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Structural Characterization of the Intermetallic Phase EuZnxIn4-x (x ≈ 1.1-1.2). Zn and In Site-Preferences in the BaAl4 Structure-Type from Computational Analysis

  • You, Tae-Soo;Nam, Gnu;Kim, Youngjo;Darone, Gregory M.;Bobev, Svilen
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1656-1662
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    • 2013
  • The ternary phase $EuZn_xIn_{4-x}$ has been identified as the main product of reactions of Eu, Zn, and In by using the In-flux method and characterized by both powder and single-crystal X-ray diffraction. The structure belongs to the common $BaAl_4$-type (tetragonal space group I4/mmm, Pearson code tI10) with lattice parameters of a = 4.5610(9) ${\AA}$, c = 12.049(3) ${\AA}$ for composition $EuZn_{1.10(12)}In_{2.90}$ and a = 4.5463(3) ${\AA}$, c = 12.028(2) ${\AA}$ for composition $EuZn_{1.18(2)}In_{2.82}$, respectively. In this structure, the Eu atoms are situated at the center of 18-vertex Fedorov polyhedra made of Zn and In atoms, where the 4d site is preferentially occupied by In and the 4e site is occupied by randomly mixed Zn and In atoms. Theoretical investigations using tight-binding linear muffintin orbital (TB-LMTO) method provide rationale for the observed site preferences and suggest potentially wider homogeneity range than the experimentally established for $EuZn_xIn_{4-x}$ ($x{\approx}1.1$).

Properties of Combustion Synthesized $SnO_2:Eu^{3+}$ Phosphors

  • Kang, Jong-Hyuk;Kim, Jin-Young;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.831-834
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    • 2002
  • A novel ceramic synthesis technique, combustion synthesis, is explored to produce an orange-emitting $SnO_2:Eu^{3+}$ phosphors. This technique involves a reaction of metal salts with a citric acid as an organic fuel. The variation of the ratio of citric acid to metal introduces change in reaction temperature and atmosphere of the combustion reaction, which in turn influences crystallinity and luminescence properties of the final products significantly. And the heat treatment of the as-synthesized product improved the CL intensity of the products. Especially, the sample treated at above 1100 $^{\circ}C$ shows an orange-emission, which is attributed to the formation of single phase and well-crystallized $SnO_2$:Eu in rutile structure.

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A Study on German Market of Korean Image Influence in Purchasing Decision - Focusing on 4 Markets in Germany - (한국 국가이미지가 독일시장 내 구매결정에 미치는 영향 분석 - 독일 4개 시장을 중심으로 -)

  • Han, Su-Jin;Kim, Byoung-Goo;Lee, Chun-Su
    • International Area Studies Review
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    • v.12 no.2
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    • pp.251-274
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    • 2008
  • This article investigated competitiveness evaluation of Korean product in German market that it is the most difficult to entry among EU countries in order to gain the upper hand against other MNCs. Specially, this empirical study analyzed product evaluation by using country image, corporate image and purchase experience. As the empirical results, Korean economy image and general image are significant. This means that German consumers have good image for economic, social and cultural image, so these factors influence product evaluation through halo effect. Also, we analyzed the effect of brand purchase experience and knowledge for Korea on product evaluation of German consumer. The results that country competitiveness and image play a role into product evaluation provide implication that we should make not only country image but also developed political, cultural image.

A Study on Photoluminance Properties of $(Y,Gd)BO_3:Eu^{3+}$ Phosphor Synthesized by Ultrasonic Spray Pyrolysis (초음파 분무법으로 제조한 $(Y,Gd)BO_3:Eu^{3+}$ 형광체의 발광특성에 관한 연구)

  • Kim, Dae-Su;Lee, Rhim-Youl
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.204-211
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    • 2000
  • The $(Y,Gd)BO_3:Eu$ red phosphors for PDP application were synthesized by ultrasonic spray method and then their photoluminance properties were investigated under 147nm VUV irradiation. The precursor solution of acetates of Y, GD and Eu and boric acid diluted in water was sprayed using 1.7 MHz ultra-sonic sprayer into the reaction tube held at high temperature. The as-sprayed particles were amorphous phase having C-C and C-H bonds due to the insufficient thermal reaction during the pass along the tube. But the sprayed samples followed by heat treatment at $1100^{\circ}C$ had the same crystal structure and chemical composition as those samples followed by solid state reaction. It was found that the $(Y_{0.7}Gd_{0.3})_{0.95} BO_3:Eu_{0.05}^{3+}$ phosphor particles synthesized by spray at $500^{\circ}C$ and then heat treated at $900^{\circ}C$ had a spherical-like shape and fine particle size at $0.7{\mu\textrm{m}}$ having a narrow size distribution, while the phosphor particles made by solid state reaction was $3{\mu\textrm{m}}$ coarse and non-uniform size distribution. The emitting intensity under 147nm VUV excitation for $(Y_{0.7}Gd_{0.3})_{0.95}BO_3:Eu_{0.05}^{3+}$ phosphor prepared by spray method was found to be higher than those phosphor made by solid state reaction and the commercial $(Y,Gd)BO_3:Eu$ product.

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Analysis Research on Preparation of 4th Wave (AI) of the Visegrad Group

  • Kim, Dong Hwa;Seo, Dae-Sung
    • The Journal of Asian Finance, Economics and Business
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    • v.5 no.4
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    • pp.201-211
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    • 2018
  • The paper suggests making a policy and strategies for a way of exporting Korean ICT product effectively in the EU and Eastern area, and an effective preparation of 4th industrial revolution through analysis of preparation status of 4th industrial revolution of the Visegrad group. Analyze policy, status, what they want for 4th preparation in the Visegrad group from comparing characteristics analysis of each country's official data, publication data, portal, paper, and etc. They have been preparing for 4th industrial revolution long time ago as basic research and business before 4th wave word. With these basic results, they are trying to apply such as, AI, S/W, security, ICT, etc. of 4th wave core technology. For the development of new export market in EU, the Korean team should research with university and research center or venture company. Through these cooperation, they should understand their personal characteristic, lifestyle, and what consumers want to purchase in EU. And this results can be used in South Asia and India that give a big effect to all over the world ICT market. The external impact of the 4th wave must have a long-term shift in manpower, and production policy is related to the EU's strategic role, or the preparation of the 4th wave to the V4 country in the short term.

Geochemical Study of Some Mesozoic Granitic Rocks in South Korea (남한의 일부 중생대 화강암류의 지구화학적 연구)

  • Kim, Kyu Han
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.435-446
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    • 1992
  • REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

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A Study on the Practical Approach of European Union's Market Access through the Understanding of Tariffs and Non-Tariff Barriers in European Union (EU의 관세 및 비관세 장벽 이해를 통한 EU시장 개척 방안)

  • Jung, Jae-Woo;Lee, Kil-Nam
    • International Commerce and Information Review
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    • v.16 no.4
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    • pp.191-225
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    • 2014
  • Most of all, this paper analyzes the current situation of EU(European Union) and ascertain EU's economic condition in terms of tariff lines and non-tariff barriers. and the purpose of this article is to find out the problems of EU's tariff lines and non-tariff barriers. Next, We suggest some future direction of export promotion from Korea to EU more largely for our companies. First, this paper describes the characteristics and outline of EU. The EU is a politico-economic union of 28 member states that are primarily located in Europe. The EU traces its origins from the European Coal and Steel Community(ECSC) and the European Economic Community(EEC), formed by the Inner Six countries in 1951 and 1958, respectively. After that, The Maastricht Treaty established the European Union under its current name in 1993. The latest major amendment to the constitutional basis of the EU, the Treaty of Lisbon, came into force in 2009. There are a combined population of over 500 million inhabitants and generated a nominal gross domestic product(GDP) of 16.692 trillion US dollars in EU. The results are as follows ; First of all, In terms of tariff lines and customs duties, Our companies have to know precisely EU's real tariff lines and other customs duties, and such as value added tax and exercise tax, corporate tax regulated by EU commission and EU's 28 members. second, our companies have to confirm EU's non-tariff barriers. such as RoHS, WEEE, REACH. These non-tariff barriers could be hindrances or obstacles to trade with foreign companies in other countries. We perceive all companies exporting to EU are related with these Technical Barriers to Trade irrespective of their nationality. So, Our companies fulfill the requirements of EU Commission concerning safety, health, environment etc. Also, Our companies choose market-driven strategy to export more largely than before in the field of marketing and logistics.

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Characteristics of Halophosphate Phosphor for Long-wavelength UV Prepared by Spray Pyrolysis (분무열분해법에 의해 합성된 장파장 자외선용 할로포스페이트계 형광체의 특성)

  • Sohn, Jong-Rak;Kang, Yun-Chan;Park, Hee-Dong;Yoon, Soon-Gil
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.555-559
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    • 2002
  • Blue-emitting $Sr_{10}$($PO$)$_{6}$ $Cl_2$:$Eu^{2+}$ and $_{(Sr,Mg) }$ 10/($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles for application of long-wavelength UV LED were prepared by ultrasonic spray pyrolysis. The luminescence characteristics under long- wave-length ultraviolet of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ and (Sr,Mg)$_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$^Eu{2+}$ phosphor particles prepared by the spray pyrolysis were compared with that of the commercial product. The PL intensity of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles prepared by the spray pyrolysis was lower than that of the commercial $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles because prepared $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles had porous structure and hollow morphology. However, the PL intensity of the (Sr,Mg)$_{10}$($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles prepared by the spray pyrolysis was 8% higher than that of the commercial one. The high brightness of $(Sr,Mg)_{10}$ ($PO_4$)$_{6}$ $Cl_2$:Eu$^{2+}$ phosphor particles prepared by spray pyrolysis is due to the dense structure and high crystallinity of particles. The TEX>$(Sr,Mg)<_{10}$ ($PO_4$)$_{6}$ /$Cl_2$:$Eu^{ 2+}$ phosphor particles had main emission peak t 448 nm under long- wavelength ultraviolet.

유럽의 새로운 환경정책 동향 : 통합제품정책

  • 이광원
    • Environmental engineer
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    • s.169
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    • pp.26-30
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    • 2000
  • (1) 통합제품정책의 배경 - 지속가능한 개발 달성을 위한 환경영향의 감소를 위해서는 공정 중심에서 제품 중심으로의 환경정책 변화가 필요하다는 인식이 확산 - EU에서는 새로운 환경정책 분야인 통합제품정책(Integrated Product Policy : IPP) 개발을 추진하여 이에 대한 연구과제 수행 및 워크숍을 개최하였고 올해에는 통합제품정책에 대한 녹서(Green Paper)를 발간할 예정 (2) 통합제품정책의 주요내용 - 정책의 개념 o (환경

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Life Cycle Assessment of Korean Tilting Train eXpress for Environmental Declaration of Product(EDP) (환경성적표지 인증을 위한 한국형 틸팅열차의 전과정평가)

  • Lee, Hyun-Bae;Kim, Yong-Ki;Lee, Kun-Mo
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.2262-2269
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    • 2010
  • A recent Tilting train development operation for existing line high speed, already developed "Korean Tilting Train eXpress(bellow TTX)" and that doing demonstration of operation. And TTX are going to commercial service in 2012. They are preparing Environmental Declaration of Product(bellow EDP) for offering environmental impact of TTX to customer. EDP calculated environmental impact of target product's whole life cycle(raw material and manufacturing, distribution, use, end of life) more quantity for that improving environmental impact and then certification them, it is using for that estimate some part of existence of specific pollutants, GHGs, energy consumption and recycling ratio. In this study, 1) analyze the process of getting EDP, 2) satisfy common criteria and each criteria(plan) in the Product Category Rules(bellow PCRs) provided KEITI, 3) according to ISO 14044, implementation of LCA. 4) These results be shown Characterized Impact(bellow CI) about each life cycle stage and six impact categories(ARD, GWP, OD, AD, EU, POC).

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