• Elastomers and Composites
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• v.51 no.3
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• pp.175-180
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• 2016

Influence of amino acidic chemical on properties of maleic anhydride-grafted ethylene-propylene-diene terpolymer/zinc oxide (EPDM-g-MAH/ZnO) composites was investigated. 4-Aminosalicylic acid (ASA), 4-amino-2-methoxybenzoic acid (AMBA), 12-aminolauric acid (ALA), and glutamine (Gln) were employed as the amino acidic chemicals. Though small quantity (0.5 phr) of the amino acidic chemical was added to the EPDM-g-MAH/ZnO composite, the properties were notably changed. By adding the amino acidic chemical, the percent crystallinity and apparent crosslink density were reduced. Order of the percent crystallinity was related to that of the $pK_a$ values of amino acidic chemicals. By adding the amino acidic chemical, the basic tensile properties were on the whole improved. The experimental results were explained by the $pK_a$ values of amino acidic chemicals, change of zinc ionomer formation, and interactions between the additive and EPDM-g-MAH chain.

• Elastomers and Composites
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• v.51 no.2
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• pp.93-98
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• 2016

The composites of EVA/EPDM including aluminum trioxide (ATH) as a fire retardant were manufactured for the purpose of improving low temperature property and flame resistance in the rubbery materials. The ratio of EVA to EPDM didn't affect the flame resistance of the rubber composites. The addition of ATH resulted in increase of the flame resistance. In the evaluation of the cold resistance, the increasing EPDM content showed enhancement of cold resistance in the composites due to increasing low Tg EPDM. It was found out that tensile strengths of the composites showed a maximum value at 100 phr of ATH by reinforcing effect, but a minimum value at 200 phr of ATH owing to slippage between the flame retardant by the external stress. In the measurement of solvent resistance in tetrahydrofuran, the increasing ATH content yielded enhancement of solvent resistance by reducing swelling of the composite, and increasing EPDM content also resulted from increase of the solvent resistance by reduction of polarizability as well as increase of crosslink in the composites.

• Proceedings of the KAIS Fall Conference
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• 2004.06a
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• pp.82-85
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• 2004

EPDM 봉인물질을 가진 SOV의 작동실패 사례 및 원인을 분석해보면 많은 SOV 고장(SOV failures)은 결국 EPDM 봉인물질이 원인인 것으로 나타났다. SOV 고장은 SOV가 그것의 설계 범위를 초과하는 주위 온도(ambient temperature)에 노출되어 있었기 때문에 발생되었다. 그러한 SOV 고장은 증기누설, 주위 온도의 부정확한 평가 등의 원인에 의해 발생되었다. 또한 SOV 고장은 연속적인 coil의 여기시 발생하는 가열(heatup from energization)로 인해 수명이 단축되는 영향이 서비스 수명 기간에 적절하게 포함되지 않았기 때문에 발생되었다 많은 발전소 운용자는 이러한 사실을 알고 있지 못하였으며 결과적으로 서비스 수명 기간이 과도 예측되는 결과가 초래되었다 SOV의 또 다른 연성(Soft) 봉인물질로, 열저항 특성이 EPDM에 비해 약 $50^{\circ}C$ 정도 우수한 Viton 봉인물질에 대한 특성이 제시되었다. 더불어 현재 많은 국외 솔레노이드구동밸브 전문 생산업체들이 Viton 재료를 옵션으로 채택하고 있는 추세이다. 그러나 고온주변에서 지속적으로 노출되어 있는 환경에서 Viton이 EPDM의 문제점을 어느 정도 해결할 수 있는 지의 여부는 현재 결론 내리기 어려울 것으로 판단되며, 향후 이를 채택한 SOV의 운전경험을 계속 주시할 필요가 있을 것으로 판단된다.

• Polymer(Korea)
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• v.34 no.5
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• pp.430-433
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• 2010

The gasket materials of for the lithium ion battery requires chemical resistance to electrolyte, electrical insulating, compression set, anti-contamination and low temperature property. To check the special characteristics of fillers which are applied to rubber for gasket, compound of EPDM, NBR and FKM (fluoro elastomer) were made by adjusting weights of carbon black and silica additive. Using these compounds, we had done tests of long-term stability against electrolyte, compression set and low-temperature property with considering operating condition of the lithium ion battery. From this test, we investigated the physical and chemical characteristics of rubber with using of carbon black and silica additive in each.

• Elastomers and Composites
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• v.44 no.1
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• pp.47-54
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• 2009

EPDM(Ethylene-propylene-diene-terpolymer) compound reinforced with carbon black having four different particle size, acetylene black(thermal conductivity carbon black), and silica were manufactured by internal mix and open mill. To investigate the effect of particle size of filler and filler type on far-infrared vulcanization, intermal temperature of compound, degree of curing, infrared spectroscopy, and thermal analysis were measured. The thermal conductivity of far-infrared vulcanized EPDM compound increased with increasing particle size of carbon filler, but hot air vulcanized EPDM compound is not affected by particle size. The thermal conductivity was increased in the order of carbon black < silica < acetylene black(thermal conductivity carbon black).

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.5
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• pp.453-458
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• 2020

In this study, ethylene-propylene-diene monomer (EPDM) rubbers reinforced with various particle size of carbon black were prepared and tested. We followed recently published CSA/ANSI CHMC2 standard "the test methods for evaluating material compatibility in compressed hydrogen applications-polyemr". Measurement of change in hardness, tensile strength and volume were performed after exposure to maximum operating pressure, 87.5 MPa, for 168 hours (1 week). Once EPDM was exposed to high-pressure hydrogen, the samples experience volume increase and degradation of the physical properties. Also, after the dissolved hydrogen was fully eliminated from the specimens, the hardness and the tensile properties were not recovered. The rubber reinforced with smaller sizes of carbon black particles showed less volume expansion and decrease of physical properties. As a result, smaller particle size of carbon black filler led to more resistance to high-pressure hydrogen.

• Elastomers and Composites
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• v.42 no.4
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• pp.232-237
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• 2007

We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

• Elastomers and Composites
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• v.42 no.4
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• pp.249-258
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• 2007

In this study, the EPDM powder which was surface activated by high temperature and shear pulverization process was prepared and the mechanical properties and odor material analysis were investigated. Analysis for particle size and size distribution of waste of the EPDM powder has been performed. The waste EPDMs used in this study were 4 types of solid, sponge, solid+sponge, and solid+metal. According to the results, the solid type showed the smallest particle size among the 4 types of EPDM powder. Effective surface devulcanization of EPDM powder could be obtained by the addition of the reclaiming agent. The dicumyl peroxide was considered as the best crosslink agent for dynamic vulcanization when the surface activated EPDM powder was blended with polyolefin in order to make TPE. Also, the optimum amounts of DCP was 6 phr in terms of surface crosslink reaction and mechanical properties of EPDM powder. The processes of water adsorption and rose oil addition were employed to remove the odor of EPDM powder caused by reclaiming agent. The GC/MS was used to analyze the odor compounds.

• Elastomers and Composites
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• v.52 no.1
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• pp.59-68
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• 2017

The effect on the hydrolysis resistance properties by the addition of maleic anhydride grafted EMDM (MA-g-EPDM) and PP (MA-g-PP) to a PA66/GF composite was investigated with respect to the mechanical properties, thermal properties, and morphology. The degree of hydrolysis of the PA66/GF composite was measured using py-GC/MS analysis. When compared to the PA66/GFcomposite in MEG/water solution, the composites where MA-g-EPDM and MA-g-PP were added to PA66/GF showed a higher degree of hydrolysis resistance, impact strength, and thermal properties, whereas their tensile strength, tensile modulus, flexural strength and flexural modulus decreased. As immersion time in the solution increases, the rate of tensile strength drop of the MA-g-PP added composite appeared lower than that of the PA66/MA-g-EPDM/GF and PA66/GF composites. The py-GC/MS analysis confirmed the formation of PA66 hydrolysis reaction by products such as carboxylic acid and alkylamine with increasing immersion time.

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1265-1267
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• 1994

EPDM has excellent electric characteristics and so that it has been rapidly finding use is high voltage applications in recent years. At present EPDM is widely used for insulator of cable and accessories, and further the commercial use of Premolded housing for elbow surge arrester is started. In this paper, we have measured the temperature, pressure and voltages dependence of $tan{\delta}$ in EPDM. As a results, dielectric characteristics($tan{\delta}$) increases slightly with increasing the temperature. However, it is almost independent of the pressure and voltages.