem are obtained with high precision.

Influence of a soft FGM interlayer on contact stresses under a beam on an elastic foundation

  • Aizikovich, Sergey M.;Mitrin, Boris I.;Seleznev, Nikolai M.;Wang, Yun-Che;Volkov, Sergey S.
    • Structural Engineering and Mechanics
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    • v.58 no.4
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    • pp.613-625
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    • 2016
  • Contact interaction of a beam (flexible element) with an elastic half-plane is considered, when a soft inhomogeneous (functionally graded) interlayer is present between them. The beam is bent under the action of a distributed load applied to the surface and a reaction of the elastic interlayer and the half-space. Solution of the contact problem is obtained for different values of thickness and parameters of inhomogeneity of the layer. The interlayer is assumed to be significantly softer than the underlying half-plane; case of 100 times difference in Young's moduli is considered as an example. The influence of the interlayer thickness and gradient of elastic properties on the distribution of the contact stresses under the beam is studied.

Plasma Surface Treatment of Aluminum Extrusion Die (알루미늄 압출용 금형의 플라즈마 표면처리)

  • Choi, In Kyu;Lee, Su Young;Kim, Sang Ho
    • Journal of Surface Science and Engineering
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    • v.47 no.6
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    • pp.282-286
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    • 2014
  • Wear characteristic of the nitrided SKD61 which is a typical mold material using for the extrusion of Al6061 alloy was investigated. The surface of SKD61 was nitrided by salt bath and plasma processes. The thickness of surface nitride layer was about $8.9{\mu}m{\sim}21.3{\mu}m$. Reciprocating friction wear test conducted using pin on disk type indicated the plasma treatment followed salt bath has a lower friction coefficient and a smaller adhesive wear with Al6061 alloy. That was identified by the $Fe_4N$ which has a better wear resistance than FeN mainly formed by plasma nitriding.

Catalytic deoxygenation of vanillin over layered double hydroxide supported Pd catalyst

  • Liao, Chanjuan;Liu, Xixi;Ren, Yongshen;Gong, Daoxin;Zhang, Zehui
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.380-386
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    • 2018
  • A sustainable method was developed for the upgrade of biomass derived vanillin (a typical model compound of lignin) into the potential liquid biofuels over a layered double hydroxide supported Pd catalyst (abbreviated as CoAl-LDH/Pd). The CoAl-LDH/Pd catalyst showed high catalytic activity towards the hydrodeoxygenation of vanillin into 2-methoxy-4-methylphenol (MMP) under mild conditions in aqueous media. High MMP yield up to 86% was produced at $120^{\circ}C$ after 4 h. Kinetic studies revealed that the rate-determining step for the hydrodeoxygenation of vanillin was the hydrogenolysis of vanillyl alcohol. More importantly, the CoAl-LDH/Pd catalyst was highly stable without the loss of activity.

Property Comparison of Bio-Polyurethane and Petroleum based Polyurethane (바이오 폴리우레탄과 석유기반 폴리우레탄의 물성 비교)

  • Lee, Dam Hee;Lee, Kwan Hee;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.2
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    • pp.47-52
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    • 2018
  • The three polyols, poly(trimethylene ether) glycol 2000, poly(tetramethylene ether) glycol 2000 and poly (tetramethylene ether) glycol 1000 were reacted with 4,4-diphenylmethane diisocyanate to get polyurethanes. The synthesized three polyurethanes were measured by FT-IR, NMR for investigating chemical structures. Through two spectroscophical methods, It is found that urethane group exists in the three polymers. From the evaluation of hardness, glass transition temperature, tensile strength, and water resistance, the results showed increasing order of Poly(tetramethylene ether) glycol 1000 > Poly(trimethylene ether) glycol 2000 > Poly(tetramethylene ether) glycol 2000 with the content of hard segment in polyurethane.

Study on Properties with Different Plasticizers in the Preparation of Polymer Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.35-39
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    • 2019
  • Four different polymer compounds were prepared from four kinds of plasticizers, viz. di-2-ethylhexyl azelate (DOZ), di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl sebacate (DOS), and di-2-butyl sebacate (DBS), for making cable sheaths for ships. Ethylene-vinyl acetate and ethylene-propylene-diene-copolymer as matrix polymers and ethylene-vinyl acetate grafted maleic anhydride as a coupling agent were compounded with a flame retardant, crosslinking agent, filler, and other additives, besides the plasticizer to obtain the polymer compounds. The polymer containing DOZ showed the highest MH and ${\Delta}T$ in the rheology test, while that containing DBS was found to have the lowest tensile strength and highest elongation because of low ${\Delta}T$. The four polymers showed similar values (31.7-31.9) for flame resistance, while the polymer containing DOZ showed the highest value for cold resistance.

Electrodeposited WO3 films and their application in electrochromic boards

  • Kim, Dae-Hyeon;Kang, Kwang-Mo;Nah, Yoon-Chae
    • Journal of Surface Science and Engineering
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    • v.55 no.4
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    • pp.187-195
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    • 2022
  • WO3 thin films were synthesized by electrodeposition, and their electrochromic properties were investigated. The application of static voltage produced WO3 films with a smooth, compact surface morphology, and the film thickness linearly increased with the application time. The thicker film showed a strong color contrast but a slow color-switching speed. High-temperature heat treatment exceeding 300 ℃ induced a phase transformation from an amorphous to a monoclinic structure and resulted in degraded electrochromic performance. Furthermore, the optimized WO3 thin films demonstrated their potential application as electrochromic boards for writing and erasing letters using a simple modified 3D printer in a rapid, accurate process